Connect for Chemistry
13th Edition
ISBN: 9781260161854
Author: Raymond Chang, Jason Overby
Publisher: Mcgraw-hill Higher Education (us)
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Textbook Question
Chapter 20, Problem 20.60QP
Which of the following settings is the most suitable for photochemical smog formation: (a) Gobi desert at noon in June, (b) New York City at 1 p.m. in July, (c) Boston at noon in January? Explain your choice.
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Solution
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Use retrosynthetic analysis to suggest two paths to synthesize 2-methyl-3-hexanol using the Grignard reaction. (Click and drag
the appropriate image to the correct position in the reactions.)
Route 1
Aldehyde 1
or
+98
Aldehyde 2
Route 2
Q6
+100
Solved in 1 attempt
Q7
+95
Solved in 2 attempts
Q8
+98
Unlimited attempts
possible
+
+
Grignard 1
OH
H3O+
Grignard 2
Answer Bank
Q9
+90
MgBr
Unlimited attempts
possible
CH3CH2CH2MgBr
Q10
Unlimited attempts
Q11
?
?
+100
in 1 attempt
2-methyl-3-hexanol
CH3CH2MgBr
H
H
о
H
Attempt 3
2) (4 pt) After the reaction was completed, the student collected the following data. Crude
product data is the data collected after the reaction is finished, but before the product
is purified. "Pure" product data is the data collected after attempted purification using
recrystallization.
Student B's data:
Crude product data
"Pure"
product data
after
recrystallization
Crude mass: 0.93 g grey solid
Crude mp: 96-106 °C
Crude % yield:
Pure mass: 0.39 g white solid
Pure mp: 111-113 °C
Pure % yield:
a) Calculate the crude and pure percent yields for the student's reaction.
b) Summarize what is indicated by the crude and pure melting points.
Don't used hand raiting
Chapter 20 Solutions
Connect for Chemistry
Ch. 20.2 - Calculate the wavelength (in nm) of a photon...Ch. 20.5 - Prob. 2PECh. 20.5 - Prob. 1RCFCh. 20.8 - Prob. 3PECh. 20 - Prob. 20.1QPCh. 20 - Prob. 20.2QPCh. 20 - Prob. 20.3QPCh. 20 - Prob. 20.4QPCh. 20 - Prob. 20.5QPCh. 20 - Prob. 20.6QP
Ch. 20 - Prob. 20.7QPCh. 20 - Prob. 20.8QPCh. 20 - Prob. 20.9QPCh. 20 - Prob. 20.10QPCh. 20 - Prob. 20.11QPCh. 20 - The green color observed in aurora borealis is...Ch. 20 - Prob. 20.13QPCh. 20 - Prob. 20.14QPCh. 20 - Prob. 20.15QPCh. 20 - Prob. 20.16QPCh. 20 - Prob. 20.17QPCh. 20 - Prob. 20.18QPCh. 20 - Prob. 20.19QPCh. 20 - Prob. 20.20QPCh. 20 - Prob. 20.21QPCh. 20 - Prob. 20.22QPCh. 20 - Prob. 20.23QPCh. 20 - Prob. 20.24QPCh. 20 - Prob. 20.25QPCh. 20 - Prob. 20.26QPCh. 20 - Prob. 20.27QPCh. 20 - Prob. 20.28QPCh. 20 - Prob. 20.29QPCh. 20 - Prob. 20.30QPCh. 20 - Prob. 20.31QPCh. 20 - Prob. 20.32QPCh. 20 - Prob. 20.33QPCh. 20 - Prob. 20.34QPCh. 20 - Prob. 20.35QPCh. 20 - Prob. 20.36QPCh. 20 - Prob. 20.37QPCh. 20 - Prob. 20.38QPCh. 20 - Prob. 20.39QPCh. 20 - Calcium oxide or quicklime (CaO) is used in...Ch. 20 - The molar heat capacity of a diatomic molecule is...Ch. 20 - Prob. 20.42QPCh. 20 - Prob. 20.43QPCh. 20 - List three detrimental effects of acid rain.Ch. 20 - Briefly discuss two industrial processes that lead...Ch. 20 - Discuss ways to curb acid rain.Ch. 20 - Prob. 20.47QPCh. 20 - Describe the removal of SO2 by CaO (to form CaSO3)...Ch. 20 - Prob. 20.49QPCh. 20 - Prob. 20.50QPCh. 20 - Prob. 20.51QPCh. 20 - Prob. 20.52QPCh. 20 - Identify the gas that is responsible for the brown...Ch. 20 - The safety limits of ozone and carbon monoxide are...Ch. 20 - Prob. 20.55QPCh. 20 - In which region of the atmosphere is ozone...Ch. 20 - Assume that the formation of nitrogen dioxide:...Ch. 20 - The gas-phase decomposition of peroxyacetyl...Ch. 20 - On a smoggy day in a certain city the ozone...Ch. 20 - Which of the following settings is the most...Ch. 20 - Prob. 20.61QPCh. 20 - Prob. 20.62QPCh. 20 - Prob. 20.63QPCh. 20 - Prob. 20.64QPCh. 20 - A concentration of 8.00 102 ppm by volume of CO...Ch. 20 - Prob. 20.66QPCh. 20 - Briefly describe the harmful effects of the...Ch. 20 - The equilibrium constant (KP) for the reaction is...Ch. 20 - As stated in the chapter, carbon monoxide has a...Ch. 20 - Instead of monitoring carbon dioxide, suggest...Ch. 20 - In 1991 it was discovered that nitrous oxide (N2O)...Ch. 20 - A glass of water initially at pH 7.0 is exposed to...Ch. 20 - A 14-m by 10-m by 3.0-m basement had a high radon...Ch. 20 - Ozone in the troposphere is formed by the...Ch. 20 - Prob. 20.75QPCh. 20 - Prob. 20.76QPCh. 20 - A person was found dead of carbon monoxide...Ch. 20 - The carbon dioxide level in the atmosphere today...Ch. 20 - What is funny about the following cartoon?Ch. 20 - Calculate the standard enthalpy of formation (Hf )...Ch. 20 - Prob. 20.81QPCh. 20 - Prob. 20.82QPCh. 20 - Prob. 20.83QPCh. 20 - Peroxyacetyl nitrate (PAN) undergoes thermal...Ch. 20 - How are past temperatures determined from ice...Ch. 20 - The balance between SO2 and SO3 is important in...Ch. 20 - Prob. 20.87QPCh. 20 - The HO3 radical was once thought of as a temporary...Ch. 20 - What is the difference between weather and...Ch. 20 - Estimate the annual production of carbon dioxide...
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- A DEPT NMR spectrum is shown for a molecule with the molecular formula of C5H12O. Draw the structure that best fits this data. 200 180 160 140 120 100 一盆 00 40 8- 20 ppm 0 Qarrow_forwardDon't used hand raitingarrow_forwardShown below is the major resonance structure for a molecule. Draw the second best resonance structure of the molecule. Include all non-zero formal charges. H. H. +N=C H H H Cl: Click and drag to start drawing a structure. : ? g B S olo Ar B Karrow_forward
- Don't used hand raitingarrow_forwardS Shown below is the major resonance structure for a molecule. Draw the second best resonance structure of the molecule. Include all non-zero formal charges. H H = HIN: H C. :0 H /\ H H Click and drag to start drawing a structure. ×arrow_forwardPlease help me figure out these calculation and what should be plotted. These are notes for my chemistry class.arrow_forward
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