ORGANIC CHEMISTRY (LL) >CUSTOM PACKAGE<
ORGANIC CHEMISTRY (LL) >CUSTOM PACKAGE<
4th Edition
ISBN: 9781119838791
Author: Klein
Publisher: WILEY
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Chapter 20.3, Problem 7CC
Interpretation Introduction

Interpretation:

Mechanism of the following salt formation should be identify

Concept introduction:

Generally carboxylic acids reacts with bases like potassium hydroxide, sodium hydroxide it forms the corresponding carboxylate salt. Carboxylate salts are ionic and more soluble in water than their corresponding carboxylic acids.  IUPAC name of carboxylate ions replaces the “ic” suffix of the carboxylic acids by “ate”.

For example

ORGANIC CHEMISTRY (LL) >CUSTOM PACKAGE<, Chapter 20.3, Problem 7CC

To provide: To predict the reaction mechanism of the given acid and base

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Consider the following nucleophilic substitution reaction. The compound listed above the arrow is the solvent for the reaction. If nothing is listed over the arrow, then the nucleophile is also the solvent for the reaction. Part 1 of 2 Br CH,CN + I¯ What is the correct mechanism for the reaction? Select the single best answer. @SN2 ○ SN 1 Part: 1/2 Part 2 of 2 Draw the products for the reaction. Include both the major organic product and the inorganic product. If more than one stereoisomer is possible, draw only one stereoisomer. Include stereochemistry where relevant. Click and drag to start drawing a structure. X હૈ
20.33 Think-Pair-Share (a) Rank the following dienes and dienophiles in order of increasing reactivity in the Diels-Alder reaction. (i) CO₂Et (ii) COEt || CO₂Et MeO MeO (b) Draw the product that results from the most reactive diene and most reactive dienophile shown in part (a). (c) Draw a depiction of the orbital overlap involved in the pericyclic reaction that oc- curs between the diene and dienophile in part (b). (d) Is the major product formed in part (b) the endo or exo configuration? Explain your reasoning.
20.40 The following compound undergoes an intramolecular Diels-Alder reaction to give a tricyclic product. Propose a structural formula for the product. CN heat An intramolecular Diels-Alder adduct

Chapter 20 Solutions

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