ORGANIC CHEM +SG +SAPLING >IP<
ORGANIC CHEM +SG +SAPLING >IP<
6th Edition
ISBN: 9781319171179
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 20, Problem 20.29AP
Interpretation Introduction

Interpretation:

The structure and names of all dicarboxylic acid possible with the formula, C6H10O4, is to be stated. Among them, chiral dicarboxylic acids, dicarboxylic acids that readily form cyclic anhydrides and dicarboxylic acids that decarboxyalte on heating are to be identified.

Concept introduction:

The carboxylic acids are the organic acids which contain a carboxyl group. The general formula of carboxylic acids is RCOOH. In the general formula RCOOH R is the alkyl or aryl group.

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.
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