Lab Manual for Zumdahl/Zumdahl/DeCoste¿s Chemistry, 10th Edition
10th Edition
ISBN: 9781305957459
Author: ZUMDAHL
Publisher: CENGAGE L
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Chapter 20, Problem 26E
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The reaction sequence shown in Scheme 5 demonstrates the synthesis of a
substituted benzene derivative Q.
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NH2
NaNO2, HCI
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0°C
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CHINO₂
N
O
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PO
Q
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Scheme 5
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Draw the structure of intermediate O.
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(ii) Draw the mechanism for the transformation of aniline N to intermediate O.
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(b)
[6 marks]
(iii) Identify the reagent X used to convert compound O to the iodinated compound
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P.
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(iv) Identify the possible structures of compound Q.
[2 marks]
[2 marks]
[shom 2]
(v)
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Draw the mechanism for the transformation of intermediate P to compound Q.
[5 marks]
vi
(vi) Account for the regiochemical outcome observed in the reaction forming
compound Q.
[3 marks]
PROBLEM 4 Solved
Show how 1-butanol can be converted into the following compounds:
a.
PROBLEM 5+
b.
d.
-C=
N
Which alkene is the major product of this dehydration?
OH
H2SO4
heat
Chapter 20 Solutions
Lab Manual for Zumdahl/Zumdahl/DeCoste¿s Chemistry, 10th Edition
Ch. 20 - What are the two most abundant elements by mass in...Ch. 20 - Prob. 2RQCh. 20 - Prob. 3RQCh. 20 - What is the valence electron configuration for the...Ch. 20 - Prob. 5RQCh. 20 - Prob. 6RQCh. 20 - Table 19-14 lists some common nitrogen compounds...Ch. 20 - Prob. 8RQCh. 20 - Prob. 9RQCh. 20 - Prob. 10RQ
Ch. 20 - Prob. 1QCh. 20 - Prob. 2QCh. 20 - Prob. 3QCh. 20 - Diagonal relationships in the periodic table exist...Ch. 20 - Prob. 6QCh. 20 - Prob. 7QCh. 20 - Prob. 8QCh. 20 - All the Group 1A (1) and 2A (2) metals are...Ch. 20 - Prob. 10QCh. 20 - Prob. 11QCh. 20 - The major industrial use of hydrogen is in the...Ch. 20 - Prob. 13QCh. 20 - Prob. 14QCh. 20 - Prob. 17ECh. 20 - Prob. 18ECh. 20 - Prob. 19ECh. 20 - Prob. 20ECh. 20 - Prob. 21ECh. 20 - Prob. 22ECh. 20 - Prob. 23ECh. 20 - Prob. 24ECh. 20 - Prob. 25ECh. 20 - Electrolysis of an alkaline earth metal chloride...Ch. 20 - Prob. 28ECh. 20 - Prob. 29ECh. 20 - Prob. 30ECh. 20 - Prob. 31ECh. 20 - Prob. 32ECh. 20 - Boron hydrides were once evaluated for possible...Ch. 20 - Prob. 34ECh. 20 - Prob. 35ECh. 20 - Prob. 36ECh. 20 - Prob. 37ECh. 20 - Prob. 38ECh. 20 - Prob. 39ECh. 20 - Prob. 40ECh. 20 - The following illustration shows the orbitals used...Ch. 20 - Prob. 42ECh. 20 - Silicon is produced for the chemical and...Ch. 20 - Prob. 44ECh. 20 - The compound Pb3O4 (red lead) contains a mixture...Ch. 20 - Prob. 46ECh. 20 - Prob. 47ECh. 20 - Prob. 48ECh. 20 - Prob. 49ECh. 20 - Prob. 50ECh. 20 - Prob. 51ECh. 20 - Prob. 52ECh. 20 - Prob. 53ECh. 20 - Prob. 54ECh. 20 - Prob. 55ECh. 20 - Phosphate buffers are important in regulating the...Ch. 20 - Prob. 57ECh. 20 - Trisodium phosphate (TSP) is an effective grease...Ch. 20 - Prob. 59ECh. 20 - Prob. 60ECh. 20 - Prob. 61ECh. 20 - Complete and balance each of the following...Ch. 20 - Prob. 63ECh. 20 - Prob. 64ECh. 20 - How can the paramagnetism of O2 be explained using...Ch. 20 - Describe the bonding in SO2 and SO3 using the...Ch. 20 - Write the Lewis structure for O2F2. Predict the...Ch. 20 - Give the Lewis structure, molecular structure, and...Ch. 20 - Prob. 69ECh. 20 - Prob. 70ECh. 20 - Prob. 71ECh. 20 - Prob. 72ECh. 20 - Prob. 73ECh. 20 - Prob. 74ECh. 20 - Prob. 75ECh. 20 - Prob. 76ECh. 20 - Prob. 77ECh. 20 - Prob. 78ECh. 20 - Prob. 79AECh. 20 - The inert-pair effect is sometimes used to explain...Ch. 20 - How could you determine experimentally whether the...Ch. 20 - Prob. 82AECh. 20 - Prob. 83AECh. 20 - Prob. 84AECh. 20 - Prob. 85AECh. 20 - Hydrazine is somewhat toxic. Use the following...Ch. 20 - Prob. 87AECh. 20 - Draw Lewis structures for the AsCl4+ and AsCl6...Ch. 20 - There are two forms of solid sulfur: rhombic and...Ch. 20 - Prob. 90AECh. 20 - Prob. 91AECh. 20 - What is a disproportionation reaction? Use the...Ch. 20 - Sulfur forms a wide variety of compounds in which...Ch. 20 - Prob. 94AECh. 20 - Prob. 95CWPCh. 20 - Prob. 96CWPCh. 20 - Prob. 97CWPCh. 20 - Prob. 98CWPCh. 20 - Prob. 99CWPCh. 20 - Nitrous oxide (N2O) can be produced by thermal...Ch. 20 - What is the hybridization of the central atom in...Ch. 20 - Prob. 102CWPCh. 20 - Prob. 103CWPCh. 20 - Prob. 104CWPCh. 20 - Prob. 105CPCh. 20 - Prob. 106CPCh. 20 - Lead forms compounds in the +2 and +4 oxidation...Ch. 20 - Prob. 108CPCh. 20 - Prob. 109CPCh. 20 - Prob. 110CPCh. 20 - You travel to a distant, cold planet where the...Ch. 20 - Prob. 112CPCh. 20 - Prob. 113CPCh. 20 - Provide a reasonable estimate for the number of...Ch. 20 - Prob. 116IPCh. 20 - Prob. 117IPCh. 20 - Although nitrogen trifluoride (NF3) is a thermally...Ch. 20 - While selenic acid has the formula H2SeO4 and thus...Ch. 20 - Prob. 120MPCh. 20 - Prob. 121MP
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Electrolysis; Author: Tyler DeWitt;https://www.youtube.com/watch?v=dRtSjJCKkIo;License: Standard YouTube License, CC-BY