CHM 111/112 LAB MANUAL >C<
CHM 111/112 LAB MANUAL >C<
11th Edition
ISBN: 9781337310956
Author: SLOWINSKI
Publisher: CENGAGE LEARNING (CUSTOM)
bartleby

Videos

Textbook Question
Book Icon
Chapter 20, Problem 1ASA

In a reaction involving the iodination of acetone, the following volumes were used to make up the reaction mixture:

5 mL 4.0 M acetone  + 10 mL 1.0 M HCl  + 10 mL 0.0050 M  I 2  + 25 mL H 2 O

a. How many moles of acetone were in the reaction mixture? Recall that, for a component A, moles A = M A × V , where M A is the molarity of A and V is the volume in liters of the solution of A that was used.

__________ moles acetone

b. What was the molarity of acetone in the reaction mixture? The volume of the mixture was 50 mL, 0.050 L, and the number of moles of acetone was found in Part (a). Again,

M A = moles of  A V of soln. in liters

__________ M acetone

c. How could you double the molarity of the acetone in the reaction mixture, keeping the total volume at 50 mL and keeping the same concentrations of H + ion and I 2 as in the original mixture?

(a)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation:

The reaction of iodination of acetone, forms a reaction mixture;

  5mL 4.0 M acetone + 10 mL 1.0 M HCl + 10 mL 0.0050 M I2+ 25 mL H2O

The moles of acetone are present in the reaction mixture should be determined.

Concept Introduction:

Mole is the amount of the substance that contains the same number of particles or atoms or molecules. Molar mass is defined as an average mass of atoms present in the chemical formula. It is the sum of the atomic masses of all the atoms present in the chemical formula of any compound.

Answer to Problem 1ASA

Moles of acetone = 0.02 mol

Explanation of Solution

Given information:

Molarity of acetone = 4 M

Molarity of HCl = 1M

Molarity of I2 = 0.0050 M

Volume of acetone = 5 mL

Volume of HCl = 10 mL

Volume of I2 = 10 mL

Volume of H2O = 25 mL

  Total volume = 5 + 10 + 10 + 25                   = 50 mL                   = 0.05 L

The calculation of moles of acetone is shown below:

  moles=molarity×volume=4molL-1×0.005L=0.02mol

(b)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation:

The reaction of iodination of acetone, forms a reaction mixture;

  5mL 4.0 M acetone + 10 mL 1.0 M HCl + 10 mL 0.0050 M I2+ 25 mL H2O

The molarity of acetone in the reaction mixture should be determined when volume of mixture is 50 mL

Concept Introduction:

Mole is the amount of the substance that contains the same number of particles or atoms or molecules. Molar mass is defined as an average mass of atoms present in the chemical formula. It is the sum of the atomic masses of all the atoms present in the chemical formula of any compound.

The ratio of moles to the volume in liters is known as molarity.

Answer to Problem 1ASA

Molarity of acetone = 0.4 M

Explanation of Solution

Given information:

Molarity of acetone = 4 M

Molarity of HCl = 1M

Molarity of I2 = 0.0050 M

Volume of acetone = 5 mL

Volume of HCl = 10 mL

Volume of I2 = 10 mL

Volume of H2O = 25 mL

  Total volume = 5 + 10 + 10 + 25                   = 50 mL                   = 0.05 L

The calculation of molarity of acetone is shown below:

  Molarity=molesvolume(L)=0.02mol0.05L=0.4M

(c)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation:

The reaction of iodination of acetone, forms a reaction mixture;

  5mL 4.0 M acetone + 10 mL 1.0 M HCl + 10 mL 0.0050 M I2+ 25 mL H2O

Keeping the total volume and concentration of H+ and I2 remains same; predict how the molarity of aceteone should be doubled.

Concept Introduction:

Mole is the amount of the substance that contains the same number of particles or atoms or molecules. Molar mass is defined as an average mass of atoms present in the chemical formula. It is the sum of the atomic masses of all the atoms present in the chemical formula of any compound.

Answer to Problem 1ASA

  20mLof4Macetone+10mLof1MHCl+10mLof0.005MI2+10mLH2O

Explanation of Solution

If concentration of H+ and I2 remains the same then decreases the volume of H2O by 15 mL and increases the initial concentration of acetone with volume by 15 mL.

  20mLof4Macetone+10mLof1MHCl+10mLof0.005MI2+10mLH2O

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!
Students have asked these similar questions
(11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B Bond A Bond C a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest Bond Strongest Bond b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. c. (5pts) Use principles discussed in lecture, supported by relevant structures, to succinctly explain the why your part b (i) radical is more stable than your part b(ii) radical. Written explanation can be no more than one-two succinct sentence(s)!
. 3°C with TH 12. (10pts total) Provide the major product for each reaction depicted below. If no reaction occurs write NR. Assume heat dissipation is carefully controlled in the fluorine reaction. 3H 24 total (30) 24 21 2h • 6H total ● 8H total 34 래 Br2 hv major product will be most Substituted 12 hv Br NR I too weak of a participate in P-1 F₂ hv Statistically most favored product will be major = most subst = thermo favored hydrogen atom abstractor to LL F
Five chemistry project topic that does not involve practical

Chapter 20 Solutions

CHM 111/112 LAB MANUAL >C<

Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Text book image
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Text book image
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Text book image
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
O-Level Chemistry | 16 | Qualitative Analysis [1/3]; Author: Bernard Ng;https://www.youtube.com/watch?v=oaU8dReeBgA;License: Standard YouTube License, CC-BY