Organic Chemistry, Books a la Carte Edition (8th Edition)
Organic Chemistry, Books a la Carte Edition (8th Edition)
8th Edition
ISBN: 9780134074580
Author: Bruice, Paula Yurkanis
Publisher: PEARSON
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Chapter 20.11, Problem 24P

a)

Interpretation Introduction

Interpretation:

The OH groups present at axial position in βD-idopyranose are to be identified.

Concept Introduction:

Sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise, β sugar.  Hydroxyl group of α-sugar present on right side in Fischer projection is represented down in Haworth projection and at axial position in chair conformation.

b)

Interpretation Introduction

Interpretation:

The OH groups present at axial position in αD-allopyranose are to be identified.

Concept Introduction:

Sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise, β sugar.  Hydroxyl group of α-sugar present on right side in Fischer projection is represented down in Haworth projection and at axial position in chair conformation.

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Organic Chemistry, Books a la Carte Edition (8th Edition)

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