ORGANIC CHEMISTRY BOOK& SG/SM
6th Edition
ISBN: 9781264094493
Author: SMITH
Publisher: MCG
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7. The standard reduction potentials for two half-reactions are shown above. Which of the
statements listed below will be true for the following reaction taking place under standard
conditions?
a. E°
b. E°
c. E°
=
d. E°
e. E° =
Al (s) + Cr³+
→ Al³+ + Cr (s)
0.93 V, and the reaction is not spontaneous
0.93 V, and the reaction is spontaneous
2.39 V, and the reaction is not spontaneous
2.39 V, and the reaction is not spontaneous
0.93 V, and the reaction is spontaneous
Cu2+ + 2e
→ Cu
E° = +0.34 V
Zn2+ + 2e
→ Zn
E° = -0.76 V
E° = -1.18 V
Mn2+ + 2e → Mn
8. Based on the above reduction potential, which of the following reactions will occur
spontaneously?
a. Mn²+ + Cu → Mn + Cu2+
b. Mn²+ + Zn → Mn + Zn²+
c. Zn2+ + Cu → Zn + Cu²+
d. Zn²+ + Mn → Zn + Mn2+
e. Cu²+ + Zn²+ → Cu + Zn
14.35 For which compounds can a second resonance structure be drawn?
Draw an additional resonance structure and the hybrid for each
resonance-stabilized compound.
a.
OCH3
OCH 3
b.
C.
d.
CH3
NHCH3
pls help on all, inlcude all steps.
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