Masteringchemistry With Pearson Etext -- Valuepack Access Card -- For Principles Of Chemistry: A Molecular Approach
3rd Edition
ISBN: 9780133890686
Author: Tro
Publisher: PEARSON
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Chapter 2, Problem 54E
(a)
Interpretation Introduction
Interpretation: The number of protons and neutrons in
(b)
Interpretation Introduction
Interpretation: The number of protons and neutrons in
(c)
Interpretation Introduction
Interpretation: The number of protons and neutrons in
(d)
Interpretation Introduction
Interpretation: The number of protons and neutrons in
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
CI
OH
CI
カー
11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
Same position
+
Likely
to oc
occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
stagere
Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
-2
B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
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Parent name (noname)
4 Bromo
Sub = 2-methylethyl-4 Bromo nonane
b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
# -2
-2
Chapter 2 Solutions
Masteringchemistry With Pearson Etext -- Valuepack Access Card -- For Principles Of Chemistry: A Molecular Approach
Ch. 2 - Two samples of a compound containing elements A...Ch. 2 - Q2. A compound containing only carbon and hydrogen...Ch. 2 - Prob. 3SAQCh. 2 - Q4 A student recreates the Millikan’s oil drop...Ch. 2 - Q5. Determine the number of protons and neutrons...Ch. 2 - Prob. 6SAQCh. 2 - Prob. 7SAQCh. 2 - Prob. 8SAQCh. 2 - Prob. 9SAQCh. 2 - Prob. 10SAQ
Ch. 2 - Prob. 11SAQCh. 2 - Prob. 12SAQCh. 2 - Prob. 13SAQCh. 2 - Prob. 14SAQCh. 2 - Prob. 15SAQCh. 2 - Prob. 1ECh. 2 - 2. Summarize the history of the atomic idea. How...Ch. 2 - 3. State and explain the law of conservation of...Ch. 2 - Prob. 4ECh. 2 - Prob. 5ECh. 2 - Prob. 6ECh. 2 - Prob. 7ECh. 2 - 8. Explain Millikan’s oil drop experiment and how...Ch. 2 - Prob. 9ECh. 2 - 10. Describe the Rutherford’s gold foil...Ch. 2 - 11. Describe Rutherford’s nuclear model of the...Ch. 2 - 12. If matter is mostly empty space, as suggested...Ch. 2 - Prob. 13ECh. 2 - Prob. 14ECh. 2 - Prob. 15ECh. 2 - Prob. 16ECh. 2 - 17. What are isotopes? What is the percent natural...Ch. 2 - 18. Describe the two different notations used to...Ch. 2 - Prob. 19ECh. 2 - Prob. 20ECh. 2 - Prob. 21ECh. 2 - Prob. 22ECh. 2 - Prob. 23ECh. 2 - Prob. 24ECh. 2 - Prob. 25ECh. 2 - Prob. 26ECh. 2 - Prob. 27ECh. 2 - 28. Why is the mass corresponding to a mole of one...Ch. 2 - 29. A hydrogen-filled balloon is ignited and 1.50...Ch. 2 - 30. An automobile gasoline tank holds 21 kg of...Ch. 2 - Prob. 31ECh. 2 - 32. Two samples of sodium chloride are decomposed...Ch. 2 - Prob. 33ECh. 2 - Prob. 34ECh. 2 - Prob. 35ECh. 2 - Prob. 36ECh. 2 - Prob. 37ECh. 2 - 38. Sulfur and fluorine form several different...Ch. 2 - 39. Which statements are consistent with Dalton’s...Ch. 2 - 40. Which statements are inconsistent with...Ch. 2 - 41. Which statements are consistent with...Ch. 2 - Prob. 42ECh. 2 - 43. A chemist in an imaginary universe, where...Ch. 2 - Prob. 44ECh. 2 - 45. On a dry day, your body can accommodate static...Ch. 2 - Prob. 46ECh. 2 - 47. Which statements about subatomic particles are...Ch. 2 - Prob. 48ECh. 2 - 49. How many electrons does it take to equal the...Ch. 2 - Prob. 50ECh. 2 - 51. Write isotopic symbols in the form X-A (e.g.,...Ch. 2 - Prob. 52ECh. 2 - Prob. 53ECh. 2 - 54. Determine the number of protons and the number...Ch. 2 - Prob. 55ECh. 2 - Prob. 56ECh. 2 - Prob. 57ECh. 2 - 58. Determine the number of protons and the number...Ch. 2 - Prob. 59ECh. 2 - 60. Predict the charge of the ion formed by each...Ch. 2 - Prob. 61ECh. 2 - Prob. 62ECh. 2 - Prob. 63ECh. 2 - Write the symbolfor each element and classify it...Ch. 2 - Prob. 65ECh. 2 - Prob. 66ECh. 2 - Prob. 67ECh. 2 - Prob. 68ECh. 2 - 69. Which pair of elements do you expect to be...Ch. 2 - 70. Which pair of elements do you expect to be...Ch. 2 - 71. Gallium has two naturally occurring isotopes...Ch. 2 - Prob. 72ECh. 2 - Prob. 73ECh. 2 - Prob. 74ECh. 2 - Prob. 75ECh. 2 - 76. An element has four naturally occurring...Ch. 2 - 77. Bromine has two naturally occurring isotopes...Ch. 2 - 78. Silicon has three naturally occurring isotopes...Ch. 2 - 79. Use the mass spectrum of europium to determine...Ch. 2 - 80. Use the mass spectrum of rubidium to determine...Ch. 2 - 81. How many sulfur atoms are there in 5.52 mol of...Ch. 2 - Prob. 82ECh. 2 - Prob. 83ECh. 2 - Prob. 84ECh. 2 - Prob. 85ECh. 2 - Prob. 86ECh. 2 - 87. Calculate the number of atoms in each...Ch. 2 - 88. Calculate the number of atoms in each...Ch. 2 - 89. Calculate the mass, in grams, of each...Ch. 2 - Prob. 90ECh. 2 - Prob. 91ECh. 2 - Prob. 92ECh. 2 - 93. Calculate the average mass, in grams, of one...Ch. 2 - 94. Using scanning tunneling microscopy,...Ch. 2 - 95. A 7.83 g sample of HCN contains 0.290 g of H...Ch. 2 - Prob. 96ECh. 2 - 97. The ratio of oxygen to carbon by mass in...Ch. 2 - 98. The ratio of the mass of a nitrogen atom to...Ch. 2 - An particle, 4He2+, has a mass of 4.00151 amu....Ch. 2 - Prob. 100ECh. 2 - Prob. 101ECh. 2 - Prob. 102ECh. 2 - Prob. 103ECh. 2 - Prob. 104ECh. 2 - 105. Fill in the blanks to complete the...Ch. 2 - Prob. 106ECh. 2 - 107. Carbon-12 contains six protons and six...Ch. 2 - 108. A penny has a thickness of approximately 1.0...Ch. 2 - 109. Consider the stack of pennies in the previous...Ch. 2 - Prob. 110ECh. 2 - Prob. 111ECh. 2 - Prob. 112ECh. 2 - 113. A pure copper sphere has a radius of 0.935...Ch. 2 - 116. Boron has only two naturally occurring...Ch. 2 - Prob. 115ECh. 2 - Prob. 116ECh. 2 - Prob. 117ECh. 2 - 120. Naturally occurring chlorine is composed of...Ch. 2 - Prob. 119ECh. 2 - 122. The US Environmental Protection Agency (EPA)...Ch. 2 - 123. Pure gold is usually too soft for jewelry, so...Ch. 2 - Prob. 122ECh. 2 - Prob. 123ECh. 2 - 126. On the previous page is a representation of...Ch. 2 - Prob. 125ECh. 2 - Prob. 126ECh. 2 - Prob. 127ECh. 2 - Prob. 128ECh. 2 - Prob. 129ECh. 2 - 132. Which answer is an example of the law of...Ch. 2 - 133. Lithium has two naturally occurring isotopes:...Ch. 2 - 134. As we saw in the previous problem, lithium...Ch. 2 - Prob. 133ECh. 2 - Prob. 134ECh. 2 - Prob. 135E
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