ORGANIC CHEMISTRY (LL)-W/WILEYPLUS
ORGANIC CHEMISTRY (LL)-W/WILEYPLUS
4th Edition
ISBN: 9781119659556
Author: Klein
Publisher: WILEY
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Chapter 20.9, Problem 19CC

(a)

Interpretation Introduction

Interpretation: To Predict the major products for the given reactions.

Concept Introduction:

Esterification of anhydrides: symmetric aliphatic or aromatic acid anhydrides reacts with alcohols it gives esters and carboxylic acid as products. Anhydrides also react with amines it gives amides and acids.

Acylation: Acylation of alcohol or amine with aliphatic or aromatic acid anhydride(acetic anhydride) it gives ester with carboxylic acid as products.

(b)

Interpretation Introduction

Interpretation: To Predict the major products for the given reactions.

Concept Introduction:

Esterification of anhydrides: symmetric aliphatic or aromatic acid anhydrides reacts with alcohols it gives esters and carboxylic acid as products. Anhydrides also react with amines it gives amides and acids.

Acylation: Acylation of alcohol or amine with aliphatic or aromatic acid anhydride(acetic anhydride) it gives ester with carboxylic acid as products.

(c)

Interpretation Introduction

Interpretation: To Predict the major products for the given reactions.

Concept Introduction:

Esterification of anhydrides: symmetric aliphatic or aromatic acid anhydrides reacts with alcohols it gives esters and carboxylic acid as products. Anhydrides also react with amines it gives amides and acids.

Acylation: Acylation of alcohol or amine with aliphatic or aromatic acid anhydride(acetic anhydride) it gives ester with carboxylic acid as products.

(d)

Interpretation Introduction

Interpretation: To Predict the major products for the given reactions.

Concept Introduction:

Esterification of anhydrides: symmetric aliphatic or aromatic acid anhydrides reacts with alcohols it gives esters and carboxylic acid as products. Anhydrides also react with amines it gives amides and acids.

Acylation: Acylation of alcohol or amine with aliphatic or aromatic acid anhydride(acetic anhydride) it gives ester with carboxylic acid as products.

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Experiment 1 Data Table 1: Conservation of Mass - Initial Mass Data Table 1 Data Table 2 Data Table 3 Data Table 4 Panel 1 Photo 1 Data Table 5 Reaction Mass of test tube and 5.0% HC₂H₂O2 (g) # (A) (B) Mass of NaHCO, (g) Mass of balloon and NaHCO, (g) (C) 0.10 1 0829 14.38g 0.20 2 0.929 14.29g 0.35 1.00g 3 14.25g 0.50 1.14g 14.29 Experiment 1 Data Table 2: Moles of HC2H3O2 Reaction Volume of Mass of Moles of HC₂H₂O₂ 5.0% Vinegar (g) (ML) 5.0 0.25 0042 mol 2 5.0 0.25 0042 mol 3 5.0 0.25 0042 mol 5.0 0.25 0042 mol Experiment 1 Data Table 3: Moles of NaHCO3 Reaction Mass of NaHCO (g) 10g 20g 35g 50g Experiment 1 Data Table 4: Theoretical Yield of CO₂ Reaction # 1 2 3 Experiment 1 Total mass before reaction (g) (D=A+C) 15.29 15.21g 15.25g 15.349 Exercise 1 Data Table 1 Data Table 2 Data Table 3 Data Table 4 Panel 1 Photo 1 Data Table 5 Exercise 1- Data Table 1 Data Table 2 DataTable 3 Data Table 4 Panel 1 Photo 1 Data Table 5 Exercise 1- Moles of NaHCO 0012 mol 0025 mol 0044 mol 0062 mol…
The chemical reaction you investigated is a two-step reaction. What type of reaction occurs in each step? How did you determine your answer?

Chapter 20 Solutions

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