ORGANIC CHEMISTRY-PRINT (LL)-W/WILEY
ORGANIC CHEMISTRY-PRINT (LL)-W/WILEY
4th Edition
ISBN: 9781119761105
Author: Klein
Publisher: WILEY
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Chapter 20, Problem 52PP
Interpretation Introduction

Interpretation:

The electron with drawing and electron donating groups are should be drawn and identified for the given corresponding statements by using its structures.

Concept introduction:

Ortho and Para direction: The organic reaction involved for many direction groups, for example the methyl group is an ortho, para directing group, this groups are electron donation groups, further the meta directing groups are electron with drawing groups.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Esterification reaction: This type of conversion reaction involved aliphatic, aromatic carboxylic acid to different esters using mineral acids (like dil.HCl, dil.H2SO4 ) and alcohols Fisher Esterification. The equal amount of carboxylic acid is treated with alcohols in presence of acid catalyst conditions to give target ester along with water. This type of conversion called as Fisher Esterification.

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For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? NH2 MgBr Will the first product that forms in this reaction create a new CC bond? ○ Yes ○ No MgBr ? Will the first product that forms in this reaction create a new CC bond? O Yes O No Click and drag to start drawing a structure. :☐ G x c olo Ar HE
Predicting As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C - C bond as its major product: H₂N O H 1. ? 2. H3O+ If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. 0 If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. فا Explanation Check Click and drag to start drawing a structure.
Highlight the chirality (or stereogenic) center(s) in the given compound. A compound may have one or more stereogenic centers. OH OH OH OH OH OH

Chapter 20 Solutions

ORGANIC CHEMISTRY-PRINT (LL)-W/WILEY

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