
CHEMISTRY:CENTRAL SCIENCE-W/MOD.ACCESS
14th Edition
ISBN: 9780134809694
Author: Brown
Publisher: PEARSON
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Chapter 20, Problem 19E
(a)
Interpretation Introduction
To determine: If the given balanced chemical equation involves oxidation-reduction and the elements that undergo a change in their oxidation number if it involves oxidation-reduction.
(b)
Interpretation Introduction
To determine: If the given balanced chemical equation involves oxidation-reduction and the elements that undergo a change in their oxidation number if it involves oxidation-reduction.
(c)
Interpretation Introduction
To determine: If the given balanced chemical equation involves oxidation-reduction and the elements that undergo a change in their oxidation number if it involves oxidation-reduction.
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
Chapter 20 Solutions
CHEMISTRY:CENTRAL SCIENCE-W/MOD.ACCESS
Ch. 20.1 - What is the reducing agent in the following...Ch. 20.1 - Prob. 20.1.2PECh. 20.2 - Prob. 20.2.1PECh. 20.2 - Prob. 20.2.2PECh. 20.2 - Prob. 20.3.1PECh. 20.2 - Prob. 20.3.2PECh. 20.3 - Prob. 20.4.1PECh. 20.3 - Prob. 20.4.2PECh. 20.4 - Prob. 20.5.1PECh. 20.4 - The standard cell potential is 1.46 V for a...
Ch. 20.4 - Prob. 20.6.1PECh. 20.4 - Prob. 20.6.2PECh. 20.4 - Prob. 20.7.1PECh. 20.4 - Prob. 20.7.2PECh. 20.4 - Prob. 20.8.1PECh. 20.4 - Practice Exercise 2
Using Table 20.1, rank...Ch. 20.5 - Practice Exercise 1
Which of the following...Ch. 20.5 - Prob. 20.9.2PECh. 20.5 - Prob. 20.10.1PECh. 20.5 - Prob. 20.10.2PECh. 20.6 - Prob. 20.11.1PECh. 20.6 - Prob. 20.11.2PECh. 20.6 - Prob. 20.12.1PECh. 20.6 - Prob. 20.12.2PECh. 20.6 - Prob. 20.13.1PECh. 20.6 - Prob. 20.13.2PECh. 20.9 - Prob. 20.14.1PECh. 20.9 - Prob. 20.14.2PECh. 20 - Prob. 1DECh. 20 - Prob. 1ECh. 20 - 20.2 You may have heard that “antioxidants” are...Ch. 20 - Prob. 3ECh. 20 - Prob. 4ECh. 20 - Prob. 5ECh. 20 - Prob. 6ECh. 20 - 20.7 Consider a redox reaction for which Eo is a...Ch. 20 - Prob. 8ECh. 20 - Prob. 9ECh. 20 - Prob. 10ECh. 20 - Prob. 11ECh. 20 - Prob. 12ECh. 20 - 20.13
What is meant by the term oxidation?
On...Ch. 20 - Prob. 14ECh. 20 - Prob. 15ECh. 20 - Prob. 16ECh. 20 - Prob. 17ECh. 20 - Prob. 18ECh. 20 - Prob. 19ECh. 20 - Prob. 20ECh. 20 - Prob. 21ECh. 20 - Prob. 22ECh. 20 - Complete and balance the following half-reactions....Ch. 20 - Complete and balance the following half-reaction,...Ch. 20 - Complete and balance the following equations, and...Ch. 20 - Complete and balance the following equations, and...Ch. 20 - Prob. 27ECh. 20 - Prob. 28ECh. 20 - Prob. 29ECh. 20 - Prob. 30ECh. 20 - Prob. 31ECh. 20 - Prob. 32ECh. 20 - Prob. 33ECh. 20 - Prob. 34ECh. 20 - Prob. 35ECh. 20 - Prob. 36ECh. 20 - Prob. 37ECh. 20 - Prob. 38ECh. 20 - Prob. 39ECh. 20 - Prob. 40ECh. 20 - Prob. 41ECh. 20 - Prob. 42ECh. 20 - Prob. 43ECh. 20 - Prob. 44ECh. 20 - Prob. 45ECh. 20 - Prob. 46ECh. 20 - Assuming standard conditions, arrange the...Ch. 20 - Prob. 48ECh. 20 - Prob. 49ECh. 20 - Prob. 50ECh. 20 - Prob. 51ECh. 20 - For each of the following reactions, write a...Ch. 20 - Prob. 53ECh. 20 - Prob. 54ECh. 20 - Prob. 55ECh. 20 - Prob. 56ECh. 20 - A cell has a standard cell potential of +0.177 V...Ch. 20 - Prob. 58ECh. 20 - Prob. 59ECh. 20 - Prob. 60ECh. 20 - Prob. 61ECh. 20 - Prob. 62ECh. 20 - Prob. 63ECh. 20 - A voltaic cell utilizes the following reaction:...Ch. 20 - Prob. 65ECh. 20 - Prob. 66ECh. 20 - Prob. 67ECh. 20 - Prob. 68ECh. 20 - Prob. 69ECh. 20 - Prob. 70ECh. 20 - Prob. 71ECh. 20 - 20. 72 A voltaic cell is constructed that is based...Ch. 20 - Prob. 73ECh. 20 - Prob. 74ECh. 20 - Prob. 75ECh. 20 - Prob. 76ECh. 20 - Prob. 77ECh. 20 - In some applications nickel-cadmium batteries have...Ch. 20 - Prob. 79ECh. 20 - Prob. 80ECh. 20 - Prob. 81ECh. 20 - Prob. 82ECh. 20 - Prob. 83ECh. 20 - Prob. 84ECh. 20 - Prob. 85ECh. 20 - Prob. 86ECh. 20 - Prob. 87ECh. 20 - Prob. 88ECh. 20 - Prob. 89ECh. 20 - Prob. 90ECh. 20 - Prob. 91ECh. 20 - Metallic magnesium can be made by the electrolysis...Ch. 20 - 20.93
Calculate the mass of Li formed by...Ch. 20 - Prob. 94ECh. 20 - Prob. 95ECh. 20 - Prob. 96ECh. 20 - Prob. 97AECh. 20 - Prob. 98AECh. 20 - Prob. 99AECh. 20 - [20.100] Gold exists in two common positive...Ch. 20 - Prob. 101AECh. 20 - Prob. 102AECh. 20 - Prob. 103AECh. 20 - Prob. 104AECh. 20 - Prob. 105AECh. 20 - Prob. 106AECh. 20 - Prob. 107AECh. 20 - Prob. 108AECh. 20 - Prob. 109AECh. 20 - Prob. 110AECh. 20 - Prob. 111IECh. 20 - Prob. 112IECh. 20 - Prob. 113IECh. 20 - Prob. 114IECh. 20 - Prob. 115IECh. 20 - Prob. 116IECh. 20 - Prob. 117IECh. 20 - Prob. 118IECh. 20 - Prob. 119IE
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