a) Interpretation: The structure of the step-growth polymer expected to be obtained from the reaction given is to be shown. Concept introduction: In step growth polymers each bond is formed independently in a discrete step. In the formation of these step growth polymers, n moles of one component react with n moles of other component to form a polymer with n repeating units eliminating 2n moles of small molecules. To draw: The structure of the step-growth polymer expected to be obtained from the reaction given.

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Answer 1

Question

Chapter 21.9, Problem 23P

Interpretation Introduction

a)

Interpretation:

The structure of the step-growth polymer expected to be obtained from the reaction given is to be shown.

Concept introduction:

In step growth polymers each bond is formed independently in a discrete step. In the formation of these step growth polymers, n moles of one component react with n moles of other component to form a polymer with n repeating units eliminating 2n moles of small molecules.

To draw:

The structure of the step-growth polymer expected to be obtained from the reaction given.

Interpretation Introduction

b)

Interpretation:

The structure of the step-growth polymer expected to be obtained from the reaction given is to be given.

Concept introduction:

In step growth polymers each bond is formed independently in a discrete step. In the formation of these step growth polymers, n moles of one component react with n moles of other component to form a polymer with n repeating units eliminating 2n moles of small molecules.

To draw:

The structure of the step-growth polymer expected to be obtained from the reaction given.

Interpretation Introduction

c)

Interpretation:

The structure of the step-growth polymer expected to be obtained from the reaction given is to be given.

Concept introduction:

In step growth polymers each bond is formed independently in a discrete step. In the formation of these step growth polymers, n moles of one component react with n moles of other component to form a polymer with n repeating units eliminating 2n moles of small molecules.

To draw:

The structure of the step-growth polymer expected to be obtained from the reaction given.

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The table includes macrostates characterized by 4 energy levels (&) that are equally spaced but with different degrees of occupation. a) Calculate the energy of all the macrostates (in joules). See if they all have the same energy and number of particles. b) Calculate the macrostate that is most likely to exist. For this macrostate, show that the population of the levels is consistent with the Boltzmann distribution. macrostate 1 macrostate 2 macrostate 3 ε/k (K) Populations Populations Populations 300 5 3 4 200 7 9 8 100 15 17 16 0 33 31 32 DATO: k = 1,38×10-23 J K-1

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In an experiment, the viscosity of water was measured at different temperatures and the table was constructed from the data obtained. a) Calculate the activation energy of viscous flow (kJ/mol). b) Calculate the viscosity at 30°C. T/°C 0 20 40 60 80 η/cpoise 1,972 1,005 0,656 0,469 0,356

Answer 2

Question

Chapter 21.9, Problem 23P

Interpretation Introduction

a)

Interpretation:

The structure of the step-growth polymer expected to be obtained from the reaction given is to be shown.

Concept introduction:

In step growth polymers each bond is formed independently in a discrete step. In the formation of these step growth polymers, n moles of one component react with n moles of other component to form a polymer with n repeating units eliminating 2n moles of small molecules.

To draw:

The structure of the step-growth polymer expected to be obtained from the reaction given.

Interpretation Introduction

b)

Interpretation:

The structure of the step-growth polymer expected to be obtained from the reaction given is to be given.

Concept introduction:

In step growth polymers each bond is formed independently in a discrete step. In the formation of these step growth polymers, n moles of one component react with n moles of other component to form a polymer with n repeating units eliminating 2n moles of small molecules.

To draw:

The structure of the step-growth polymer expected to be obtained from the reaction given.

Interpretation Introduction

c)

Interpretation:

The structure of the step-growth polymer expected to be obtained from the reaction given is to be given.

Concept introduction:

In step growth polymers each bond is formed independently in a discrete step. In the formation of these step growth polymers, n moles of one component react with n moles of other component to form a polymer with n repeating units eliminating 2n moles of small molecules.

To draw:

The structure of the step-growth polymer expected to be obtained from the reaction given.

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Answer 3

Question

Chapter 21.9, Problem 23P

Interpretation Introduction

a)

Interpretation:

The structure of the step-growth polymer expected to be obtained from the reaction given is to be shown.

Concept introduction:

In step growth polymers each bond is formed independently in a discrete step. In the formation of these step growth polymers, n moles of one component react with n moles of other component to form a polymer with n repeating units eliminating 2n moles of small molecules.

To draw:

The structure of the step-growth polymer expected to be obtained from the reaction given.

Interpretation Introduction

b)

Interpretation:

The structure of the step-growth polymer expected to be obtained from the reaction given is to be given.

Concept introduction:

In step growth polymers each bond is formed independently in a discrete step. In the formation of these step growth polymers, n moles of one component react with n moles of other component to form a polymer with n repeating units eliminating 2n moles of small molecules.

To draw:

The structure of the step-growth polymer expected to be obtained from the reaction given.

Interpretation Introduction

c)

Interpretation:

The structure of the step-growth polymer expected to be obtained from the reaction given is to be given.

Concept introduction:

In step growth polymers each bond is formed independently in a discrete step. In the formation of these step growth polymers, n moles of one component react with n moles of other component to form a polymer with n repeating units eliminating 2n moles of small molecules.

To draw:

The structure of the step-growth polymer expected to be obtained from the reaction given.

Expert Solution & Answer

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Answer 4

Question

Chapter 21.9, Problem 23P

Interpretation Introduction

a)

Interpretation:

The structure of the step-growth polymer expected to be obtained from the reaction given is to be shown.

Concept introduction:

In step growth polymers each bond is formed independently in a discrete step. In the formation of these step growth polymers, n moles of one component react with n moles of other component to form a polymer with n repeating units eliminating 2n moles of small molecules.

To draw:

The structure of the step-growth polymer expected to be obtained from the reaction given.

Interpretation Introduction

b)

Interpretation:

The structure of the step-growth polymer expected to be obtained from the reaction given is to be given.

Concept introduction:

In step growth polymers each bond is formed independently in a discrete step. In the formation of these step growth polymers, n moles of one component react with n moles of other component to form a polymer with n repeating units eliminating 2n moles of small molecules.

To draw:

The structure of the step-growth polymer expected to be obtained from the reaction given.

Interpretation Introduction

c)

Interpretation:

The structure of the step-growth polymer expected to be obtained from the reaction given is to be given.

Concept introduction:

In step growth polymers each bond is formed independently in a discrete step. In the formation of these step growth polymers, n moles of one component react with n moles of other component to form a polymer with n repeating units eliminating 2n moles of small molecules.

To draw:

The structure of the step-growth polymer expected to be obtained from the reaction given.

Expert Solution & Answer

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See solution

Answer 5

Chapter 21.9, Problem 23P

Interpretation Introduction

a)

Interpretation:

The structure of the step-growth polymer expected to be obtained from the reaction given is to be shown.

Concept introduction:

In step growth polymers each bond is formed independently in a discrete step. In the formation of these step growth polymers, n moles of one component react with n moles of other component to form a polymer with n repeating units eliminating 2n moles of small molecules.

To draw:

The structure of the step-growth polymer expected to be obtained from the reaction given.

Interpretation Introduction

b)

Interpretation:

The structure of the step-growth polymer expected to be obtained from the reaction given is to be given.

Concept introduction:

In step growth polymers each bond is formed independently in a discrete step. In the formation of these step growth polymers, n moles of one component react with n moles of other component to form a polymer with n repeating units eliminating 2n moles of small molecules.

To draw:

The structure of the step-growth polymer expected to be obtained from the reaction given.

Interpretation Introduction

c)

Interpretation:

The structure of the step-growth polymer expected to be obtained from the reaction given is to be given.

Concept introduction:

In step growth polymers each bond is formed independently in a discrete step. In the formation of these step growth polymers, n moles of one component react with n moles of other component to form a polymer with n repeating units eliminating 2n moles of small molecules.

To draw:

The structure of the step-growth polymer expected to be obtained from the reaction given.

Answer 6

Chapter 21.9, Problem 23P

Interpretation Introduction

a)

Interpretation:

The structure of the step-growth polymer expected to be obtained from the reaction given is to be shown.

Concept introduction:

In step growth polymers each bond is formed independently in a discrete step. In the formation of these step growth polymers, n moles of one component react with n moles of other component to form a polymer with n repeating units eliminating 2n moles of small molecules.

To draw:

The structure of the step-growth polymer expected to be obtained from the reaction given.

Answer 7

Chapter 21.9, Problem 23P

Interpretation Introduction

a)

Interpretation:

The structure of the step-growth polymer expected to be obtained from the reaction given is to be shown.

Concept introduction:

In step growth polymers each bond is formed independently in a discrete step. In the formation of these step growth polymers, n moles of one component react with n moles of other component to form a polymer with n repeating units eliminating 2n moles of small molecules.

To draw:

The structure of the step-growth polymer expected to be obtained from the reaction given.

Answer 8

Interpretation Introduction

b)

Interpretation:

The structure of the step-growth polymer expected to be obtained from the reaction given is to be given.

Concept introduction:

In step growth polymers each bond is formed independently in a discrete step. In the formation of these step growth polymers, n moles of one component react with n moles of other component to form a polymer with n repeating units eliminating 2n moles of small molecules.

To draw:

The structure of the step-growth polymer expected to be obtained from the reaction given.

Answer 9

Interpretation Introduction

b)

Interpretation:

The structure of the step-growth polymer expected to be obtained from the reaction given is to be given.

Concept introduction:

In step growth polymers each bond is formed independently in a discrete step. In the formation of these step growth polymers, n moles of one component react with n moles of other component to form a polymer with n repeating units eliminating 2n moles of small molecules.

To draw:

The structure of the step-growth polymer expected to be obtained from the reaction given.

Answer 10

Interpretation Introduction

c)

Interpretation:

The structure of the step-growth polymer expected to be obtained from the reaction given is to be given.

Concept introduction:

In step growth polymers each bond is formed independently in a discrete step. In the formation of these step growth polymers, n moles of one component react with n moles of other component to form a polymer with n repeating units eliminating 2n moles of small molecules.

To draw:

The structure of the step-growth polymer expected to be obtained from the reaction given.

Answer 11

Interpretation Introduction

c)

Interpretation:

The structure of the step-growth polymer expected to be obtained from the reaction given is to be given.

Concept introduction:

In step growth polymers each bond is formed independently in a discrete step. In the formation of these step growth polymers, n moles of one component react with n moles of other component to form a polymer with n repeating units eliminating 2n moles of small molecules.

To draw:

The structure of the step-growth polymer expected to be obtained from the reaction given.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 21.1 - Give IUPAC names for the following substances:Ch. 21.1 - Draw structures corresponding to the following...Ch. 21.2 - Prob. 3P Ch. 21.2 - Rank the compounds in each of the following sets...Ch. 21.2 - Predict the products of the following nucleophilic...Ch. 21.2 - Prob. 6P Ch. 21.3 - Prob. 7P Ch. 21.3 - If the following molecule is treated with acid...Ch. 21.4 - How might you prepare the following esters using a...Ch. 21.4 - Prob. 10P

Solution Summary: The author explains the structure of the step-growth polymer expected to be obtained from the reaction given.

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Chapter 21 Solutions