ORGANIC CHEM. VOL.1+2-W/WILEYPLUS
12th Edition
ISBN: 9781119304241
Author: Solomons
Publisher: WILEY C
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Textbook Question
Chapter 20, Problem 28P
What products would you expect to be formed when each of the
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1. Which of the following amines would make an imine if reacted with an aldehyde or ketone?
A
B
e. Which of the following moleculo
C
NH₂
AN
D
Please help me with both of these, I am very confused and would like to study
Draw the structure of the major product expected for the following reaction. Hint, the amine acts as a base in this reaction.
Chapter 20 Solutions
ORGANIC CHEM. VOL.1+2-W/WILEYPLUS
Ch. 20 - Prob. 1PPCh. 20 - Prob. 2PPCh. 20 - Practice Problem 20.3
Write a mechanism that...Ch. 20 - Prob. 4PPCh. 20 - PRACTICE PROBLEM 20.5 Outline a preparation of...Ch. 20 - Prob. 6PPCh. 20 - Prob. 7PPCh. 20 - Prob. 8PPCh. 20 - Prob. 9PPCh. 20 - Prob. 10PP
Ch. 20 - Practice Problem 20.11 In the preceding examples...Ch. 20 - Prob. 12PPCh. 20 - Prob. 13PPCh. 20 - Practice Problem 20.14
Outline a synthesis of...Ch. 20 - Prob. 15PPCh. 20 - Prob. 16PPCh. 20 - Prob. 17PPCh. 20 - Prob. 18PPCh. 20 - Prob. 19PCh. 20 - 20.20 Give common or systematic names for each of...Ch. 20 - Which is the most basic nitrogen in each compound?...Ch. 20 - Prob. 22PCh. 20 - Prob. 23PCh. 20 - Show how you might synthesize each of the...Ch. 20 - Prob. 25PCh. 20 - 20.26 Provide the major organic product from each...Ch. 20 - Prob. 27PCh. 20 - 20.28 What products would you expect to be formed...Ch. 20 - Prob. 29PCh. 20 - Prob. 30PCh. 20 - Prob. 31PCh. 20 - Write equations for simple chemical rests or state...Ch. 20 - Prob. 33PCh. 20 - Explain the following, including mention of key...Ch. 20 - 20.35 Provide a detailed mechanism for each of the...Ch. 20 - Prob. 36PCh. 20 - Prob. 37PCh. 20 - Prob. 38PCh. 20 - Prob. 39PCh. 20 - 20.40 Give structures for compounds R-W:
Ch. 20 - Prob. 41PCh. 20 - Prob. 42PCh. 20 - Diethylpropion (shown here) is a compound used in...Ch. 20 - Prob. 44PCh. 20 - 20.45 Compound W is soluble in dilute aqueous HCI...Ch. 20 - 20.46 Propose structures for compounds X, Y, and...Ch. 20 - Compound A(C10H15N) is soluble in dilute HCI. The...Ch. 20 - Prob. 48PCh. 20 - Prob. 49PCh. 20 - For each of the following, identify the product...Ch. 20 - 20.51 Develop a synthesis for the following...Ch. 20 - 20.52 When phenyl isochiocyanatc, , is reduced...Ch. 20 - Prob. 53PCh. 20 - 20.54 Propose a mechanism that can explain the...Ch. 20 - When acetone is treated with anhydrous ammonia in...Ch. 20 - Prob. 56P
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- Write the mechanism for the following reactions:1. the acid-catalyzed hydrolysis of an imine to a carbonyl compound and a primary amine2. the acid-catalyzed hydrolysis of an enamine to a carbonyl compound and a secondary aminearrow_forwardAccount for the experimental behavior of each class of amines (primary,secondary and tertiary) based on their relative reactivities with benzenesulfonyl chloride.arrow_forwardWhich of the following statements about carbonyl derivatives is FALSE? O Formation of an amide from an acyl chloride requires use of two equivalents of the amine. O The product of the base-promoted saponification of an ester is a carboxylate anion. O Acetals are great protecting groups for aldehydes and ketones because they are stable to acidic conditions. O Despite being a terrible leaving group, H2N¯ is indeed the leaving group in the base-promoted hydrolysis of an amide. O Transesterification can occur under either acidic or basic reactions conditions.arrow_forward
- Which of the following functional groups will react faster and at lower conditions to a nucleophilic attack? (you can think of a nucleophilic attack by an amine). O a. Carboxylic Acid o b. Nitrile о с. Асyl Нalide d. Esterarrow_forwarda) What are the difficulties with the following reaction to synthesize an amine. + HBr Br + NH3 NH2 b) Show a possible alternatives to this synthesis.arrow_forwardOut of acid chlorides (least stable), anhydrides, esters, and amides (most stable). True or false Acid chlorides would be the most reactive to hydrolysis and Amides would be the least reactivearrow_forward
- Give the amine and coupling component of the given compound.arrow_forwardFollowing are structural formulas for two more widely used sulfonylurea hypoglycemic agents.Show how each might be synthesized by converting an appropriate amine to a carbamic ester and then treating the carbamate with the sodium salt of a substituted benzenesulfonamide.arrow_forwardAn aqueous solution of a primary or secondary amine reacts with an acyl chloride to form an amide as the major product. However, if the amine is tertiary, an amide is not formed. What product is formed? Explain.arrow_forward
- Please help me with this I am very confused and I want to study.arrow_forwardWhy is there a need to add two (2) equivalents of amine in the reaction of an acid chloride and an amine ? A) The extra amine will deprotonate the amine or alcohol, making it a better nucleophile. B) The extra amine will neutralize the acid by-product of the reaction. C) The extra amine will protonate the carbonyl of the acid chloride, making it more reactive. D) The extra amine will absorb the heat of the reaction.arrow_forwardDraw the possible stereoisomers of 2-methylocta-4,6-dien-1-amine. Note that E-, Z- isomers of each stereoisomer are also possible and would not be accounted for by the formula above; draw any E- or Z- isomers.arrow_forward
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