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10th Edition
ISBN: 9780357096949
Author: Kotz
Publisher: CENGAGE C
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Chapter 21, Problem 75PS
Interpretation Introduction
Interpretation: The halogen which has the highest bond dissociation enthalpy is to be stated.
Concept introduction: The
As number of bond increase, length gets shorter and bond energy increases.
Therefore,
Nitrogen has a triple bond, which takes a lot of energy to break and is pretty much inert.
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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10
Consider the following reaction:
CH3OH(g)
CO(g) + 2H2(g)
(Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.)
Part A
Calculate AG for this reaction at 25 °C under the following conditions:
PCH₂OH
Pco
PH2
0.815 atm
=
0.140 atm
0.170 atm
Express your answer in kilojoules to three significant figures.
Ο ΑΣΦ
AG = -150
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kJ
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Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship:
AGrxn = AGrxn + RTInQ,
AGxn+RTInQ,
where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a
is the reaction quotient.
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Chapter 21 Solutions
CHEMISTRY+CHEM...(LL)-W/ACCESS >CUSTOM<
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