Whether the given compound is an alkane , alkene , alkyne , aromatic hydrocarbon, alcohol, ether, aldehyde , ketone , carboxylic acid , ester, or amine , and to write the name of the compound.

Question

16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してし

Answer 1

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 21, Problem 89E

(a)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(b)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(c)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(d)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(e)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(f)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

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16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してし

3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing mechanism below, but make sure to draw the product of each proposed step (3 points). + En CN CN

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Answer 2

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 21, Problem 89E

(a)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(b)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(c)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(d)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(e)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(f)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

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Answer 3

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 21, Problem 89E

(a)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(b)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(c)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(d)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(e)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(f)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

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Answer 4

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 21, Problem 89E

(a)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(b)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(c)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(d)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(e)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(f)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

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Answer 5

Chapter 21, Problem 89E

(a)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(b)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(c)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(d)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(e)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

(f)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

Answer 6

Chapter 21, Problem 89E

(a)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

Answer 7

Chapter 21, Problem 89E

(a)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

Answer 8

(b)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

Answer 9

(b)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

Answer 10

(c)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

Answer 11

(c)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

Answer 12

(d)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

Answer 13

(d)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

Answer 14

(e)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

Answer 15

(e)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

Answer 16

(f)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

Answer 17

(f)

Interpretation Introduction

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

Answer 18

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Answer 19

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Answer 29

Ch. 21 - Prob. 1SAQ Ch. 21 - Prob. 2SAQ Ch. 21 - Prob. 3SAQ Ch. 21 - Prob. 4SAQ Ch. 21 - Prob. 5SAQ Ch. 21 - Q6. Name the compound: a) 4-methyl-2-pentyne b)...Ch. 21 - Q7. Determine the product of the...Ch. 21 - Prob. 8SAQ Ch. 21 - Q9. Which compound is an ester? a) CH3—CH2—0—CH3 ...Ch. 21 - Prob. 10SAQ

Whether the given compound is an alkane , alkene , alkyne , aromatic hydrocarbon, alcohol, ether, aldehyde , ketone , carboxylic acid , ester, or amine , and to write the name of the compound.

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To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

To identify: Whether the given compound is an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and to write the name of the compound.

Chapter 21 Solutions