ORGANIC CHEMISTRY-PRINT COMPANION (LL)
ORGANIC CHEMISTRY-PRINT COMPANION (LL)
3rd Edition
ISBN: 9781119444251
Author: Klein
Publisher: WILEY
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Chapter 21.3, Problem 14PTS

(a)

Interpretation Introduction

Interpretation:

The major product in the reaction of the given aldehyde with aqueous sodium hydroxide has to be predicted.

Concept Introduction:

Aldol addition:

When an aldehyde is treated with aqueous sodium hydroxide, the major product has the aldehydic group and a hydroxyl group. It is therefore called an “aldol” (“ald” for aldehyde and “ol” for alcohol). In the product, it is important to note that hydroxy group should be located in the β (beta) -position relative to the carbonyl group. Thus the product aldol is also known as β- hydroxy aldehyde.

General scheme:

ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 21.3, Problem 14PTS , additional homework tip  1

(b)

Interpretation Introduction

Interpretation:

The major product in the reaction of the given aldehyde with aqueous sodium hydroxide has to be predicted.

Concept Introduction:

Aldol addition:

When an aldehyde is treated with aqueous sodium hydroxide, the major product has the aldehydic group and a hydroxyl group. It is therefore called an “aldol” (“ald” for aldehyde and “ol” for alcohol). In the product, it is important to note that hydroxy group should be located in the β (beta) -position relative to the carbonyl group. Thus the product aldol is also known as β- hydroxy aldehyde.

General scheme:

ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 21.3, Problem 14PTS , additional homework tip  2

(c)

Interpretation Introduction

Interpretation:

The major product in the reaction of the given aldehyde with aqueous sodium hydroxide has to be predicted.

Concept Introduction:

Aldol addition:

When an aldehyde is treated with aqueous sodium hydroxide, the major product has the aldehydic group and a hydroxyl group. It is therefore called an “aldol” (“ald” for aldehyde and “ol” for alcohol). In the product, it is important to note that hydroxy group should be located in the β (beta) -position relative to the carbonyl group. Thus the product aldol is also known as β- hydroxy aldehyde.

General scheme:

ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 21.3, Problem 14PTS , additional homework tip  3

(d)

Interpretation Introduction

Interpretation: The major product in the reaction of the given aldehyde with aqueous sodium hydroxide has to be predicted.

Concept Introduction:

Aldol addition:

When an aldehyde is treated with aqueous sodium hydroxide, the major product has the aldehydic group and a hydroxyl group. It is therefore called an “aldol” (“ald” for aldehyde and “ol” for alcohol). In the product, it is important to note that hydroxy group should be located in the β (beta) -position relative to the carbonyl group. Thus the product aldol is also known as β- hydroxy aldehyde.

General scheme:

ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 21.3, Problem 14PTS , additional homework tip  4

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Chapter 21 Solutions

ORGANIC CHEMISTRY-PRINT COMPANION (LL)

Ch. 21.2 - Prob. 10CCCh. 21.2 - Prob. 11CCCh. 21.2 - Prob. 12CCCh. 21.2 - Prob. 13CCCh. 21.3 - Prob. 2LTSCh. 21.3 - Prob. 14PTSCh. 21.3 - Prob. 15PTSCh. 21.3 - Prob. 16ATSCh. 21.3 - Prob. 3LTSCh. 21.3 - Prob. 17PTSCh. 21.3 - Prob. 18ATSCh. 21.3 - Prob. 4LTSCh. 21.3 - Prob. 19PTSCh. 21.3 - Prob. 20ATSCh. 21.3 - Prob. 21CCCh. 21.3 - Prob. 22CCCh. 21.3 - Prob. 23CCCh. 21.4 - Prob. 24CCCh. 21.4 - Prob. 25CCCh. 21.4 - Prob. 26CCCh. 21.4 - Prob. 27CCCh. 21.4 - Prob. 28CCCh. 21.5 - Prob. 29CCCh. 21.5 - Prob. 30CCCh. 21.5 - Prob. 5LTSCh. 21.5 - Prob. 31PTSCh. 21.5 - Prob. 32ATSCh. 21.5 - Prob. 6LTSCh. 21.5 - Prob. 33PTSCh. 21.5 - Prob. 34ATSCh. 21.6 - Prob. 35CCCh. 21.6 - Prob. 36CCCh. 21.6 - Prob. 37CCCh. 21.6 - Prob. 7LTSCh. 21.6 - Prob. 38PTSCh. 21.6 - Prob. 39ATSCh. 21.6 - Prob. 40CCCh. 21.6 - Prob. 41CCCh. 21.7 - Prob. 8LTSCh. 21.7 - Prob. 42PTSCh. 21.7 - Prob. 43PTSCh. 21.7 - Prob. 9LTSCh. 21.7 - Prob. 45PTSCh. 21.7 - Prob. 46ATSCh. 21 - Prob. 47PPCh. 21 - Prob. 48PPCh. 21 - Prob. 49PPCh. 21 - Prob. 50PPCh. 21 - Prob. 51PPCh. 21 - Prob. 52PPCh. 21 - Prob. 53PPCh. 21 - Prob. 54PPCh. 21 - Prob. 55PPCh. 21 - Prob. 56PPCh. 21 - Prob. 57PPCh. 21 - Prob. 58PPCh. 21 - Prob. 59PPCh. 21 - Prob. 60PPCh. 21 - Prob. 61PPCh. 21 - Prob. 62PPCh. 21 - Prob. 63PPCh. 21 - Prob. 64PPCh. 21 - Prob. 65PPCh. 21 - Prob. 66PPCh. 21 - Prob. 67PPCh. 21 - Prob. 68PPCh. 21 - Prob. 69PPCh. 21 - Prob. 70PPCh. 21 - Prob. 71PPCh. 21 - Prob. 72PPCh. 21 - Prob. 73PPCh. 21 - Prob. 74PPCh. 21 - Prob. 75PPCh. 21 - Prob. 76PPCh. 21 - Prob. 77PPCh. 21 - Prob. 78PPCh. 21 - Prob. 79PPCh. 21 - Prob. 80PPCh. 21 - Prob. 81PPCh. 21 - Prob. 82PPCh. 21 - Prob. 83PPCh. 21 - Prob. 84PPCh. 21 - Prob. 85PPCh. 21 - Prob. 86PPCh. 21 - Prob. 87PPCh. 21 - Prob. 88PPCh. 21 - Prob. 89IPCh. 21 - Prob. 90IPCh. 21 - Prob. 91IPCh. 21 - Prob. 92IPCh. 21 - Prob. 93IPCh. 21 - Prob. 94IPCh. 21 - Prob. 95IPCh. 21 - Prob. 96IPCh. 21 - Prob. 97IPCh. 21 - Prob. 98IPCh. 21 - Prob. 99IPCh. 21 - Prob. 100IPCh. 21 - Prob. 101IPCh. 21 - Prob. 102IPCh. 21 - Prob. 103IPCh. 21 - Prob. 104IPCh. 21 - Prob. 105IPCh. 21 - Prob. 106IPCh. 21 - Prob. 107IPCh. 21 - Prob. 108IPCh. 21 - Prob. 109IPCh. 21 - Prob. 110IPCh. 21 - Prob. 111IPCh. 21 - Prob. 112IPCh. 21 - Prob. 113IPCh. 21 - Prob. 114IPCh. 21 - Prob. 115IPCh. 21 - Prob. 116CPCh. 21 - Prob. 117CPCh. 21 - Prob. 118CP
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