Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Chapter 20, Problem 20.65QE
Interpretation Introduction
Interpretation:
The structure of
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Draw the stepwise mechanism for the reactions
Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Chapter 20 Solutions
Chemistry: Principles and Practice
Ch. 20 - Prob. 20.1QECh. 20 - Prob. 20.2QECh. 20 - Prob. 20.3QECh. 20 - Prob. 20.4QECh. 20 - Prob. 20.5QECh. 20 - Prob. 20.6QECh. 20 - Prob. 20.7QECh. 20 - Prob. 20.8QECh. 20 - Prob. 20.9QECh. 20 - Prob. 20.10QE
Ch. 20 - Prob. 20.11QECh. 20 - Prob. 20.12QECh. 20 - Prob. 20.13QECh. 20 - Prob. 20.14QECh. 20 - Prob. 20.15QECh. 20 - Prob. 20.16QECh. 20 - Prob. 20.17QECh. 20 - Prob. 20.18QECh. 20 - Prob. 20.19QECh. 20 - Prob. 20.20QECh. 20 - Prob. 20.21QECh. 20 - Prob. 20.23QECh. 20 - Prob. 20.24QECh. 20 - Prob. 20.25QECh. 20 - Prob. 20.26QECh. 20 - Prob. 20.27QECh. 20 - Prob. 20.28QECh. 20 - Prob. 20.30QECh. 20 - Prob. 20.31QECh. 20 - Prob. 20.32QECh. 20 - Prob. 20.33QECh. 20 - Prob. 20.34QECh. 20 - Prob. 20.35QECh. 20 - Prob. 20.36QECh. 20 - Prob. 20.37QECh. 20 - Prob. 20.38QECh. 20 - Prob. 20.39QECh. 20 - Prob. 20.40QECh. 20 - Prob. 20.41QECh. 20 - Prob. 20.42QECh. 20 - Prob. 20.43QECh. 20 - Prob. 20.44QECh. 20 - Prob. 20.46QECh. 20 - Prob. 20.47QECh. 20 - Prob. 20.49QECh. 20 - Prob. 20.50QECh. 20 - Prob. 20.51QECh. 20 - Prob. 20.52QECh. 20 - Prob. 20.53QECh. 20 - Prob. 20.54QECh. 20 - Prob. 20.55QECh. 20 - Prob. 20.56QECh. 20 - Prob. 20.57QECh. 20 - Prob. 20.58QECh. 20 - Prob. 20.59QECh. 20 - Prob. 20.60QECh. 20 - Prob. 20.61QECh. 20 - Prob. 20.62QECh. 20 - Prob. 20.63QECh. 20 - Prob. 20.64QECh. 20 - Prob. 20.65QECh. 20 - Prob. 20.66QECh. 20 - Prob. 20.67QECh. 20 - Prob. 20.68QECh. 20 - Prob. 20.69QECh. 20 - Prob. 20.70QECh. 20 - Prob. 20.71QECh. 20 - Prob. 20.72QECh. 20 - Prob. 20.73QECh. 20 - Prob. 20.74QECh. 20 - Prob. 20.75QECh. 20 - Prob. 20.76QECh. 20 - Prob. 20.77QECh. 20 - Prob. 20.78QECh. 20 - Prob. 20.79QECh. 20 - Prob. 20.80QECh. 20 - Prob. 20.82QECh. 20 - Prob. 20.83QECh. 20 - Prob. 20.84QE
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Similar questions
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
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