(a) Interpretation: The alkyl halide needed to prepare carboxylic acid by the malonic ester synthesis is to be predicted. Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO 2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

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Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 21.9, Problem 24P

Interpretation Introduction

(a)

Interpretation: The alkyl halide needed to prepare carboxylic acid by the malonic ester synthesis is to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Interpretation Introduction

(b)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Interpretation Introduction

(c)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

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Answer 2

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Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 21.9, Problem 24P

Interpretation Introduction

(a)

Interpretation: The alkyl halide needed to prepare carboxylic acid by the malonic ester synthesis is to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Interpretation Introduction

(b)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Interpretation Introduction

(c)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 21.9, Problem 24P

Interpretation Introduction

(a)

Interpretation: The alkyl halide needed to prepare carboxylic acid by the malonic ester synthesis is to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Interpretation Introduction

(b)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Interpretation Introduction

(c)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 21.9, Problem 24P

Interpretation Introduction

(a)

Interpretation: The alkyl halide needed to prepare carboxylic acid by the malonic ester synthesis is to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Interpretation Introduction

(b)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Interpretation Introduction

(c)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

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Answer 5

Chapter 21.9, Problem 24P

Interpretation Introduction

(a)

Interpretation: The alkyl halide needed to prepare carboxylic acid by the malonic ester synthesis is to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Interpretation Introduction

(b)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Interpretation Introduction

(c)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Answer 6

Chapter 21.9, Problem 24P

Interpretation Introduction

(a)

Interpretation: The alkyl halide needed to prepare carboxylic acid by the malonic ester synthesis is to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Answer 7

Chapter 21.9, Problem 24P

Interpretation Introduction

(a)

Interpretation: The alkyl halide needed to prepare carboxylic acid by the malonic ester synthesis is to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Answer 8

Interpretation Introduction

(b)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Answer 9

Interpretation Introduction

(b)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Answer 10

Interpretation Introduction

(c)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Answer 11

Interpretation Introduction

(c)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Answer 12

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Answer 14

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Answer 15

Ch. 21.2 - Problem 23.1 Draw the enol or keto tautomer(s) of...Ch. 21.2 - Problem 23.3 When phenylacetaldehyde is dissolved...Ch. 21.3 - Prob. 5P Ch. 21.3 - Problem 23.5 Which bonds in the following...Ch. 21.3 - Prob. 7P Ch. 21.3 - Prob. 8P Ch. 21.3 - Prob. 9P Ch. 21.4 - Prob. 10P Ch. 21.5 - Prob. 11P Ch. 21.7 - Problem 23.11 Draw the products of each...

Solution Summary: The author explains that the alkyl halide needed to prepare carboxylic acid by the malonic ester synthesis is to be predicted.

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Chapter 21 Solutions