Chemistry: Structures and Properties, Books a la Carte Plus MasteringChemistry with eText -- Access Card Package
1st Edition
ISBN: 9780321974617
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 20, Problem 65E
Calculate the equilibrium constant for the reaction between Ni2+(aq) and Cd(s) (at 25 °C).
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This deals with synthetic organic chemistry. Please fill in the blanks appropriately.
Use the References to access important values if needed for this question.
What is the IUPAC name of each of the the following?
0
CH3CHCNH₂
CH3
CH3CHCNHCH2CH3
CH3
You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
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Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
Chapter 20 Solutions
Chemistry: Structures and Properties, Books a la Carte Plus MasteringChemistry with eText -- Access Card Package
Ch. 20 - Balance the redox reaction equation (occurring in...Ch. 20 - Prob. 2SAQCh. 20 - Prob. 3SAQCh. 20 - Refer to Table 19.1 to determine which statement...Ch. 20 - Prob. 5SAQCh. 20 - The Zn/Zn2+ electrode has a standard electrode...Ch. 20 - Refer to Table 19.1 to calculate G for the...Ch. 20 - A redox reaction has an Ecell=0.56V . What can you...Ch. 20 - Prob. 9SAQCh. 20 - Prob. 10SAQ
Ch. 20 - Prob. 11SAQCh. 20 - Prob. 12SAQCh. 20 - Which reaction occurs at the cathode of an...Ch. 20 - Copper is plated onto the cathode of an...Ch. 20 - Prob. 15SAQCh. 20 - Prob. 1ECh. 20 - Explain the difference between a voltaic (or...Ch. 20 - Prob. 3ECh. 20 - Prob. 4ECh. 20 - Prob. 5ECh. 20 - Prob. 6ECh. 20 - What is the definition of the standard cell...Ch. 20 - Describe the basic features of a cell diagram (or...Ch. 20 - Why do some electrochemical cells employ inert...Ch. 20 - Describe the standard hydrogen electrode (SHE) and...Ch. 20 - How is the cell potential of an electrochemical...Ch. 20 - Prob. 12ECh. 20 - Prob. 13ECh. 20 - How can Table 19.1be used to predict whether or...Ch. 20 - Explain why Ecell , Grxn , and K are all...Ch. 20 - Does a redox reaction with a small equilibrium...Ch. 20 - How does Ecell depend on the concentrations of the...Ch. 20 - Prob. 18ECh. 20 - What is a concentration electrochemical cell?Ch. 20 - What are the anode and cathode reactions in a...Ch. 20 - What are the anode and cathode reactions in a...Ch. 20 - Prob. 22ECh. 20 - What is a fuel cell? What is the most common type...Ch. 20 - The anode of an electrolytic cell must be...Ch. 20 - What species is oxidized, and what species is...Ch. 20 - If an electrolytic cell contains a mixture of...Ch. 20 - Why does the electrolysis of an aqueous sodium...Ch. 20 - What is overvoltage in an electrochemical cell?...Ch. 20 - How is the amount of current flowing through an...Ch. 20 - Prob. 30ECh. 20 - Prob. 31ECh. 20 - Prob. 32ECh. 20 - Balance each redox reaction occurring in acidic...Ch. 20 - Prob. 34ECh. 20 - Balance each redox reaction occurring in acidic...Ch. 20 - Prob. 36ECh. 20 - Prob. 37ECh. 20 - Balance each redox reaction occurring in basic...Ch. 20 - Prob. 39ECh. 20 - Prob. 40ECh. 20 - Calculate the standard cell potential for each of...Ch. 20 - Prob. 42ECh. 20 - Consider the voltaic cell: Determine the direction...Ch. 20 - Prob. 44ECh. 20 - Use line notation to represent each...Ch. 20 - Use line notation to represent each...Ch. 20 - a sketch of the voltaic cell represented by the...Ch. 20 - Prob. 48ECh. 20 - Determine whether or not each redox reaction...Ch. 20 - Prob. 50ECh. 20 - Which metal could you use to reduce Mn2+ ions but...Ch. 20 - Prob. 52ECh. 20 - Prob. 53ECh. 20 - Prob. 54ECh. 20 - Prob. 55ECh. 20 - Prob. 56ECh. 20 - Calculate Ecell for each balanced redox reaction...Ch. 20 - Prob. 58ECh. 20 - Prob. 59ECh. 20 - Which metal is the best reducing agent? Mn Al Ni...Ch. 20 - Use tabulated electrode potentials to calculate...Ch. 20 - Use tabulated electrode potentials to calculate...Ch. 20 - Prob. 63ECh. 20 - Calculate the equilibrium constant for each of the...Ch. 20 - Calculate the equilibrium constant for the...Ch. 20 - Prob. 66ECh. 20 - Calculate Grxn and Ecell for a redox reaction with...Ch. 20 - Prob. 68ECh. 20 - Prob. 69ECh. 20 - Prob. 70ECh. 20 - Prob. 71ECh. 20 - Prob. 72ECh. 20 - Prob. 73ECh. 20 - Prob. 74ECh. 20 - Prob. 75ECh. 20 - Consider the concentration cell: Label the anode...Ch. 20 - Prob. 77ECh. 20 - Prob. 78ECh. 20 - Prob. 79ECh. 20 - Prob. 80ECh. 20 - Refer to the tabulated values of Gf in Appendix...Ch. 20 - Refer to the tabulated values of Gf in Appendix...Ch. 20 - Prob. 83ECh. 20 - Prob. 84ECh. 20 - Prob. 85ECh. 20 - Prob. 86ECh. 20 - Prob. 87ECh. 20 - Which products are obtained in the electrolysis of...Ch. 20 - Write equations for the half-reactions that occur...Ch. 20 - Which products are obtained in the electrolysis of...Ch. 20 - Prob. 91ECh. 20 - Write equations for the half-reactions that occur...Ch. 20 - Prob. 93ECh. 20 - Prob. 94ECh. 20 - Prob. 95ECh. 20 - Silver can be electroplated at the cathode of an...Ch. 20 - A major source of sodium metal is the electrolysis...Ch. 20 - Prob. 98ECh. 20 - Prob. 99ECh. 20 - Prob. 100ECh. 20 - Consider the molecular view of an AL strip and...Ch. 20 - Consider the molecular view of an electrochemical...Ch. 20 - Prob. 103ECh. 20 - Prob. 104ECh. 20 - The cell potential of this electrochemical cell...Ch. 20 - Prob. 106ECh. 20 - Prob. 107ECh. 20 - What voltage can theoretically be achieved in a...Ch. 20 - A battery relies on the oxidation of magnesium and...Ch. 20 - A rechargeable battery is constructed based on a...Ch. 20 - If a water electrolysis cell operates at a current...Ch. 20 - Prob. 112ECh. 20 - Prob. 113ECh. 20 - Prob. 114ECh. 20 - Calculate Grxn and K for each reaction. The...Ch. 20 - Calculate Grxn and K for each reaction. The...Ch. 20 - The molar mass of a metal (M) is 50.9 g/mol; it...Ch. 20 - A metal forms the fluoride MF3. Electrolysis of...Ch. 20 - A sample of impure tin of mass 0.535 g is...Ch. 20 - Prob. 120ECh. 20 - Prob. 121ECh. 20 - A 215 mL sample of a 0.500 M NaCl solution with an...Ch. 20 - Prob. 123ECh. 20 - Prob. 124ECh. 20 - Prob. 125ECh. 20 - Prob. 126ECh. 20 - Prob. 127ECh. 20 - Prob. 128ECh. 20 - Prob. 129ECh. 20 - Three electrolytic cells are connected in a...Ch. 20 - Prob. 131ECh. 20 - Prob. 132ECh. 20 - Prob. 133ECh. 20 - Prob. 134ECh. 20 - Prob. 135E
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- b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;' The compound has the ff electronic transitions: 0%o* and no a* 1H NMR Spectrum (CDCl3, 400 MHz) 3.5 3.0 2.5 2.0 1.5 1.0 0.5 ppm 13C{H} NMR Spectrum (CDCl3, 100 MHz) Solvent 80 70 60 50 40 30 20 10 0 ppm ppm ¹H-13C me-HSQC Spectrum ppm (CDCl3, 400 MHz) 5 ¹H-¹H COSY Spectrum (CDCl3, 400 MHz) 0.5 10 3.5 3.0 2.5 2.0 1.5 1.0 10 15 20 20 25 30 30 -35 -1.0 1.5 -2.0 -2.5 3.0 -3.5 0.5 ppm 3.5 3.0 2.5 2.0 1.5 1.0 0.5 ppmarrow_forwardShow work with explanation. don't give Ai generated solutionarrow_forwardRedraw the flowchartarrow_forward
- redraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward• Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forward
- What is/are the product(s) of the following reaction? Select all that apply. * HI A B C OD OH A B OH D Carrow_forwardIn the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forwardNonearrow_forward
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