From the given structure of a compound, the name has to be written. Concept Introduction: Benzene Nomenclature: Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here: • Identifying as what is the functional group . • Identifying the position of the functional group on the benzene ring. • Identifying as what is the alkyl substituent. • Identifying the position of the alkyl substituent on the benzene ring. Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

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Answer 1

Question

Chapter 21.3, Problem 21.5P

(a)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(b)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(c)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(d)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

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For each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 CI MgCl ? Will the first product that forms in this reaction create a new CC bond? Yes No MgBr ? Will the first product that forms in this reaction create a new CC bond? Yes No G टे

For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. དྲ。 ✗MgBr ? O CI Will the first product that forms in this reaction create a new C-C bond? Yes No • ? Will the first product that forms in this reaction create a new CC bond? Yes No × : ☐ X

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Answer 2

Question

Chapter 21.3, Problem 21.5P

(a)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(b)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(c)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(d)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

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Answer 3

Question

Chapter 21.3, Problem 21.5P

(a)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(b)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(c)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(d)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

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Answer 4

Question

Chapter 21.3, Problem 21.5P

(a)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(b)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(c)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(d)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

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Answer 5

Chapter 21.3, Problem 21.5P

(a)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(b)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(c)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

(d)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

Answer 6

Chapter 21.3, Problem 21.5P

(a)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

Answer 7

Chapter 21.3, Problem 21.5P

(a)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

Answer 8

(b)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

Answer 9

(b)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

Answer 10

(c)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

Answer 11

(c)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

Answer 12

(d)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

Answer 13

(d)

Interpretation Introduction

Interpretation: From the given structure of a compound, the name has to be written.

Concept Introduction:

Benzene Nomenclature:

Ø The name of any given benzene compound can be analysed by observing and identifying various aspects of its given structure which are outlined here:

• Identifying as what is the functional group.

• Identifying the position of the functional group on the benzene ring.

• Identifying as what is the alkyl substituent.

• Identifying the position of the alkyl substituent on the benzene ring.

Ø It is most important to remember that in the benzene nomenclature, the substituted benzene ring has to be named as “phenyl”.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 21.2 - Construct a Frost circle for a planar...Ch. 21.2 - Which compound gives a signal in the 1H-NMR...Ch. 21.2 - Prob. 21.3P Ch. 21.2 - Prob. 21.4P Ch. 21.3 - Prob. 21.5P Ch. 21.4 - Arrange these compounds in order of increasing...Ch. 21.4 - Prob. AQ Ch. 21.4 - Prob. BQ Ch. 21.4 - Prob. CQ Ch. 21.5 - Prob. 21.7P

Solution Summary: The author explains that the name of a compound can be analysed by observing and identifying various aspects of its given structure.

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Chapter 21 Solutions