Concept explainers
You have gone back in time and are working with Daltonon a table of relative masses. Following are his data:
0.602 g gas A reacts with 0.295 g gas B
0.172 g gas B reacts with 0.401 g gas C
0.320 g gas A reacts with 0.374 g gas C
a. Assuming simplest formulas (AB, BC, and AC), construct a table of relative masses for Dalton.
b. Knowing some history of chemistry, you tell Daltonthat if he determines the volumes of the gases reactedat constant temperature and pressure, he need notassume simplest formulas. You collect the following data:
Write the simplest balanced equations, and find theactual relative masses of the elements. Explain yourreasoning.
Trending nowThis is a popular solution!
Chapter 2 Solutions
EBK WEBASSIGN FOR ZUMDAHL'S CHEMICAL PR
- The early alchemists used to do an experiment in which water was boiled for several days in a sealed glass container. Eventually. some solid residue would appear in die bottom of the flask, which was interpreted to mean that some of the water in the flask had been converted into earth. When Lavoisier repeated this experiment, he found that the water weighed the same before and after heating, and the mass of die flask plus the solid residue equaled the original mass of the flask. Were the alchemists correct? Explain what really happened. (This experiment is described in the article by A. F. Scott in Scientific American, January 1984.)arrow_forwardSeveral samples of carbon dioxide are obtained and decomposed into carbon and oxygen. The masses of the carbon and oxygen are then weighed, and the results are tabulated as shown here. One of these results does not follow the law of constant composition and is therefore wrong. Which one? a. 12 grams of carbon and 32 grams of oxygen b. 4.0 grams of carbon and 16 grams of oxygen c. 1.5 grams of carbon and 4.0 grams of oxygen d. 22.3 grams of carbon and 59.4 grams of oxygenarrow_forwardSeveral samples of methane gas, the primary component of natural gas, are decomposed into carbon and hydrogen. The masses of the carbon and hydrogen are then weighed, and the results are tabulated as shown here. Which of these does not follow the law of constant composition? a. 4.0 grams hydrogen and 12.0 grams carbon b. 1.5 grams hydrogen and 4.5 grams carbon c. 7.0 grams hydrogen and 17.0 grams carbon d. 10 grams hydrogen and 30 grams carbonarrow_forward
- Copper atoms. (a) What is the average mass of one copper atom? (b) Students in a college computer science class once sued the college because they were asked to calculate the cost of one atom and could not do it. But you are in a chemistry course, and you can do this. (See E. Felsenthal, Wall Street Journal, May 9, 1995.) If the cost of 2.0-mm diameter copper wire (99.9995% pure] is currently 41.70 for 7.0 g, what is the cost of one copper atom?arrow_forwardAverage Atomic Weight Part 1: Consider the four identical spheres below, each with a mass of 2.00 g. Calculate the average mass of a sphere in this sample. Part 2: Now consider a sample that consists of four spheres, each with a different mass: blue mass is 2.00 g, red mass is 1.75 g, green mass is 3.00 g, and yellow mass is 1.25 g. a Calculate the average mass of a sphere in this sample. b How does the average mass for a sphere in this sample compare with the average mass of the sample that consisted just of the blue spheres? How can such different samples have their averages turn out the way they did? Part 3: Consider two jars. One jar contains 100 blue spheres, and the other jar contains 25 each of red, blue, green, and yellow colors mixed together. a If you were to remove 50 blue spheres from the jar containing just the blue spheres, what would be the total mass of spheres left in the jar? (Note that the masses of the spheres are given in Part 2.) b If you were to remove 50 spheres from the jar containing the mixture (assume you get a representative distribution of colors), what would be the total mass of spheres left in the jar? c In the case of the mixture of spheres, does the average mass of the spheres necessarily represent the mass of an individual sphere in the sample? d If you had 80.0 grams of spheres from the blue sample, how many spheres would you have? e If you had 60.0 grams of spheres from the mixed-color sample, how many spheres would you have? What assumption did you make about your sample when performing this calculation? Part 4: Consider a sample that consists of three green spheres and one blue sphere. The green mass is 3.00 g, and the blue mass is 1.00 g. a Calculate the fractional abundance of each sphere in the sample. b Use the fractional abundance to calculate the average mass of the spheres in this sample. c How are the ideas developed in this Concept Exploration related to the atomic weights of the elements?arrow_forwardIn 1886 Eugene Goldstein observed positively charged particles moving in the opposite direction to electrons in a cathode ray tube (illustrated below). From their mass, he concluded that these particles were formed from residual gas in the tube. For example, if the cathode ray tube contained helium, the canal rays consisted of He+ ions. Describe a process that could lead to these ions. Canal rays. In 1886, Eugene Goldstein detected a stream of particles traveling in the direction opposite to that of the negatively charged cathode rays (electrons). He called this stream of positive particles "canal rays:"arrow_forward
- These questions concern the work of J. J. Thomson: From Thomson’s work, which particles do you think he would feel are most important in the formation of compounds (chemical changes) and why? Of the remaining two subatomic particles, which do you place second in importance for forming compounds and why? Come up with three models that explain Thomson’s findings and evaluate them. To be complete you should include Thomson’s findings.arrow_forwardEach of the following statements is true, but Dalton might have had trouble explaining some of them with his atomic theory. Give explanations for the following statements. a. The space-filling models for ethyl alcohol and dimethyl ether are shown below. These two compounds have die same composition by mass (52% carbon, 13% hydrogen, and 35% oxygen), yet the two have different melting points, boiling points, and solubilities in water. b. Burning wood leaves an ash that is only a small fraction of the mass of the original wood. c. Atoms can be broken down into smaller particles. d. One sample of lithium hydride is 87.4% lithium by mass, while another sample of lithium hydride Ls 74.9% lithium by mass. However, the two samples have the same chemical properties.arrow_forwardIndium oxide contains 4.784 g of indium for every 1.000 g of oxygen. In 1869, when Mendeleev first presented his version of the periodic table, he proposed the formula ln2O3 for indium oxide. Before that time it was thought that the formula was InO. What values for the atomic mass of indium are obtained using these two formulas? Assume that oxygen has an atomic mass of 16.00.arrow_forward
- Calculate the number of atoms in the universe. The following steps will guide you through this calculation: a. Planets constitute less than 1% of the total mass of the universe and can, therefore, be neglected. Stars make up most of the visible mass of the universe, so we need to determine how many atoms are in a star. Stars are primarily composed of hydrogen atoms and our Sun is an average-sized star. Calculate the number of hydrogen atoms in our Sun given that the radius of the Sun is 7108 m and its density is 1.4g/cm3. The volume of a sphere is given by V=(43)r3 (Hint: Use the volume and the density to get the mass of the Sun.) b. The average galaxy (like our own Milky Way galaxy) contains 11011 stars, and the universe contains 1109 galaxies. Calculate the number of atoms in an average galaxy and finally the number of atoms in the entire universe. c. You can hold 11023 atoms in your hand (five copper pennies constitute 1.41023 copper atoms.) How does this number compare with the number of atoms in the universe?arrow_forwardUranium-235 is the isotope of uranium commonly used in nuclear power plants. How many (a) protons are in its nucleus? (b) neutrons are in its nucleus? (c) electrons are in a uranium atom?arrow_forwardHydrazine, ammonia, and hydrogen azide al1 contain only nitrogen and hydrogen. The mass of hydrogen that combines with 1.00 g of nitrogen for each compound is 1.44 101 g, 2.16 101 g, and 2.40 102 g, respectively. Show how these data illustrate the law of multiple proportions.arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
- Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStaxChemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub CoChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning