Chemistry
Chemistry
4th Edition
ISBN: 9780078021527
Author: Julia Burdge
Publisher: McGraw-Hill Education
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Chapter 20, Problem 19QP
Interpretation Introduction

Interpretation:

The nuclear binding energy and nuclear binding energyper nucleon, in joules, for a given nucleus is to be determined.

Concept introduction:

The nuclear binding energy is calculated by using the relation as follows:

ΔE=(Δm)c2

Here, Δm is the mass defect and c is the speed of light.

The mass defect is defined as the difference between the given mass and the predicted mass. Thus, the formula of themass defect is as follows:

Δm= Given mass Predicted mass

Here, Δm is the mass defect.

Expert Solution & Answer
Check Mark

Answer to Problem 19QP

Solution:

6.30×1012 J , 9.00×1013 J/nucleon

4.78×1011 J , 1.37×1012 J/nucleon.

Explanation of Solution

a) 37Li 7.01600  amu.

In the given nucleus, 37Li, the number of protons and neutrons are 3 and 4, respectively.

The mass of 3 11H atoms is as follows:

Mass of 3 11=3×mass of hydrogen=(3×1.007825 amu)=3.023475 amu

Mass of 4 neutrons =(4×mass of neutron)=(4×1.008665 amu)=4.03466 amu

The predicted mass of 37Li is calculated as follows:

Predicted mass = Mass of 3 11H+mass of 4 neutrons=(3.023475 amu+4.03466 amu)=7.058315  amu

The mass defect is calculated by using the relation as follows:

Δm=Given mass Predicted mass

Substitute 7.058315  amu for predicted mass and 7.01600  amu for a given mass.

Δm=(7.01600  amu)(7.058315  amu)=0.042135 amu.

The value of mass defect is converted into Kg by using the relation:

1 Kg=6.0221418×1026 amu(0.042135 amu×1 Kg6.022×1026 amu)=6.996×1029Kg

The nuclear binding energy is calculated by the relation as follows:

ΔE=(Δm)c2

Substitute 6.996×1029Kg for Δm and 3.00×108 m/s for c in the above expression.

ΔE=(6.996×1029Kg)(3.00×108 m/s)2=63.0×1013 Kg.m2/s2=6.30×1012 J 

The magnitude of binding energy is considered.

Now, the nuclear binding energy per nucleon is calculated as follows:

Nuclear binding energytotal number of nucleons

The number of nucleons is defined as the sum of protons and neutrons.

Thus, 7 nucleons are present in nucleus 37Li.

Substitute 6.30×1012 J  for nuclear binding energy and 7 nucleons for the total number of nucleons,

6.30×1012 J  7 nucleons=9.00×1013 J/nucleon.

Therefore, the nuclear binding energy per nucleon is 9.00×1013 J/nucleon.

b) 1735Cl 34.96885  amu.

In the given nucleus, 1735Cl, the number of protons and neutrons are 17 and 18, respectively.

The mass of 17 11H atoms is as follows:

Mass of 17 11=17×mass of hydrogen=(17×1.007825 amu)=17.133025 amu

Mass of 18 neutrons =18×mass of neutron=(18×1.008665 amu)=18.15597 amu

The predicted mass of 1735Cl is calculated as follows:

Predicted mass = Mass of 17 11H+mass of 18 neutrons=(17.133025 amu+18.15597 amu)=35.28899 amu

The mass defect is calculated by using the relation as follows:

Δm=Given mass Predicted mass

Substitute 35.28899 amu for predicted mass and 34.96885  amu for a given mass,

Δm=(34.96885  amu)(35.28899 amu)=0.320145 amu

The value of mass defect is converted into Kg by using the relation:

1 Kg=6.0221418×1026 amu(0.320145amu×1 Kg6.022×1026 amu)=5.3162×1028Kg

The nuclear binding energy is calculated by the relation as follows:

ΔE=(Δm)c2

Substitute 5.3162×1028Kg for Δm and 3.00×108 m/s for c in the above equation,

ΔE=(5.3162×1028Kg)(3.00×108 m/s)2=47.8×1012 Kg.m2/s2=4.78×1011 J 

The magnitude of binding energy is considered.

Now, the nuclear binding energy per nucleon is calculated as follows:

Nuclear binding energytotal number of nucleons

The number of nucleons is defined as the sum of protons and neutrons.

Thus, 35 nucleons are present in nucleus 1735Cl.

Substitute 4.78×1011 J  for nuclear binding energy and 35 nucleons for the total number of nucleons,

(4.78×1011 J   35 nucleons)=1.37×1012 J/nucleon

Therefore, the nuclear binding energy per nucleon is 1.37×1012 J/nucleon.

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Chapter 20 Solutions

Chemistry

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