CHEMISTRY:MOLECULAR..(LL)-PRINT..W/CODE
7th Edition
ISBN: 9781119457282
Author: JESPERSEN
Publisher: WILEY
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Chapter 20, Problem 62RQ
Interpretation Introduction
Interpretation:
The symbol of the missing particles for the given nuclear reactions are to be written.
Concept Introduction:
A
There is a difference between a chemical reaction and a nuclear reaction. A chemical reaction involves atoms, molecules and electrons, whereas a nuclear reaction involves the nucleus of an atom.
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Draw the anti-Markovnikov product of the hydration of this alkene.
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Explanation
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
Chapter 20 Solutions
CHEMISTRY:MOLECULAR..(LL)-PRINT..W/CODE
Ch. 20 - Prob. 1PECh. 20 - Prob. 2PECh. 20 - Prob. 3PECh. 20 - Prob. 4PECh. 20 - Prob. 5PECh. 20 - Prob. 6PECh. 20 - Prob. 7PECh. 20 - Prob. 8PECh. 20 - Prob. 9PECh. 20 - Prob. 10PE
Ch. 20 - Prob. 11PECh. 20 - Prob. 12PECh. 20 - Prob. 13PECh. 20 - Prob. 14PECh. 20 - Prob. 15PECh. 20 - Prob. 1RQCh. 20 - Conservation of Mass and Energy
20.2 How can we...Ch. 20 - Conservation of Mass and Energy
20.3 State the...Ch. 20 - Conservation of Mass and Energy What is the...Ch. 20 - Prob. 5RQCh. 20 - Prob. 6RQCh. 20 - Prob. 7RQCh. 20 - Prob. 8RQCh. 20 - Prob. 9RQCh. 20 - Prob. 10RQCh. 20 - Prob. 11RQCh. 20 - Prob. 12RQCh. 20 - Prob. 13RQCh. 20 - Prob. 14RQCh. 20 - Prob. 15RQCh. 20 - Prob. 16RQCh. 20 - Prob. 17RQCh. 20 - Prob. 18RQCh. 20 - Prob. 19RQCh. 20 - Band of Stability
20.20 Although lead-164 has two...Ch. 20 - Prob. 21RQCh. 20 - Prob. 22RQCh. 20 - Prob. 23RQCh. 20 - Prob. 24RQCh. 20 - Prob. 25RQCh. 20 - Prob. 26RQCh. 20 - Prob. 27RQCh. 20 - Prob. 28RQCh. 20 - Prob. 29RQCh. 20 - Prob. 30RQCh. 20 - Prob. 31RQCh. 20 - Prob. 32RQCh. 20 - Prob. 33RQCh. 20 - Prob. 34RQCh. 20 - Prob. 35RQCh. 20 - Prob. 37RQCh. 20 - Prob. 38RQCh. 20 - Prob. 39RQCh. 20 - Prob. 40RQCh. 20 - Prob. 41RQCh. 20 - Prob. 42RQCh. 20 - Prob. 43RQCh. 20 - Prob. 44RQCh. 20 - Prob. 45RQCh. 20 - Prob. 46RQCh. 20 - Prob. 47RQCh. 20 - Prob. 48RQCh. 20 - Prob. 49RQCh. 20 - Prob. 50RQCh. 20 - Prob. 51RQCh. 20 - Conservation of Mass and Energy Calculate the...Ch. 20 - Prob. 53RQCh. 20 - Prob. 54RQCh. 20 - Prob. 55RQCh. 20 - Prob. 56RQCh. 20 - Prob. 57RQCh. 20 - Prob. 58RQCh. 20 - Prob. 59RQCh. 20 - Prob. 60RQCh. 20 - Prob. 61RQCh. 20 - Prob. 62RQCh. 20 - Prob. 63RQCh. 20 - Prob. 64RQCh. 20 - Prob. 65RQCh. 20 - Prob. 66RQCh. 20 - Prob. 67RQCh. 20 - Prob. 68RQCh. 20 - Prob. 69RQCh. 20 - Prob. 70RQCh. 20 - Prob. 71RQCh. 20 - Prob. 72RQCh. 20 - Prob. 73RQCh. 20 - Prob. 74RQCh. 20 - Prob. 75RQCh. 20 - Prob. 76RQCh. 20 - Prob. 77RQCh. 20 - Prob. 78RQCh. 20 - Prob. 79RQCh. 20 - Prob. 80RQCh. 20 - Prob. 81RQCh. 20 - Prob. 82RQCh. 20 - Prob. 83RQCh. 20 - Prob. 84RQCh. 20 - Prob. 85RQCh. 20 - Prob. 86RQCh. 20 - Prob. 87RQCh. 20 - Prob. 88RQCh. 20 - Prob. 89RQCh. 20 - Prob. 90RQCh. 20 - Prob. 91RQCh. 20 - Prob. 92RQCh. 20 - Prob. 93RQCh. 20 - Prob. 94RQCh. 20 - Prob. 95RQCh. 20 - Prob. 96RQCh. 20 - Prob. 97RQCh. 20 - Prob. 98RQCh. 20 - Prob. 99RQCh. 20 - Prob. 100RQCh. 20 - Prob. 101RQCh. 20 - Prob. 102RQCh. 20 - Prob. 103RQCh. 20 - Prob. 104RQCh. 20 - Prob. 105RQCh. 20 - Prob. 106RQCh. 20 - Prob. 107RQCh. 20 - Prob. 108RQCh. 20 - Prob. 109RQCh. 20 - Prob. 110RQCh. 20 - Prob. 111RQCh. 20 - Prob. 112RQCh. 20 - Prob. 113RQCh. 20 - Prob. 114RQCh. 20 - Prob. 115RQCh. 20 - Prob. 116RQCh. 20 - Prob. 117RQCh. 20 - Prob. 118RQCh. 20 - Prob. 119RQCh. 20 - Prob. 120RQCh. 20 - Prob. 121RQCh. 20 - Prob. 122RQCh. 20 - Prob. 123RQCh. 20 - Prob. 124RQCh. 20 - Prob. 125RQCh. 20 - A complex ion of chromium(III) with oxalate ion...Ch. 20 - Prob. 127RQCh. 20 - Prob. 128RQCh. 20 - Prob. 129RQCh. 20 - Prob. 132RQ
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- fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transferarrow_forward34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10arrow_forwardelow are experimentally determined van Deemter plots of column efficiency, H, vs. flow rate. H is a quantitative measurement of band broadening. The left plot is for a liquid chromatography application and the night is for gas chromatography. Compare and contrast these two plots in terms of the three band broadening mechanisms presented in this activity. How are they similar? How do they differ? Justify your answers.? 0.4 H (mm) 0.2 0.1- 0.3- 0 0.5 H (mm) 8.0 7.0 6.0 5.0 4.0- 3.0 T +++ 1.0 1.5 0 2.0 4.0 Flow Rate, u (cm/s) 6.0 8.0 Flow Rate, u (cm/s)arrow_forward
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