Chemistry: A Molecular Approach, Books a la Carte Edition (4th Edition)
4th Edition
ISBN: 9780134113593
Author: Nivaldo J. Tro
Publisher: PEARSON
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Question
Chapter 2, Problem 65E
(a)
Interpretation Introduction
To determine: Whether tellurium is a main group element or not.
(b)
Interpretation Introduction
To determine: Whether potassium is a main group element or not.
(c)
Interpretation Introduction
To determine: Whether vanadium is a main group element or not.
(d)
Interpretation Introduction
To determine: Whether manganese is a main group element or not.
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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.
Chapter 2 Solutions
Chemistry: A Molecular Approach, Books a la Carte Edition (4th Edition)
Ch. 2 - Q1. Two samples of a compound containing elements...Ch. 2 - Q2. A compound containing only carbon and hydrogen...Ch. 2 - Prob. 3SAQCh. 2 - Q4 A student recreates the Millikan’s oil drop...Ch. 2 - Q5. Determine the number of protons and neutrons...Ch. 2 - Prob. 6SAQCh. 2 - Prob. 7SAQCh. 2 - Prob. 8SAQCh. 2 - Prob. 9SAQCh. 2 - Prob. 10SAQ
Ch. 2 - Prob. 11SAQCh. 2 - Prob. 12SAQCh. 2 - Q13. Determine the number of atoms in 1.85 mL of...Ch. 2 - Prob. 14SAQCh. 2 - Prob. 15SAQCh. 2 - 1. What is Brownian motion? How is it related to...Ch. 2 - 2. Summarize the history of the atomic idea. How...Ch. 2 - 3. State and explain the law of conservation of...Ch. 2 - 4. State and explain the law of definite...Ch. 2 - Prob. 5ECh. 2 - Prob. 6ECh. 2 - Prob. 7ECh. 2 - 8. Explain Millikan’s oil drop experiment and how...Ch. 2 - Prob. 9ECh. 2 - 10. Describe the Rutherford’s gold foil...Ch. 2 - 11. Describe Rutherford’s nuclear model of the...Ch. 2 - 12. If matter is mostly empty space, as suggested...Ch. 2 - Prob. 13ECh. 2 - Prob. 14ECh. 2 - Prob. 15ECh. 2 - Prob. 16ECh. 2 - 17. What are isotopes? What is the percent natural...Ch. 2 - 18. Describe the two different notations used to...Ch. 2 - Prob. 19ECh. 2 - Prob. 20ECh. 2 - Prob. 21ECh. 2 - Prob. 22ECh. 2 - Prob. 23ECh. 2 - Prob. 24ECh. 2 - Prob. 25ECh. 2 - Prob. 26ECh. 2 - Prob. 27ECh. 2 - 28. Why is the mass corresponding to a mole of one...Ch. 2 - 29. A hydrogen-filled balloon is ignited and 1.50...Ch. 2 - 30. An automobile gasoline tank holds 21 kg of...Ch. 2 - Prob. 31ECh. 2 - 32. Two samples of sodium chloride are decomposed...Ch. 2 - Prob. 33ECh. 2 - Prob. 34ECh. 2 - Prob. 35ECh. 2 - Prob. 36ECh. 2 - Prob. 37ECh. 2 - 38. Sulfur and fluorine form several different...Ch. 2 - 39. Which statements are consistent with Dalton’s...Ch. 2 - 40. Which statements are inconsistent with...Ch. 2 - 41. Which statements are consistent with...Ch. 2 - Prob. 42ECh. 2 - 43. A chemist in an imaginary universe, where...Ch. 2 - Prob. 44ECh. 2 - 45. On a dry day, your body can accommodate static...Ch. 2 - Prob. 46ECh. 2 - 47. Which statements about subatomic particles are...Ch. 2 - Prob. 48ECh. 2 - 49. How many electrons does it take to equal the...Ch. 2 - Prob. 50ECh. 2 - 51. Write isotopic symbols in the form X-A (e.g.,...Ch. 2 - Prob. 52ECh. 2 - Prob. 53ECh. 2 - 54. Determine the number of protons and the number...Ch. 2 - Prob. 55ECh. 2 - Prob. 56ECh. 2 - Prob. 57ECh. 2 - 58. Determine the number of protons and the number...Ch. 2 - Prob. 59ECh. 2 - 60. Predict the charge of the ion formed by each...Ch. 2 - Prob. 61ECh. 2 - Prob. 62ECh. 2 - Prob. 63ECh. 2 - Prob. 64ECh. 2 - Prob. 65ECh. 2 - Prob. 66ECh. 2 - Prob. 67ECh. 2 - Prob. 68ECh. 2 - 69. Which pair of elements do you expect to be...Ch. 2 - 70. Which pair of elements do you expect to be...Ch. 2 - 71. Gallium has two naturally occurring isotopes...Ch. 2 - Prob. 72ECh. 2 - Prob. 73ECh. 2 - Prob. 74ECh. 2 - Prob. 75ECh. 2 - 76. An element has four naturally occurring...Ch. 2 - 77. Bromine has two naturally occurring isotopes...Ch. 2 - 78. Silicon has three naturally occurring isotopes...Ch. 2 - 79. Use the mass spectrum of europium to determine...Ch. 2 - 80. Use the mass spectrum of rubidium to determine...Ch. 2 - 81. How many sulfur atoms are there in 5.52 mol of...Ch. 2 - Prob. 82ECh. 2 - Prob. 83ECh. 2 - Prob. 84ECh. 2 - Prob. 85ECh. 2 - Prob. 86ECh. 2 - 87. Calculate the number of atoms in each...Ch. 2 - 88. Calculate the number of atoms in each...Ch. 2 - 89. Calculate the mass, in grams, of each...Ch. 2 - Prob. 90ECh. 2 - Prob. 91ECh. 2 - Prob. 92ECh. 2 - 93. Calculate the average mass, in grams, of one...Ch. 2 - 94. Using scanning tunneling microscopy,...Ch. 2 - 95. A 7.83 g sample of HCN contains 0.290 g of H...Ch. 2 - Prob. 96ECh. 2 - 97. The ratio of oxygen to carbon by mass in...Ch. 2 - 98. The ratio of the mass of a nitrogen atom to...Ch. 2 - Prob. 99ECh. 2 - Prob. 100ECh. 2 - Prob. 101ECh. 2 - Prob. 102ECh. 2 - Prob. 103ECh. 2 - Prob. 104ECh. 2 - 105. Fill in the blanks to complete the...Ch. 2 - Prob. 106ECh. 2 - 107. Carbon-12 contains six protons and six...Ch. 2 - 108. A penny has a thickness of approximately 1.0...Ch. 2 - 109. Consider the stack of pennies in the previous...Ch. 2 - Prob. 110ECh. 2 - Prob. 111ECh. 2 - Prob. 112ECh. 2 - 113. A pure copper sphere has a radius of 0.935...Ch. 2 - Prob. 114ECh. 2 - Prob. 115ECh. 2 - 116. Boron has only two naturally occurring...Ch. 2 - Prob. 117ECh. 2 - Prob. 118ECh. 2 - Prob. 119ECh. 2 - 120. Naturally occurring chlorine is composed of...Ch. 2 - Prob. 121ECh. 2 - 122. The US Environmental Protection Agency (EPA)...Ch. 2 - 123. Pure gold is usually too soft for jewelry, so...Ch. 2 - Prob. 124ECh. 2 - Prob. 125ECh. 2 - 126. On the previous page is a representation of...Ch. 2 - Prob. 127ECh. 2 - Prob. 128ECh. 2 - Prob. 129ECh. 2 - Prob. 130ECh. 2 - Prob. 131ECh. 2 - 132. Which answer is an example of the law of...Ch. 2 - 133. Lithium has two naturally occurring isotopes:...Ch. 2 - 134. As we saw in the previous problem, lithium...Ch. 2 - Prob. 135ECh. 2 - Prob. 136ECh. 2 - Prob. 137ECh. 2 - Prob. 138QGWCh. 2 - Prob. 139QGWCh. 2 - Prob. 140QGWCh. 2 - Prob. 141QGWCh. 2 - 142. Demand for recycled paper has increased as...
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