The structures of the chiral isomers of the given complex are to be drawn. Concept Information: Isomerism is the phenomenon that is exhibited by compounds having different structural formula of the atoms in space with the same chemical formula. Chirality is the term used for compounds that are mirror images of each other and are non-superimposable. Geometrical isomerism is the form of the stereoisomerism that atoms or group of atoms show when they have different spatial arrangements.

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Chapter 21, Problem 74RQ

Interpretation Introduction

Interpretation:

The structures of the chiral isomers of the given complex are to be drawn.

Concept Information:

Isomerism is the phenomenon that is exhibited by compounds having different structural formula of the atoms in space with the same chemical formula.

Chirality is the term used for compounds that are mirror images of each other and are non-superimposable.

Geometrical isomerism is the form of the stereoisomerism that atoms or group of atoms show when they have different spatial arrangements.

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Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**

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