(a)
Interpretation:
The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.
(b)
Interpretation:
The importance of introducing benzyl group in chloramine has to be explained for the conversion of B to C.
(c)
Interpretation:
The reagent has to be proposed for the conversion of D to E for removing benzyl group.
Concept introduction:
Hydrogenolysis:
Metal catalyst gives the corresponding amine or alcohol.
(d)
Interpretation:
The reagent has to be proposed for the conversion of E to bidisomide.
(e)
Interpretation:
The possible stereoisomer’s has to be shown if the product is chiral.
Concept introduction:
Chiral:
A molecule is non superimposable on its mirror image is called chiral molecule. Four different atoms attached to a carbon atom is called chiral molecule.
Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.
Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.
Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.
Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.
Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.
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Chapter 21 Solutions
EP ORGANIC CHEMISTRY-OWL V2 ACCESS
- The kinetics of a gas phase reaction of the form A → Products results in a rate constant of 0.00781 M/min. For this reaction, the initial concentration of A is 0.501 M. How many minutes will it take for the concentration of A to reach 0.144 Marrow_forwardWhat is the rate for the second order reaction A → Products when [A] = 0.256 M? (k = 0.761 M⁻¹s⁻¹)arrow_forwardFor reaction N2(g) + O2(g) --> 2NO(g) Write the rate of the reaction in terms of change of NO.arrow_forward
- What is the name of the major product formed during the reaction between benzoyl chloride and phenol? benzyl ester O phenyl benzoate ○ cyclopentanoate ○ benzyl phenoate ○ benzenecarboxylic acidarrow_forwardProvide the proper IUPAC or common name for the following compound. Dashes, commas, and spaces must be used correctly.arrow_forwardProvide the proper IUPAC name (only) for the following compound. Dashes, commas, and spaces must be used correctly. HO. OHarrow_forward
- Question 2 0/1 pts Provide the proper IUPAC name only for the following compound. Dashes, commas, and spaces must be used correctly. HO CH 3 1-methyl-1-cyclohexanecarboxylic acidarrow_forwardPlease assign all the carbons for C-NMR and hydrogen for H-NMR. Please if I can get that less than hourarrow_forwardAssign these peaks spectrum ( H-NMR and C-NMR)arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage LearningIntroduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
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