Considering the given compound to be diamagnetic, weather the ligands A and B produce very similar or very different crystal fields is to be determined. Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin. To determine: If the ligands A and B will produce very similar or very different crystal fields.

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Chapter 20, Problem 89CP

Interpretation Introduction

Interpretation: Considering the given compound to be diamagnetic, weather the ligands A and B produce very similar or very different crystal fields is to be determined.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: If the ligands A and B will produce very similar or very different crystal fields.

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