The structure of product formed by the reaction of diethyl malonate with each of the reagents is to be drawn. Concept introduction: The reaction of diethyl malonate with sodium ethoxide and alkyl halide results in the formation of alkylated malonate ester. Sodium ethoxide extract α -hydrogen atom present between the two carbonyl groups and generate negative charge on carbon atom. It acts as a nucleophile and attacks the alkyl part of alkyl halide and form alkylated malonate ester. The basic hydrolysis of ester involves cleavage of − O − R bond and formation of carboxylic acid and alcohol. The decarboxylation of compound involves removal of CO 2 .

Question

Want to see the full answer?

Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 21, Problem 42P

Interpretation Introduction

Interpretation:

The structure of product formed by the reaction of diethyl malonate with each of the reagents is to be drawn.

Concept introduction:

The reaction of diethyl malonate with sodium ethoxide and alkyl halide results in the formation of alkylated malonate ester.

Sodium ethoxide extract α-hydrogen atom present between the two carbonyl groups and generate negative charge on carbon atom. It acts as a nucleophile and attacks the alkyl part of alkyl halide and form alkylated malonate ester.

The basic hydrolysis of ester involves cleavage of −O−R

bond and formation of carboxylic acid and alcohol. The decarboxylation of compound involves removal of CO2.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Intercalation compounds have their sheetsa) negatively charged.b) positively charged.

Indicate whether the following two statements are correct or not:- Polythiazine, formed by N and S, does not conduct electricity- Carbon can have a specific surface area of 3000 m2/g

Indicate whether the following two statements are correct or not:- The S8 heterocycle is the origin of a family of compounds- Most of the elements that give rise to stable heterocycles belong to group d.

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 21, Problem 42P

Interpretation Introduction

Interpretation:

The structure of product formed by the reaction of diethyl malonate with each of the reagents is to be drawn.

Concept introduction:

The reaction of diethyl malonate with sodium ethoxide and alkyl halide results in the formation of alkylated malonate ester.

Sodium ethoxide extract α-hydrogen atom present between the two carbonyl groups and generate negative charge on carbon atom. It acts as a nucleophile and attacks the alkyl part of alkyl halide and form alkylated malonate ester.

The basic hydrolysis of ester involves cleavage of −O−R

bond and formation of carboxylic acid and alcohol. The decarboxylation of compound involves removal of CO2.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 21, Problem 42P

Interpretation Introduction

Interpretation:

The structure of product formed by the reaction of diethyl malonate with each of the reagents is to be drawn.

Concept introduction:

The reaction of diethyl malonate with sodium ethoxide and alkyl halide results in the formation of alkylated malonate ester.

Sodium ethoxide extract α-hydrogen atom present between the two carbonyl groups and generate negative charge on carbon atom. It acts as a nucleophile and attacks the alkyl part of alkyl halide and form alkylated malonate ester.

The basic hydrolysis of ester involves cleavage of −O−R

bond and formation of carboxylic acid and alcohol. The decarboxylation of compound involves removal of CO2.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 21, Problem 42P

Interpretation Introduction