Principles of Modern Chemistry
8th Edition
ISBN: 9781305079113
Author: David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher: Cengage Learning
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Indicate how to obtain 2-metilbencimidazol from 1,2-diaminobenzene.
break down both reactions shown and explain it correctly using the bromonium ion mechanism, instead of the (disproven) carbocation-based mechanism.
Indicate how from 1,2-diaminobenzene to obtain 1-metilbenzotriazol.
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- -C = C - C - + Br₂ + I" -> -C-C-c -C = C -C- + Br² + I₂ -C=C Br I + Brū + Iz -7- C - C-C- I Br Mechanism; - C = c - c - + Br - Br > - C-c-c- Br -C-C-C- + 1 - - -Ċ-Ċ'-c' - Br Br Iarrow_forwardWrite the mechanism of the esterification reaction (please show the mechanism included line pairs and arrows)arrow_forwardHow do I break down the reaction shown on the chalkboard and explain it correctly using the bromonium ion mechanism, instead of the (disproven) carbocation-based mechanismarrow_forward
- ¿Qué the product is obtained from tetraethoxypropano and hidrazina?. Indicate the reason why the corresponding dial is used.arrow_forwardIf CH3COCH2CH(OCH3)2 is reacted with hydrazine, two isomeric products are formed. Indicate their structures and the major product.arrow_forwardIs it possible to obtain addition derivatives to nitrogen in position 2 of pyrazoles by reaction with electrophilic agents? Reason for this.arrow_forward
- Starting from 1,3-dicarbonyl derivatives to obtain isooxazoles and isothiazoles. Indicate whether synthetic methods exist.arrow_forwardIn the synthesis of benzotriazole, adding NaNO2 heats the solution. State the reason.arrow_forwardIndicate the products obtained by treating benzotriazole with dimethyl sulfate or methyl iodide in a basic medium.arrow_forward
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