CHEM 212:STUDENT SOLUTION MANUAL
CHEM 212:STUDENT SOLUTION MANUAL
8th Edition
ISBN: 9781260304473
Author: SILBERBERG
Publisher: MCGRAW-HILL CUSTOM PUBLISHING
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Chapter 21, Problem 21.2P
Interpretation Introduction

Interpretation:

The reason that why should electrochemical process involves redox reaction has to be identified.

Concept Introduction:

Oxidation: If electrons are moved from a species during a chemical reaction. The species whose electrons are removed is said to be oxidized.

Reduction: If electrons are gained to a species during a chemical reaction. The species which gets electrons are said to be reduced.

Redox reaction: It occurs when oxidation and reduction takes place at the same time in a chemical reaction.

Electrochemistry: It deals with the study of relationship between chemical change and electrical work.

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2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity
Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**
11:14 ... worksheets.beyondlabz.com 3. To check your predictions, click this link for Interpreting NMR Spectra 1. You will see a list of all the - compounds in the spectra library in alphabetical order by IUPAC name. Hovering over a name in the list will show the structure on the chalkboard. The four buttons on the top of the Spectra tab in the tray are used to select the different spectroscopic techniques for the selected compound. Make sure the NMR button has been selected. 4. Scroll through the list of names to find the names for the two compounds you have been given and click on the name to display the NMR spectrum for each. In the NMR tables below, list the chemical shift, the splitting, and the number of hydrogens associated with each peak for each compound. Compare your answers to your predictions. **Not all slots must be filled** Peak Chemical Shift (d) Multiplicity 1 2 3 4 5

Chapter 21 Solutions

CHEM 212:STUDENT SOLUTION MANUAL

Ch. 21.4 - Prob. 21.6AFPCh. 21.4 - Prob. 21.6BFPCh. 21.4 - Prob. 21.7AFPCh. 21.4 - Prob. 21.7BFPCh. 21.4 - Prob. 21.8AFPCh. 21.4 - Prob. 21.8BFPCh. 21.7 - The most ionic and least ionic of the common...Ch. 21.7 - Prob. 21.9BFPCh. 21.7 - Prob. 21.10AFPCh. 21.7 - Prob. 21.10BFPCh. 21.7 - Prob. 21.11AFPCh. 21.7 - Prob. 21.11BFPCh. 21.7 - In the final steps of the ETC, iron and copper...Ch. 21.7 - Prob. B21.2PCh. 21 - Prob. 21.1PCh. 21 - Prob. 21.2PCh. 21 - Prob. 21.3PCh. 21 - Water is used to balance O atoms in the...Ch. 21 - Prob. 21.5PCh. 21 - Prob. 21.6PCh. 21 - Prob. 21.7PCh. 21 - Prob. 21.8PCh. 21 - Prob. 21.9PCh. 21 - Prob. 21.10PCh. 21 - Prob. 21.11PCh. 21 - Prob. 21.12PCh. 21 - Prob. 21.13PCh. 21 - Prob. 21.14PCh. 21 - Prob. 21.15PCh. 21 - Prob. 21.16PCh. 21 - Prob. 21.17PCh. 21 - Prob. 21.18PCh. 21 - Prob. 21.19PCh. 21 - Prob. 21.20PCh. 21 - Aqua regia, a mixture of concentrated HNO3 and...Ch. 21 - Consider the following general voltaic...Ch. 21 - Why does a voltaic cell not operate unless the two...Ch. 21 - Prob. 21.24PCh. 21 - Prob. 21.25PCh. 21 - Prob. 21.26PCh. 21 - Consider the following voltaic cell: In which...Ch. 21 - Consider the following voltaic cell: In which...Ch. 21 - Prob. 21.29PCh. 21 - Prob. 21.30PCh. 21 - A voltaic cell is constructed with an Fe/Fe2+...Ch. 21 - Prob. 21.32PCh. 21 - Prob. 21.33PCh. 21 - Prob. 21.34PCh. 21 - Prob. 21.35PCh. 21 - What does a negative indicate about a redox...Ch. 21 - Prob. 21.37PCh. 21 - In basic solution, Se2− and ions react...Ch. 21 - Prob. 21.39PCh. 21 - Prob. 21.40PCh. 21 - Use the emf series (Appendix D) to arrange each...Ch. 21 - Prob. 21.42PCh. 21 - Prob. 21.43PCh. 21 - Prob. 21.44PCh. 21 - Prob. 21.45PCh. 21 - Prob. 21.46PCh. 21 - Prob. 21.47PCh. 21 - Prob. 21.48PCh. 21 - Prob. 21.49PCh. 21 - Prob. 21.50PCh. 21 - Prob. 21.51PCh. 21 - Prob. 21.52PCh. 21 - Prob. 21.53PCh. 21 - Prob. 21.54PCh. 21 - Prob. 21.55PCh. 21 - Prob. 21.56PCh. 21 - Prob. 21.57PCh. 21 - Prob. 21.58PCh. 21 - Prob. 21.59PCh. 21 - Prob. 21.60PCh. 21 - Prob. 21.61PCh. 21 - Prob. 21.62PCh. 21 - Prob. 21.63PCh. 21 - Prob. 21.64PCh. 21 - Prob. 21.65PCh. 21 - Prob. 21.66PCh. 21 - Prob. 21.67PCh. 21 - Prob. 21.68PCh. 21 - Prob. 21.69PCh. 21 - Prob. 21.70PCh. 21 - Prob. 21.71PCh. 21 - Prob. 21.72PCh. 21 - Prob. 21.73PCh. 21 - Prob. 21.74PCh. 21 - Prob. 21.75PCh. 21 - Prob. 21.76PCh. 21 - Prob. 21.77PCh. 21 - Prob. 21.78PCh. 21 - Prob. 21.79PCh. 21 - Prob. 21.80PCh. 21 - Prob. 21.81PCh. 21 - Consider the following general electrolytic...Ch. 21 - Prob. 21.83PCh. 21 - Prob. 21.84PCh. 21 - Prob. 21.85PCh. 21 - Prob. 21.86PCh. 21 - In the electrolysis of molten NaBr: What product...Ch. 21 - Prob. 21.88PCh. 21 - Prob. 21.89PCh. 21 - Prob. 21.90PCh. 21 - Prob. 21.91PCh. 21 - Prob. 21.92PCh. 21 - Prob. 21.93PCh. 21 - Prob. 21.94PCh. 21 - Prob. 21.95PCh. 21 - Prob. 21.96PCh. 21 - Prob. 21.97PCh. 21 - Write a balanced half-reaction for the product...Ch. 21 - Prob. 21.99PCh. 21 - Prob. 21.100PCh. 21 - Prob. 21.101PCh. 21 - Prob. 21.102PCh. 21 - Prob. 21.103PCh. 21 - Prob. 21.104PCh. 21 - Prob. 21.105PCh. 21 - Prob. 21.106PCh. 21 - Prob. 21.107PCh. 21 - Prob. 21.108PCh. 21 - Prob. 21.109PCh. 21 - Prob. 21.110PCh. 21 - Prob. 21.111PCh. 21 - Prob. 21.112PCh. 21 - Prob. 21.113PCh. 21 - Prob. 21.114PCh. 21 - Prob. 21.115PCh. 21 - Prob. 21.116PCh. 21 - Prob. 21.117PCh. 21 - Prob. 21.118PCh. 21 - Prob. 21.119PCh. 21 - Prob. 21.120PCh. 21 - To examine the effect of ion removal on cell...Ch. 21 - Prob. 21.122PCh. 21 - Prob. 21.123PCh. 21 - Prob. 21.124PCh. 21 - Prob. 21.125PCh. 21 - Prob. 21.126PCh. 21 - Commercial electrolytic cells for producing...Ch. 21 - Prob. 21.129PCh. 21 - Prob. 21.130PCh. 21 - The following reactions are used in...Ch. 21 - Prob. 21.132PCh. 21 - Prob. 21.133PCh. 21 - Prob. 21.134PCh. 21 - Prob. 21.135PCh. 21 - If the Ecell of the following cell is 0.915 V,...Ch. 21 - Prob. 21.137PCh. 21 - Prob. 21.138PCh. 21 - Prob. 21.139PCh. 21 - Prob. 21.140PCh. 21 - Prob. 21.141PCh. 21 - Prob. 21.142PCh. 21 - Prob. 21.143PCh. 21 - Prob. 21.144PCh. 21 - Prob. 21.145PCh. 21 - Prob. 21.146PCh. 21 - Prob. 21.147PCh. 21 - Both Ti and V are reactive enough to displace H2...Ch. 21 - For the reaction ∆G° = 87.8 kJ/mol Identity the...Ch. 21 - Two voltaic cells are to be joined so that one...Ch. 21 - Prob. 21.152PCh. 21 - Prob. 21.153P
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