The given diagrams are to be labeled as low spin, high spin, or cannot tell with proper explanation. Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to presence of maximum unpaired electrons in lower energy t 2g orbitals and higher energy orbitals. Strong field ligand that has large crystal field splitting energy gives low spin due to presence of maximum paired electrons in lower energy t 2g orbitals. To label: The given diagram as low spin, high spins, or cannot tell with proper explanation.

Question

For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂

Answer 1

Question

Chapter 21, Problem 10Q

(a)

Interpretation Introduction

Interpretation: The given diagrams are to be labeled as low spin, high spin, or cannot tell with proper explanation.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to presence of maximum paired electrons in lower energy t2g orbitals.

To label: The given diagram as low spin, high spins, or cannot tell with proper explanation.

(b)

Interpretation Introduction

Interpretation: The given diagrams are to be labeled as low spin, high spin, or cannot tell with proper explanation.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to presence of maximum paired electrons in lower energy t2g orbitals.

To label: The given diagram as low spin, high spins, or cannot tell with proper explanation.

(c)

Interpretation Introduction

Interpretation: The given diagrams are to be labeled as low spin, high spin, or cannot tell with proper explanation.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to presence of maximum paired electrons in lower energy t2g orbitals.

To label: The given diagram as low spin, high spins, or cannot tell with proper explanation.

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For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂

Given the reaction R + Q → P, indicate the rate law with respect to R, with respect to P and with respect to P.

Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.

Answer 2

Question

Chapter 21, Problem 10Q

(a)

Interpretation Introduction

Interpretation: The given diagrams are to be labeled as low spin, high spin, or cannot tell with proper explanation.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to presence of maximum paired electrons in lower energy t2g orbitals.

To label: The given diagram as low spin, high spins, or cannot tell with proper explanation.

(b)

Interpretation Introduction

Interpretation: The given diagrams are to be labeled as low spin, high spin, or cannot tell with proper explanation.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to presence of maximum paired electrons in lower energy t2g orbitals.

To label: The given diagram as low spin, high spins, or cannot tell with proper explanation.

(c)

Interpretation Introduction

Interpretation: The given diagrams are to be labeled as low spin, high spin, or cannot tell with proper explanation.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to presence of maximum paired electrons in lower energy t2g orbitals.

To label: The given diagram as low spin, high spins, or cannot tell with proper explanation.

Expert Solution & Answer

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Answer 3

Question

Chapter 21, Problem 10Q

(a)

Interpretation Introduction

Interpretation: The given diagrams are to be labeled as low spin, high spin, or cannot tell with proper explanation.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to presence of maximum paired electrons in lower energy t2g orbitals.

To label: The given diagram as low spin, high spins, or cannot tell with proper explanation.

(b)

Interpretation Introduction

Interpretation: The given diagrams are to be labeled as low spin, high spin, or cannot tell with proper explanation.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to presence of maximum paired electrons in lower energy t2g orbitals.

To label: The given diagram as low spin, high spins, or cannot tell with proper explanation.

(c)

Interpretation Introduction

Interpretation: The given diagrams are to be labeled as low spin, high spin, or cannot tell with proper explanation.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to presence of maximum paired electrons in lower energy t2g orbitals.

To label: The given diagram as low spin, high spins, or cannot tell with proper explanation.

Expert Solution & Answer

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Answer 4

Question

Chapter 21, Problem 10Q

(a)

Interpretation Introduction

Interpretation: The given diagrams are to be labeled as low spin, high spin, or cannot tell with proper explanation.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to presence of maximum paired electrons in lower energy t2g orbitals.

To label: The given diagram as low spin, high spins, or cannot tell with proper explanation.

(b)

Interpretation Introduction

Interpretation: The given diagrams are to be labeled as low spin, high spin, or cannot tell with proper explanation.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to presence of maximum paired electrons in lower energy t2g orbitals.

To label: The given diagram as low spin, high spins, or cannot tell with proper explanation.

(c)

Interpretation Introduction

Interpretation: The given diagrams are to be labeled as low spin, high spin, or cannot tell with proper explanation.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to presence of maximum paired electrons in lower energy t2g orbitals.

To label: The given diagram as low spin, high spins, or cannot tell with proper explanation.

Expert Solution & Answer

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Answer 5

Chapter 21, Problem 10Q

(a)

Interpretation Introduction

Interpretation: The given diagrams are to be labeled as low spin, high spin, or cannot tell with proper explanation.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to presence of maximum paired electrons in lower energy t2g orbitals.

To label: The given diagram as low spin, high spins, or cannot tell with proper explanation.

(b)

Interpretation Introduction

Interpretation: The given diagrams are to be labeled as low spin, high spin, or cannot tell with proper explanation.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to presence of maximum paired electrons in lower energy t2g orbitals.

To label: The given diagram as low spin, high spins, or cannot tell with proper explanation.

(c)

Interpretation Introduction

Interpretation: The given diagrams are to be labeled as low spin, high spin, or cannot tell with proper explanation.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to presence of maximum paired electrons in lower energy t2g orbitals.

To label: The given diagram as low spin, high spins, or cannot tell with proper explanation.

Answer 6

Chapter 21, Problem 10Q

(a)

Interpretation Introduction

Interpretation: The given diagrams are to be labeled as low spin, high spin, or cannot tell with proper explanation.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to presence of maximum paired electrons in lower energy t2g orbitals.

To label: The given diagram as low spin, high spins, or cannot tell with proper explanation.

Answer 7

Chapter 21, Problem 10Q

(a)

Interpretation Introduction

Interpretation: The given diagrams are to be labeled as low spin, high spin, or cannot tell with proper explanation.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to presence of maximum paired electrons in lower energy t2g orbitals.

To label: The given diagram as low spin, high spins, or cannot tell with proper explanation.

Answer 8

(b)

Interpretation Introduction

Interpretation: The given diagrams are to be labeled as low spin, high spin, or cannot tell with proper explanation.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to presence of maximum paired electrons in lower energy t2g orbitals.

To label: The given diagram as low spin, high spins, or cannot tell with proper explanation.

Answer 9

(b)

Interpretation Introduction

Interpretation: The given diagrams are to be labeled as low spin, high spin, or cannot tell with proper explanation.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to presence of maximum paired electrons in lower energy t2g orbitals.

To label: The given diagram as low spin, high spins, or cannot tell with proper explanation.

Answer 10

(c)

Interpretation Introduction

Interpretation: The given diagrams are to be labeled as low spin, high spin, or cannot tell with proper explanation.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to presence of maximum paired electrons in lower energy t2g orbitals.

To label: The given diagram as low spin, high spins, or cannot tell with proper explanation.

Answer 11

(c)

Interpretation Introduction

Interpretation: The given diagrams are to be labeled as low spin, high spin, or cannot tell with proper explanation.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to presence of maximum paired electrons in lower energy t2g orbitals.

To label: The given diagram as low spin, high spins, or cannot tell with proper explanation.

Answer 12

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Answer 23

Ch. 21 - What two first-row transition metals have...Ch. 21 - Prob. 2RQ Ch. 21 - Prob. 3RQ Ch. 21 - Prob. 4RQ Ch. 21 - Prob. 5RQ Ch. 21 - Prob. 6RQ Ch. 21 - Prob. 7RQ Ch. 21 - Prob. 8RQ Ch. 21 - Prob. 9RQ Ch. 21 - Prob. 10RQ

Solution Summary: The author explains that the given diagrams are to be labeled as low spin, high spin or cannot tell with proper explanation.

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Chapter 21 Solutions