The geometrical isomers of the given compounds are to be determined. Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom. In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other. To determine: The geometrical isomers of Co ( C 2 O 4 ) 2 ( H 2 O ) 2 − .

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Answer 1

Question

Chapter 21, Problem 39E

(a)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Co(C2O4)2(H2O)2− .

(b)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Pt(NH3)4I22+ .

(c)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Ir(NH3)3(Cl)3 .

(d)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Cr(en)(NH3)2I2+ .

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1. Answer the questions about the following reaction: (a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this reaction. Be sure to include any relevant stereochemistry in the product structure. + SK F Br + (b) In which solvent would this reaction proceed the fastest (Circle one) Methanol Acetone (c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest other products that are formed? Draw them in the box provided.

3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in the reactant before being able to draw the arrows corresponding to product formation. A. B. Rearrangement ΘΗ

2. Draw the arrows required to make the following reactions occur. Please ensure your arrows point from exactly where you want to exactly where you want. If it is unclear from where arrows start or where they end, only partial credit will be given. Note: You may need to draw in lone pairs before drawing the arrows. A. B. H-Br 人 C Θ CI H Cl Θ + Br O

Answer 2

Question

Chapter 21, Problem 39E

(a)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Co(C2O4)2(H2O)2− .

(b)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Pt(NH3)4I22+ .

(c)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Ir(NH3)3(Cl)3 .

(d)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Cr(en)(NH3)2I2+ .

Expert Solution & Answer

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Answer 3

Question

Chapter 21, Problem 39E

(a)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Co(C2O4)2(H2O)2− .

(b)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Pt(NH3)4I22+ .

(c)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Ir(NH3)3(Cl)3 .

(d)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Cr(en)(NH3)2I2+ .

Expert Solution & Answer

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Answer 4

Question

Chapter 21, Problem 39E

(a)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Co(C2O4)2(H2O)2− .

(b)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Pt(NH3)4I22+ .

(c)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Ir(NH3)3(Cl)3 .

(d)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Cr(en)(NH3)2I2+ .

Expert Solution & Answer

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Answer 5

Chapter 21, Problem 39E

(a)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Co(C2O4)2(H2O)2− .

(b)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Pt(NH3)4I22+ .

(c)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Ir(NH3)3(Cl)3 .

(d)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Cr(en)(NH3)2I2+ .

Answer 6

Chapter 21, Problem 39E

(a)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Co(C2O4)2(H2O)2− .

Answer 7

Chapter 21, Problem 39E

(a)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Co(C2O4)2(H2O)2− .

Answer 8

(b)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Pt(NH3)4I22+ .

Answer 9

(b)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Pt(NH3)4I22+ .

Answer 10

(c)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Ir(NH3)3(Cl)3 .

Answer 11

(c)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Ir(NH3)3(Cl)3 .

Answer 12

(d)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Cr(en)(NH3)2I2+ .

Answer 13

(d)

Interpretation Introduction

Interpretation: The geometrical isomers of the given compounds are to be determined.

Concept introduction: The geometrical isomer or cis-trans isomers are the isomers with different spatial arrangements of the groups attached to the central atom.

In cis isomer, two of the liked groups are placed adjacent to each other. While in trans isomers, the two liked groups are placed opposite to each other.

To determine: The geometrical isomers of Cr(en)(NH3)2I2+ .

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 21 - What two first-row transition metals have...Ch. 21 - Prob. 2RQ Ch. 21 - Prob. 3RQ Ch. 21 - Prob. 4RQ Ch. 21 - Prob. 5RQ Ch. 21 - Prob. 6RQ Ch. 21 - Prob. 7RQ Ch. 21 - Prob. 8RQ Ch. 21 - Prob. 9RQ Ch. 21 - Prob. 10RQ

Solution Summary: The author explains that the geometrical isomers of the given compounds are to be determined.

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