Bundle: Chemistry, 9th, Loose-Leaf + OWLv2 24-Months Printed Access Card
9th Edition
ISBN: 9781305367760
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
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Chapter 21, Problem 98IP
The ferrate ion, FeO42−, is such a powerful oxidizing agent that in acidic solution, aqueous ammonia is reduced to elemental nitrogen along with the formation of the iron(III) ion.
a. What is the oxidation state of iron in FeO42−, and what is the electron configuration of iron in this polyatornic ion?
b. lf 25.0 mL of a 0.243 M FeO42− solution is allowed to react with 55.0 mL of 1.45 M aqueous ammonia, what volume of nitrogen gas can form at 25°C and 1.50 atm?
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19.78 Write the products of the following sequences of reactions. Refer to your reaction road-
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roadmaps along with your new Chapter 19 roadmap for these.
(a)
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2. H₂O₂
3. H₂CrO4
4. SOCI₂
(b)
1. Cl₂/hv
2. KOLBU
3. H₂O, catalytic H₂SO4
4. H₂CrO4
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An alkene 5. EtOH
6.0.5 Equiv. NaOEt/EtOH
7. Mild H₂O
An alkane
1.0
2. (CH3)₂S
3. H₂CrO
(d)
(c)
4. Excess EtOH, catalytic H₂SO
OH
4. Mild H₂O*
5.0.5 Equiv. NaOEt/EtOH
An alkene 6. Mild H₂O*
A carboxylic
acid
7. Mild H₂O*
1. SOC₁₂
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5.1.0 Equiv. NaOEt
6.
NH₂
(e)
1. 0.5 Equiv. NaOEt/EtOH
2. Mild H₂O*
Br
(f)
i
H
An aldehyde
1. Catalytic NaOE/EtOH
2. H₂O*, heat
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5.1.0 Equiv. LDA
Br
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Chapter 21 Solutions
Bundle: Chemistry, 9th, Loose-Leaf + OWLv2 24-Months Printed Access Card
Ch. 21 - What two first-row transition metals have...Ch. 21 - Prob. 2RQCh. 21 - Prob. 3RQCh. 21 - Prob. 4RQCh. 21 - Prob. 5RQCh. 21 - Prob. 6RQCh. 21 - Prob. 7RQCh. 21 - Prob. 8RQCh. 21 - Prob. 9RQCh. 21 - Prob. 10RQ
Ch. 21 - Prob. 1ALQCh. 21 - Prob. 2ALQCh. 21 - Prob. 3ALQCh. 21 - Prob. 4ALQCh. 21 - Prob. 5QCh. 21 - Four different octahedral chromium coordination...Ch. 21 - Prob. 7QCh. 21 - Prob. 8QCh. 21 - Prob. 9QCh. 21 - Prob. 10QCh. 21 - Prob. 11QCh. 21 - Prob. 12QCh. 21 - Prob. 13QCh. 21 - Prob. 14QCh. 21 - Which of the following ligands are capable of...Ch. 21 - Prob. 16QCh. 21 - Prob. 17QCh. 21 - Prob. 18QCh. 21 - Prob. 19QCh. 21 - Prob. 20QCh. 21 - Prob. 21ECh. 21 - Prob. 22ECh. 21 - Prob. 23ECh. 21 - Prob. 24ECh. 21 - Prob. 25ECh. 21 - Prob. 26ECh. 21 - Prob. 27ECh. 21 - Prob. 28ECh. 21 - Prob. 29ECh. 21 - When an aqueous solution of KCN is added to a...Ch. 21 - Prob. 31ECh. 21 - A coordination compound of cobalt(III) contains...Ch. 21 - Prob. 33ECh. 21 - Prob. 34ECh. 21 - Prob. 35ECh. 21 - Prob. 36ECh. 21 - Prob. 37ECh. 21 - Give formulas for the following complex ions. a....Ch. 21 - Prob. 39ECh. 21 - Prob. 40ECh. 21 - Prob. 41ECh. 21 - Amino acids can act as ligands toward transition...Ch. 21 - Prob. 43ECh. 21 - Prob. 44ECh. 21 - Prob. 45ECh. 21 - Prob. 46ECh. 21 - Prob. 47ECh. 21 - Prob. 48ECh. 21 - Prob. 49ECh. 21 - Prob. 50ECh. 21 - Prob. 51ECh. 21 - Prob. 52ECh. 21 - The CrF64 ion is known to have four unpaired...Ch. 21 - Prob. 54ECh. 21 - Prob. 55ECh. 21 - The complex ion Fe(CN)63 is paramagnetic with one...Ch. 21 - Prob. 57ECh. 21 - Prob. 58ECh. 21 - Prob. 59ECh. 21 - Prob. 60ECh. 21 - The wavelength of absorbed electromagnetic...Ch. 21 - The complex ion NiCL42 has two unpaired electrons,...Ch. 21 - How many unpaired electrons are present in the...Ch. 21 - The complex ion PdCl42is diamagnetic. Propose a...Ch. 21 - Prob. 65ECh. 21 - Prob. 66ECh. 21 - Prob. 67ECh. 21 - Prob. 68ECh. 21 - Silver is sometimes found in nature as large...Ch. 21 - Prob. 70ECh. 21 - Prob. 71AECh. 21 - The compound cisplatin, Pt(NH3)2Cl2, has been...Ch. 21 - Prob. 73AECh. 21 - Prob. 74AECh. 21 - Prob. 75AECh. 21 - Prob. 76AECh. 21 - Prob. 77AECh. 21 - Name the following coordination compounds. a....Ch. 21 - Prob. 79AECh. 21 - Prob. 80AECh. 21 - Prob. 81AECh. 21 - Prob. 82AECh. 21 - Prob. 83CWPCh. 21 - Which of the following molecules exhibit(s)...Ch. 21 - Prob. 85CWPCh. 21 - The following table indicates the number of...Ch. 21 - Prob. 87CWPCh. 21 - Which of the following statement(s) is( are) true?...Ch. 21 - Consider the following complex ion, where A and B...Ch. 21 - Consider the pseudo-octahedral complex ion of...Ch. 21 - Prob. 91CPCh. 21 - Prob. 92CPCh. 21 - Chelating ligands often form more stable complex...Ch. 21 - Prob. 94CPCh. 21 - Prob. 95CPCh. 21 - Prob. 96CPCh. 21 - Sketch and explain the most likely crystal field...Ch. 21 - The ferrate ion, FeO42, is such a powerful...Ch. 21 - Ammonia and potassium iodide solutions are added...Ch. 21 - a. In the absorption spectrum of the complex ion...Ch. 21 - There are three salts that contain complex ions of...
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