The structure of β − D -talopyranose is to be drawn. Concept Introduction: The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

Question

For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? NH2 MgBr Will the first product that forms in this reaction create a new CC bond? ○ Yes ○ No MgBr ? Will the first product that forms in this reaction create a new CC bond? O Yes O No Click and drag to start drawing a structure. :☐ G x c olo Ar HE

Answer 1

Question

Chapter 20, Problem 64P

a)

Interpretation Introduction

Interpretation:

The structure of β−D-talopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

b)

Interpretation Introduction

Interpretation:

The structure of α−D-idopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

c)

Interpretation Introduction

Interpretation:

The structure of α−D-tagatopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

d)

Interpretation Introduction

Interpretation:

The structure of β−D-psicofuranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

e)

Interpretation Introduction

Interpretation:

The structure of β−L-talopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

f)

Interpretation Introduction

Interpretation:

The structure of α−L-tagatopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

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For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? NH2 MgBr Will the first product that forms in this reaction create a new CC bond? ○ Yes ○ No MgBr ? Will the first product that forms in this reaction create a new CC bond? O Yes O No Click and drag to start drawing a structure. :☐ G x c olo Ar HE

Predicting As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C - C bond as its major product: H₂N O H 1. ? 2. H3O+ If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. 0 If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. فا Explanation Check Click and drag to start drawing a structure.

Highlight the chirality (or stereogenic) center(s) in the given compound. A compound may have one or more stereogenic centers. OH OH OH OH OH OH

Answer 2

Question

Chapter 20, Problem 64P

a)

Interpretation Introduction

Interpretation:

The structure of β−D-talopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

b)

Interpretation Introduction

Interpretation:

The structure of α−D-idopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

c)

Interpretation Introduction

Interpretation:

The structure of α−D-tagatopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

d)

Interpretation Introduction

Interpretation:

The structure of β−D-psicofuranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

e)

Interpretation Introduction

Interpretation:

The structure of β−L-talopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

f)

Interpretation Introduction

Interpretation:

The structure of α−L-tagatopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

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Answer 3

Question

Chapter 20, Problem 64P

a)

Interpretation Introduction

Interpretation:

The structure of β−D-talopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

b)

Interpretation Introduction

Interpretation:

The structure of α−D-idopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

c)

Interpretation Introduction

Interpretation:

The structure of α−D-tagatopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

d)

Interpretation Introduction

Interpretation:

The structure of β−D-psicofuranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

e)

Interpretation Introduction

Interpretation:

The structure of β−L-talopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

f)

Interpretation Introduction

Interpretation:

The structure of α−L-tagatopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

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Answer 4

Question

Chapter 20, Problem 64P

a)

Interpretation Introduction

Interpretation:

The structure of β−D-talopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

b)

Interpretation Introduction

Interpretation:

The structure of α−D-idopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

c)

Interpretation Introduction

Interpretation:

The structure of α−D-tagatopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

d)

Interpretation Introduction

Interpretation:

The structure of β−D-psicofuranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

e)

Interpretation Introduction

Interpretation:

The structure of β−L-talopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

f)

Interpretation Introduction

Interpretation:

The structure of α−L-tagatopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

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Answer 5

Chapter 20, Problem 64P

a)

Interpretation Introduction

Interpretation:

The structure of β−D-talopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

b)

Interpretation Introduction

Interpretation:

The structure of α−D-idopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

c)

Interpretation Introduction

Interpretation:

The structure of α−D-tagatopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

d)

Interpretation Introduction

Interpretation:

The structure of β−D-psicofuranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

e)

Interpretation Introduction

Interpretation:

The structure of β−L-talopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

f)

Interpretation Introduction

Interpretation:

The structure of α−L-tagatopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

Answer 6

Chapter 20, Problem 64P

a)

Interpretation Introduction

Interpretation:

The structure of β−D-talopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

Answer 7

Chapter 20, Problem 64P

a)

Interpretation Introduction

Interpretation:

The structure of β−D-talopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

Answer 8

b)

Interpretation Introduction

Interpretation:

The structure of α−D-idopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

Answer 9

b)

Interpretation Introduction

Interpretation:

The structure of α−D-idopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

Answer 10

c)

Interpretation Introduction

Interpretation:

The structure of α−D-tagatopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

Answer 11

c)

Interpretation Introduction

Interpretation:

The structure of α−D-tagatopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

Answer 12

d)

Interpretation Introduction

Interpretation:

The structure of β−D-psicofuranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

Answer 13

d)

Interpretation Introduction

Interpretation:

The structure of β−D-psicofuranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

Answer 14

e)

Interpretation Introduction

Interpretation:

The structure of β−L-talopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

Answer 15

e)

Interpretation Introduction

Interpretation:

The structure of β−L-talopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

Answer 16

f)

Interpretation Introduction

Interpretation:

The structure of α−L-tagatopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

Answer 17

f)

Interpretation Introduction

Interpretation:

The structure of α−L-tagatopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

Answer 18

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Answer 29

Ch. 20.1 - Prob. 1P Ch. 20.2 - Prob. 2P Ch. 20.2 - Prob. 3P Ch. 20.3 - Prob. 4P Ch. 20.3 - Prob. 5P Ch. 20.3 - Prob. 6P Ch. 20.4 - Prob. 7P Ch. 20.4 - Prob. 8P Ch. 20.5 - Prob. 9P Ch. 20.5 - Prob. 10P

Solution Summary: The author explains the structural representation of sugar molecule in cyclic form, known as Haworth projection.

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