
Organic Chemistry; Modified MasteringChemistry with Pearson eText -- ValuePack Access Card; Study Guide and Student Solutions Manual for Organic Chemistry, Books a la Carte Edition (7th Edition)
7th Edition
ISBN: 9780134240152
Author: Paula Yurkanis Bruice
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Concept explainers
Textbook Question
Chapter 20, Problem 43P
Organic chemists work with tetraphenylporphyrins rather than with porphyrins because tetraphenylporphyrins are much more resistant to air oxidation, Tetraphenylporphyrin can be prepared by the reaction of benzaldehyde with pyrrole. Please a mechanis, for the formation of the ring system shown here:
Expert Solution & Answer

Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
One of the pi molecular orbitals of 1,3-butadiene (CH2=CHCH=CH2) is shown below. Please identify the number of nodal planes perpendicular to the bonding axis
Draw the monomers required to synthesize this condensation polymer please.
Provide the correct systematic name for the compound shown here. Please take into account the keyboard options below
Chapter 20 Solutions
Organic Chemistry; Modified MasteringChemistry with Pearson eText -- ValuePack Access Card; Study Guide and Student Solutions Manual for Organic Chemistry, Books a la Carte Edition (7th Edition)
Ch. 20.1 - Name the following:Ch. 20.2 - Prob. 2PCh. 20.2 - Prob. 3PCh. 20.3 - Draw the product of each of the following...Ch. 20.5 - Prob. 6PCh. 20.5 - When pyrrole is added to a dilute solution of...Ch. 20.5 - Explain why cyclopentadiene (pKa = 15) is more...Ch. 20.6 - Prob. 10PCh. 20.6 - How to the mechanisms of the following reactions...Ch. 20.6 - Prob. 12P
Ch. 20.6 - Rank the following compounds from easiest to...Ch. 20.7 - Prob. 14PCh. 20.7 - Prob. 15PCh. 20.7 - Prob. 16PCh. 20.7 - Prob. 17PCh. 20.7 - Prob. 18PCh. 20.7 - Prob. 19PCh. 20.7 - Prob. 20PCh. 20 - Name the following:Ch. 20 - Prob. 22PCh. 20 - Prob. 23PCh. 20 - Which of the following compounds is easier to...Ch. 20 - Rank the following compounds from most reactive to...Ch. 20 - One of the following compounds undergoes...Ch. 20 - Benzene undergoes electrophilic aromatic...Ch. 20 - The dipole moments of furan and tetrahydrofuran...Ch. 20 - Prob. 29PCh. 20 - Prob. 30PCh. 20 - The chemical shifts of the C-2 hydrogen in the...Ch. 20 - Explain why protonating aniline has a dramatic...Ch. 20 - Prob. 33PCh. 20 - Propose a mechanism for the following reaction:Ch. 20 - Prob. 35PCh. 20 - Propose a mechanism for the following reactions:Ch. 20 - Prob. 37PCh. 20 - a. Draw resonance contributors to show why...Ch. 20 - Prob. 39PCh. 20 - Pyrrole reacts with excess...Ch. 20 - Prob. 41PCh. 20 - Prob. 42PCh. 20 - Organic chemists work with tetraphenylporphyrins...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- curved arrows are used to illustrate the flow of electrons. using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s)arrow_forwardIdentify the 'cartoon' drawing of the acceptor orbital in the first mechanistic step of an electrophilic addition reaction of butadiene with HBr. Pleasearrow_forwardH- H H H H H H Identify and select all structures below that represent a constitutional isomer(s) of the compound shown above. H- H H H A. H H H H-C CI H H D. H H H H H H C C -H H C C H H H H B. H CI H H- C C H H H H E. H CI H C.arrow_forward
- Why doesn't this carry on to form a ring by deprotonating the alpha carbon and the negatively-charged carbon attacking the C=O?arrow_forward6. A solution (0.0004 M) of Fe(S2CNEt2)3 (see the structural drawing below) in chloroform has absorption bands at: 350 nm (absorbance A = 2.34); 514 nm(absorbance A = 0.0532); Calculate the molar absorptivity values for these bands. Comment on their possible nature (charge transfer transitions or d-d S N- transitions?). (4 points)arrow_forwardWhat is the mechanism for this?arrow_forward
- For questions 1-4, consider the following complexes: [Co(CN)6], [COC14]², [Cr(H2O)6]²+ 4. Room temperature (20°C) measurement of molar magnetic susceptibility (Xm) for Fe(NH4)2(SO4)2×6H2O is 1.1888 x 102 cgs (Gaussian units). Calculate effective magnetic moment and provide a number of unpaired electrons for the iron ion. Use this number to rationalize the coordination geometry around iron center. (4 points)arrow_forward7. Describe the expected 31P and 19F (where applicable) NMR spectral patterns for the following compounds (indicate number of signals and their splitting patterns). a) tetraphenyldiphosphine Ph Ph P-P Ph Ph Ph Ph ' b) tetraphenyldiphosphine monoxide P-P-Ph Ph (2 points) (2 points c) tetrafluorophosphonium hexafluorophosphate [PF4]*[PF6]¯ (4 points)arrow_forward3. For questions 1-4, consider the following complexes: [Co(CN)6]4, [COC14]², [Cr(H2O)6]²+ Which (if any) of these complexes would be expected to display Jahn-Teller distortion? (2 points)arrow_forward
- What is Instrumental Neutron Activation and what are the advantages and disadvantages in using its applications? (I'm doing an in class assignment and need better understanding of what the instrument can be used for) Please include references so that I can better understand the application of how the instrument works!arrow_forwardWhat is Isotope Analysis and what are the advantages and disadvantages in using its applications and instrumentalization? Please include references so that I can better understand how the instrument works!arrow_forward5. Count the electrons on the following complexes and state whether they follow the 18- electron rule: (3 points) Fe(CO)5 Ni(PMe3)4 PMe3 is trimethylphosphine Mn(CO)5Brarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage LearningChemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning

Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning


Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
Coenzymes and cofactors; Author: CH15 SWAYAM Prabha IIT Madras;https://www.youtube.com/watch?v=bubY2Nm7hVM;License: Standard YouTube License, CC-BY
Aromaticity and Huckel's Rule; Author: Professor Dave Explains;https://www.youtube.com/watch?v=7-BguH4_WBQ;License: Standard Youtube License