Chemistry: The Central Science, Books a la Carte Plus MasteringChemistry with eText -- Access Card Package (13th Edition)
13th Edition
ISBN: 9780321934826
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
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Question
Chapter 21, Problem 92IE
(a)
Interpretation Introduction
To determine:
The alpha particles formed during the given time.
(b)
Interpretation Introduction
To determine:
The partial pressure of helium gas in the container.
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CHEMICAL KINETICS. Indicate the approximation methods for solving the rate equation.
TRANSMITTANCE
เบบ
Please identify the one structure below that is consistent with the 'H NMR and IR spectra
shown and draw its complete structure in the box below with the protons alphabetically labeled as
shown in the NMR spectrum and label the IR bands, including sp³C-H and sp2C-H stretch, indicated by
the arrows.
D
4000
OH
LOH
H₂C
CH3
OH
H₂C
OCH3
CH3
OH
3000
2000
1500
HAVENUMBERI-11
1000
LOCH3
Draw your structure below and label its equivalent protons according to the peak labeling that is used
in the NMR spectrum in order to assign the peaks.
Integrals indicate number of equivalent protons. Splitting patterns are: s=singlet, d=doublet, m-multiplet
8
3Hb s
m
1Hd s
3Hf
m 2Hcd
2Had
1He
鄙视
m
7
7
6
5
4
3
22
500
T
1
0
Relative Transmittance
0.995
0.99
0.985
0.98
Please draw the structure that is consistent with all the spectral data below in the box and
alphabetically label the equivalent protons in the structure (Ha, Hb, Hc ....) in order to assign all the
proton NMR peaks. Label the absorption bands in the IR spectrum indicated by the arrows.
INFRARED SPECTRUM
1
0.975
3000
2000
Wavenumber (cm-1)
1000
Structure with assigned H peaks
1
3
180 160 140 120
100
f1 (ppm)
80 60
40
20
0
C-13 NMR
note that there are 4
peaks between 120-140ppm
Integral values equal
the number of
equivalent protons
10.0
9.0
8.0
7.0
6.0
5.0
4.0
3.0
2.0
1.0
0.0
fl (ppm)
Chapter 21 Solutions
Chemistry: The Central Science, Books a la Carte Plus MasteringChemistry with eText -- Access Card Package (13th Edition)
Ch. 21.1 - Prob. 21.1.1PECh. 21.1 - Prob. 21.1.2PECh. 21.1 - Prob. 21.2.1PECh. 21.1 - Prob. 21.2.2PECh. 21.2 - Which aqueous solution will have the lowest...Ch. 21.2 - Prob. 21.3.2PECh. 21.3 - Prob. 21.4.1PECh. 21.3 - Prob. 21.4.2PECh. 21.4 - Prob. 21.5.1PECh. 21.4 - Practice Exercise 2
Camphor (C10 H16 O) melts at...
Ch. 21.4 - Prob. 21.6.1PECh. 21.4 - Prob. 21.6.2PECh. 21.4 - Prob. 21.7.1PECh. 21.4 - Rank the contents of the following containers in...Ch. 21.6 - Prob. 21.8.1PECh. 21.6 - Consider two ionic solids, both composed of singly...Ch. 21 - Prob. 1DECh. 21 - Would you expect stearic acid, CH3 (CH2)16COOH, to...Ch. 21 - 13.43 Calculate the morality of the following...Ch. 21 - Commercial aqueous nitric acid has a density of...Ch. 21 - Prob. 4ECh. 21 - Prob. 5ECh. 21 - Prob. 6ECh. 21 - Prob. 7ECh. 21 - If the experiment in Figure 14.2 is run for 60 s,...Ch. 21 - Prob. 9ECh. 21 - Indicate the principal type of solute-solvent...Ch. 21 - When ammonium chloride dissolves in water, the...Ch. 21 - Prob. 12ECh. 21 - KBr is relatively soluble in water, yet its...Ch. 21 - The solubility of MnSO4 . H2 O in water at 20 C is...Ch. 21 - Prob. 15ECh. 21 - Prob. 16ECh. 21 - Prob. 17ECh. 21 - Prob. 18ECh. 21 - Prob. 19ECh. 21 - Prob. 20ECh. 21 - Prob. 21ECh. 21 - Indicate whether each statement is true or false:...Ch. 21 - 13.36 Indicate whether each statement is true or...Ch. 21 - Prob. 24ECh. 21 - Prob. 25ECh. 21 - Prob. 26ECh. 21 - Prob. 27ECh. 21 - Prob. 28ECh. 21 - Prob. 29ECh. 21 - Calculate the molality of each of the following...Ch. 21 - (a) What is the molality of a solution formed by...Ch. 21 - Prob. 32ECh. 21 - Prob. 33ECh. 21 - Prob. 34ECh. 21 - The density of toluene (C7H8) is 0.867 g\mL, and...Ch. 21 - Calculate the number of moles of solute present in...Ch. 21 - Prob. 37ECh. 21 - Prob. 38ECh. 21 - Describe how you would prepare each of the...Ch. 21 - Prob. 40ECh. 21 - Prob. 41ECh. 21 - Prob. 42ECh. 21 - Prob. 43ECh. 21 - Prob. 44ECh. 21 - Prob. 45ECh. 21 - Prob. 46ECh. 21 - Prob. 47ECh. 21 - Prob. 48ECh. 21 - (a) Calculate the vapor pressure of water above a...Ch. 21 - Prob. 50ECh. 21 - Prob. 51ECh. 21 - Prob. 52ECh. 21 - Prob. 53ECh. 21 - Using data from Table 13.3, calculate the freezing...Ch. 21 - Prob. 55ECh. 21 - Prob. 56ECh. 21 - Prob. 57ECh. 21 - Prob. 58ECh. 21 - Prob. 59ECh. 21 - Prob. 60ECh. 21 - Prob. 61ECh. 21 - The osmotic pressure of a 0.010 M aqueous solution...Ch. 21 - Prob. 63ECh. 21 - (a) Do colloids made only of gases exist? Why or...Ch. 21 - Prob. 65ECh. 21 - An “emulsifying agent” is a compound that helps...Ch. 21 - Aerosols are important components of the...Ch. 21 - Prob. 68ECh. 21 - Soaps consist of compounds such as sodium state,...Ch. 21 - Most fish need at least 4 ppm dissolved O2 in...Ch. 21 - The presence of the radioactive gas radon (Rn) in...Ch. 21 - Prob. 72AECh. 21 - Prob. 73AECh. 21 - The maximum allowable concentration of lead in...Ch. 21 - Prob. 75AECh. 21 - Prob. 76AECh. 21 - Prob. 77AECh. 21 - Prob. 78AECh. 21 - The normal boiling point of ethanol, is 78.4 0C....Ch. 21 - Prob. 80AECh. 21 - Prob. 81AECh. 21 - Prob. 82AECh. 21 - Prob. 83AECh. 21 - Prob. 84AECh. 21 - Prob. 85AECh. 21 - Prob. 86AECh. 21 - Prob. 87AECh. 21 - Prob. 88AECh. 21 - Prob. 89IECh. 21 - Prob. 90IECh. 21 - Prob. 91IECh. 21 - Prob. 92IECh. 21 - Prob. 93IECh. 21 - Prob. 94IE
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