(a)
Interpretation: The movement of electrons needs to be identified if magnesium bars are connected electrically to iron pipes.
Concept Introduction: The movement of electrons in any electrolytic reaction depends on the
(b)
Interpretation: The average flow of current between Mg and Fe in 8.5 years needs to be estimated.
Concept Introduction: The current flowing in a system is related to the mass and time required for the flow as follows:
Here, I is current, t is time, w is mass deposited,
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CHEMISTRY MOLECULAR NATURE OF MATTER
- An aqueous solution of an unknown salt of gold is electrolyzed by a current of 2.75 amps for 3.39 hours. The electroplating is carried out with an efficiency of 93.0%, resulting in a deposit of 21.221 g of gold. a How many faradays are required to deposit the gold? b What is the charge on the gold ions (based on your calculations)?arrow_forwardChlorine, Cl2, is produced commercially by the electrolysis of aqueous sodium chloride. The anode reaction is 2Cl(aq)Cl2(g)+2e How long will it take to produce 2.00 kg of chlorine if the current is 5.00 102 A?arrow_forwardThe mass of three different metal electrodes, each from a different galvanic cell, were determined before and after the current generated by the oxidation-reduction reaction in each cell was allowed to flow for a few minutes. The first metal electrode, given the label A, was found to have increased in mass; the second metal electrode, given the label B, did not change in mass; and the third metal electrode, given the label C, was found to have lost mass. Make an educated guess as to which electrodes were active and which were inert electrodes, and which were anode(s) and which were the cathode(s).arrow_forward
- Assume the following electrochemical cell simulates the galvanic cell formed by copper and zinc in seawater at pH 7.90 and 25 C. Zn | Zn(OH)2(s) | OH(aq) || Cu(OH)2(s) | Cu(s) a. Write a balanced equation for the reaction that occurs at the cathode. b. Write a balanced equation for the reaction that occurs at the anode. c. Write a balanced chemical equation for the overall reaction. d. Determine the potential (in volts) of the cell.arrow_forwardAn electrolysis experiment is performed to determine the value of the Faraday constant (number of coulombs per mole of electrons). In this experiment, 28.8 g of gold is plated out from a AuCN solution by running an electrolytic cell for two hours with a current of 2.00 A. What is the experimental value obtained for the Faraday Constant?arrow_forwardElectrolysis of a solution of CuSO4(aq) to give copper metal is carried out using a current of 0.66 A. How long should electrolysis continue to produce 0.50 g of copper?arrow_forward
- An aqueous solution of an unknown salt of vanadium is electrolyzed by a current of 2.50 amps for 1.90 hours. The electroplating is carried out with an efficiency of 95.0%, resulting in a deposit of 2.850 g of vanadium. a How many faradays are required to deposit the vanadium? b What is the charge on the vanadium ions (based on your calculations)?arrow_forwardCalcium metal can be obtained by the direct electrolysis of molten CaCl2, at a voltage of 3.2 V. (a) How many joules of electrical energy are required to obtain 12.0 1b of calcium? (b) What is the cost of the electrical energy obtained in (a) if electrical energy is sold at the rate of nine cents per kilowatt hour?arrow_forwardHydrazine, N2H4, has been proposed as the fuel in a fuel cell in which oxygen is the oxidizing agent. The reactions are N2H4(aq) + 4 OH(aq) N2(g) + 4 H2O() + 4e O2(g) + 2 H2O() + 4e 4 OH(aq) (a) Which reaction occurs at the anode and which at thecathode? (b) What is the overall cell reaction? (c) If the cell is to produce 0.50 A of current for 50.0 h, calculate what mass in grams of hydrazine must be present. (d) Calculate what mass (g) of O2 must be available to reactwith the mass of N2H4 determined in part (c).arrow_forward
- A voltaic cell is constructed in which one half-cell consists of a silver wire in an aqueous solution of AgNO3.The other half cell consists of an inert platinum wire in an aqueous solution containing Fe2+(aq) and Fe3+(aq). (a) Calculate the cell potential, assuming standard conditions. (b) Write the net ionic equation for the reaction occurring in the cell. (c) Which electrode is the anode and which is the cathode? (d) If [Ag+] is 0.10 M, and [Fe2+] and [Fe3+] are both 1.0 M, what is the cell potential? Is the net cell reaction still that used in part (a)? If not, what is the net reaction under the new conditions?arrow_forwardthe electroplating of a silver spoon, the spoon acts as thecathode and a piece of pure silver as the anode. Both dipinto a solution of silver cyanide (AgCN). Suppose that acurrent of 1.5 A is passed through such a cell for 22 minutesand that the spoon has a surface area of 16cm2. Calculatethe average thickness of the silver layer deposited onthe spoon, taking the density of silver to be 10.5gcm3.arrow_forwardA factory wants to produce 1.00 103 kg barium from the electrolysis of molten barium chloride. What current must be applied for 4.00 h to accomplish this?arrow_forward
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