The structures of the aldol condensation products of each of the given compound in the problem 21.9 are to be drawn. Among these given aldehydes , the one that does not undergo aldol condensation is to be identified and the reason is to be explained. Concept Introduction: > In the presence of either acid or base, the two molecules of aldehydes or ketone that present alpha hydrogen are react and forms β-hydroxy carbonyl compounds, this reaction is known as aldol addition reaction. > The dehydration of aldol addition product results in the formation of α,β- unsaturated ketone or aldehyde. Such a reaction is known as aldol condensation reaction.

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 21.3, Problem 10P

Interpretation Introduction

Interpretation:

The structures of the aldol condensation products of each of the given compound in the problem 21.9 are to be drawn. Among these given aldehydes, the one that does not undergo aldol condensation is to be identified and the reason is to be explained.

Concept Introduction:
>
In the presence of either acid or base, the two molecules of aldehydes or ketone that present alpha hydrogen are react and forms β-hydroxy carbonyl compounds, this reaction is known as aldol addition reaction.
>
The dehydration of aldol addition product results in the formation of α,β- unsaturated ketone or aldehyde. Such a reaction is known as aldol condensation reaction.

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Done 11:14 ⚫ worksheets.beyondlabz.com 5 (a). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 6 5 (b). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 7 6. Are there any differences between the spectra you obtained in Beyond Labz and the predicted spectra? If so, what were the differences? <

2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity

Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 21.3, Problem 10P

Interpretation Introduction

Interpretation:

The structures of the aldol condensation products of each of the given compound in the problem 21.9 are to be drawn. Among these given aldehydes, the one that does not undergo aldol condensation is to be identified and the reason is to be explained.

Concept Introduction:
>
In the presence of either acid or base, the two molecules of aldehydes or ketone that present alpha hydrogen are react and forms β-hydroxy carbonyl compounds, this reaction is known as aldol addition reaction.
>
The dehydration of aldol addition product results in the formation of α,β- unsaturated ketone or aldehyde. Such a reaction is known as aldol condensation reaction.

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Answer 3

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 21.3, Problem 10P

Interpretation Introduction

Interpretation:

The structures of the aldol condensation products of each of the given compound in the problem 21.9 are to be drawn. Among these given aldehydes, the one that does not undergo aldol condensation is to be identified and the reason is to be explained.

Concept Introduction:
>
In the presence of either acid or base, the two molecules of aldehydes or ketone that present alpha hydrogen are react and forms β-hydroxy carbonyl compounds, this reaction is known as aldol addition reaction.
>
The dehydration of aldol addition product results in the formation of α,β- unsaturated ketone or aldehyde. Such a reaction is known as aldol condensation reaction.

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Check out a sample textbook solution

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Answer 4

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 21.3, Problem 10P

Interpretation Introduction