Chemistry
3rd Edition
ISBN: 9780073402734
Author: Julia Burdge
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Chapter 20, Problem 87AP
Interpretation Introduction
Interpretation:
The molar mass of the given isotope for the radioactive decay is to be calculated.
Concept introduction:
The rate of decay for a particular isotope is given by the rate law:
Here,
Nearly all the radioactive decay is of the first order and its rate constant is given as
Here,
The number of moles of any substance is given as
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5.
Use the MS data to answer the questions on the next page.
14.0
1.4
15.0
8.1
100-
MS-IW-5644
26.0
2.8
27.0
6.7
28.0
1.8
29.0
80
4.4
38.0
1.0
39.0
1.5
41.0
1.2
42.0
11.2
43.0
100.0
44.0
4.3
79.0
1.9
80.0
2.6
Relative Intensity
40
81.0
1.9
82.0
2.5
93.0
8.7
20-
95.0
8.2
121.0
2.0
123.0
2.0
136.0
11.8
0
138.0
11.5
20
40
8.
60
a.
Br
- 0
80
100
120
140
160
180
200
220
m/z
Identify the m/z of the base peak and molecular ion.
2
b.
Draw structures for each of the following fragments (include electrons and charges): 43.0, 93.0,
95.0, 136.0, and 138.0 m/z.
C.
Draw a reasonable a-fragmentation mechanism for the fragmentation of the molecular ion to
fragment 43.0 m/z. Be sure to include all electrons and formal charges.
6. Using the values provided in Appendix E of your lab manual, calculate the monoisotopic mass for the pyridinium
ion (CsH6N) and show your work.
None
Stereochemistry: Three possible answers- diastereomers, enantiomers
OH
CH₂OH
I
-c=0
21108 1101
41745 HOR
CH₂OH
IL
Но
CH₂OH
TIL
a. Compounds I and III have this relationship with each other: enantiomers
b. Compounds II and IV have this relationship with each other:
c. Compounds I and II have this relationship with each other:
d. *Draw one structure that is a stereoisomer of II, but neither a
diastereomer nor an enantiomer. (more than one correct answer)
Chapter 20 Solutions
Chemistry
Ch. 20.1 - Practice Problem ATTEMPT
Identify X in each of...Ch. 20.1 - Prob. 1PPBCh. 20.1 - Practice Problem CONCEPTUALIZE
For each process,...Ch. 20.1 - Prob. 1CPCh. 20.1 - Prob. 2CPCh. 20.2 - Prob. 1PPACh. 20.2 - Prob. 1PPBCh. 20.2 - Practice Problem CONCEPTUALIZE Which of the...Ch. 20.2 - Prob. 1CPCh. 20.2 - Prob. 2CP
Ch. 20.2 - Prob. 3CPCh. 20.2 - Prob. 4CPCh. 20.3 - Prob. 1PPACh. 20.3 - Prob. 1PPBCh. 20.3 - Practice Problem CONCEPTUALIZE
The Think About It...Ch. 20.3 - Prob. 1CPCh. 20.3 - Prob. 2CPCh. 20.3 - Prob. 3CPCh. 20.4 - Practice Problem ATTEMPT Determine the age of a...Ch. 20.4 - Practice Problem BUILD How much 206 Pb will be in...Ch. 20.4 - Prob. 1PPCCh. 20.4 - Prob. 1CPCh. 20.4 - Prob. 2CPCh. 20.5 - Prob. 1PPACh. 20.5 - Prob. 1PPBCh. 20.5 - Practice Problem CONCEPTUALIZE
One of the major...Ch. 20 - Prob. 1QPCh. 20 - Prob. 2QPCh. 20 - Prob. 3QPCh. 20 - Prob. 4QPCh. 20 - Prob. 5QPCh. 20 - Prob. 6QPCh. 20 - Prob. 7QPCh. 20 - Prob. 8QPCh. 20 - 20.9 why is it impossible for the isotope to...Ch. 20 - Prob. 10QPCh. 20 - Prob. 11QPCh. 20 - Prob. 12QPCh. 20 - Prob. 13QPCh. 20 - For each pair of isotopes listed, predict which...Ch. 20 - Prob. 15QPCh. 20 - Prob. 16QPCh. 20 - Prob. 17QPCh. 20 - Prob. 18QPCh. 20 - Prob. 19QPCh. 20 - Prob. 20QPCh. 20 - Prob. 21QPCh. 20 - Prob. 22QPCh. 20 - Prob. 23QPCh. 20 - Prob. 24QPCh. 20 - Prob. 25QPCh. 20 - Prob. 26QPCh. 20 - Prob. 27QPCh. 20 - Prob. 28QPCh. 20 - Prob. 29QPCh. 20 - Prob. 30QPCh. 20 - Prob. 31QPCh. 20 - Prob. 32QPCh. 20 - Prob. 33QPCh. 20 - Prob. 34QPCh. 20 - Prob. 35QPCh. 20 - Prob. 36QPCh. 20 - Prob. 37QPCh. 20 - Prob. 38QPCh. 20 - Prob. 39QPCh. 20 - Prob. 40QPCh. 20 - Prob. 41QPCh. 20 - Prob. 42QPCh. 20 - Prob. 43QPCh. 20 - Prob. 44QPCh. 20 - Prob. 45QPCh. 20 - Prob. 46QPCh. 20 - Prob. 47QPCh. 20 - Prob. 48QPCh. 20 - Prob. 49QPCh. 20 - Prob. 50QPCh. 20 - Prob. 51QPCh. 20 - Prob. 52QPCh. 20 - Prob. 53QPCh. 20 - Prob. 54QPCh. 20 - Prob. 55QPCh. 20 - Prob. 56QPCh. 20 - Prob. 57QPCh. 20 - Prob. 58QPCh. 20 - Prob. 59QPCh. 20 - Prob. 60QPCh. 20 - Prob. 61QPCh. 20 - Prob. 62APCh. 20 - Prob. 63APCh. 20 - Prob. 64APCh. 20 - Prob. 65APCh. 20 - Prob. 66APCh. 20 - Prob. 67APCh. 20 - Prob. 68APCh. 20 - Prob. 69APCh. 20 - Prob. 70APCh. 20 - Prob. 71APCh. 20 - Prob. 72APCh. 20 - Prob. 73APCh. 20 - Prob. 74APCh. 20 - Prob. 75APCh. 20 - Prob. 76APCh. 20 - Prob. 77APCh. 20 - Prob. 78APCh. 20 - Prob. 79APCh. 20 - Prob. 80APCh. 20 - Prob. 81APCh. 20 - Prob. 82APCh. 20 - Prob. 83APCh. 20 - Prob. 84APCh. 20 - Prob. 85APCh. 20 - Prob. 86APCh. 20 - Prob. 87APCh. 20 - Prob. 88APCh. 20 - Prob. 89APCh. 20 - Prob. 90APCh. 20 - Prob. 91APCh. 20 - Prob. 92APCh. 20 - Prob. 93APCh. 20 - Prob. 94APCh. 20 - Prob. 95APCh. 20 - Prob. 96APCh. 20 - Prob. 97APCh. 20 - Prob. 98APCh. 20 - Prob. 99APCh. 20 - Prob. 100APCh. 20 - Prob. 101APCh. 20 - Prob. 102APCh. 20 - Prob. 103APCh. 20 - Prob. 1SEPPCh. 20 - Prob. 2SEPPCh. 20 - Prob. 3SEPPCh. 20 - Prob. 4SEPP
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