PRINCIPLES OF MODERN CHEMISTRY
8th Edition
ISBN: 9780357671009
Author: OXTOBY
Publisher: CENGAGE L
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Question
Chapter 2, Problem 54AP
Interpretation Introduction
Interpretation:
The percentage yield of the given reaction for the production of acetylene is to be calculated.
Concept introduction:
The percentage yield of a reaction can be calculated as follows:
The theoretical yield means the amount of the product which is obtained by calculations. The actual yield is the yield which is obtained via an experiment.
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36. Give the major product(s) of each of the following reactions. Aqueous work-up steps (when necessary) have
been omitted.
a. CH3CH=CHCH3
b.
CH3CH2CH2CCH3
H,PO₂, H₂O, A
(Hint: See Section 2-2.)
1. LIAIH. (CH,CH,),O
2. H', H₂O
H
NaBH, CH,CH₂OH
d.
Br
LIAIH. (CH,CH,)₂O
f.
CH3
NaBH, CH,CH,OH
(CH3)2CH
H
NaBH, CH,CH₂OH
H
Predict the major products of this reaction:
+ H
excess
NaOH
Δ
?
Note that the second reactant is used in excess, that is, there is much more of the second reactant than the first.
If there won't be any products, just check the box under the drawing area instead.
An organic chemistry Teaching Assistant (TA) suggested in your last discussion section that there is only one major organic product of the following reaction and
that this reaction builds a ring.
If the TA is right, draw the product in the drawing area below. If the TA is wrong, just check the box below the drawing area.
1. NaOMe
CH3O
N.
OCH3
?
2. H3O+
Chapter 2 Solutions
PRINCIPLES OF MODERN CHEMISTRY
Ch. 2 - A newly synthesized compound has the molecular...Ch. 2 - Acetaminophen is the generic name of the pain...Ch. 2 - Arrange the following compounds from left to right...Ch. 2 - Arrange the following compounds from left to right...Ch. 2 - “Q-gas” is a mixture of 98.70% helium and 1.30%...Ch. 2 - A pharmacist prepares an antiulcer medicine by...Ch. 2 - Zinc phosphate is used as a dental cement. A...Ch. 2 - Bromoform is 94.85% bromine, 0.40% hydrogen, and...Ch. 2 - Fulgurites are the products of the melting that...Ch. 2 - A sample of a “suboxide” of cesium gives up...
Ch. 2 - Barium and nitrogen form two binary compounds...Ch. 2 - Prob. 12PCh. 2 - Prob. 13PCh. 2 - Prob. 14PCh. 2 - The empirical formula of a gaseous fluorocarbon is...Ch. 2 - At its boiling point (280°C) and at atmospheric...Ch. 2 - A gaseous binary compound has a vapor density that...Ch. 2 - A gaseous binary compound has a vapor density that...Ch. 2 - Prob. 19PCh. 2 - Prob. 20PCh. 2 - For each of the following chemical reactions,...Ch. 2 - Prob. 22PCh. 2 - An 18.6-g sample of K2CO3 was treated in such a...Ch. 2 - Prob. 24PCh. 2 - Disilane (Si2H6) is a gas that reacts with oxygen...Ch. 2 - Tetrasilane (Si4H10) is a liquid with a density of...Ch. 2 - Cryolite (Na3AlF6) is used in the production of...Ch. 2 - Carbon disulfide (CS2) is a liquid that is used in...Ch. 2 - Potassium nitrate (KNO3) is used as a fertilizer...Ch. 2 - Elemental phosphorus can be prepared from...Ch. 2 - An element X has a dibromide with the empirical...Ch. 2 - An element A has a triiodide with the formula AI3...Ch. 2 - A mixture consisting of only sodium chloride...Ch. 2 - A mixture of aluminum and iron weighing 9.62 g...Ch. 2 - When ammonia is mixed with hydrogen chloride...Ch. 2 - The poisonous gas hydrogen cyanide (HCN) is...Ch. 2 - The iron oxide Fe2O3 reacts with carbon monoxide...Ch. 2 - Titanium dioxide, TiO2 , reacts with carbon and...Ch. 2 - Human parathormone has the impressive...Ch. 2 - A white oxide of tungsten is 79.2976% tungsten by...Ch. 2 - A dark brown binary compound contains oxygen and...Ch. 2 - A binary compound of nickel and oxygen...Ch. 2 - Two binary oxides of the element manganese...Ch. 2 - A possible practical way to eliminate oxides of...Ch. 2 - Aspartame (molecularformula C14H18N2O5 ) is a...Ch. 2 - Prob. 46APCh. 2 - Prob. 47APCh. 2 - Citric acid (C6H8O7) is made by fermentation of...Ch. 2 - Prob. 49APCh. 2 - A sample of a substance with the empirical formula...Ch. 2 - A newspaper article about the danger of global...Ch. 2 - In the Solvay process for producing sodium...Ch. 2 - A yield of 3.00gKClO4 is obtained from the...Ch. 2 - Prob. 54APCh. 2 - Silicon nitride (Si3N4) , a valuable ceramic, is...
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Similar questions
- Complete the reaction in the drawing area below by adding the major products to the right-hand side. If there won't be any products, because nothing will happen under these reaction conditions, check the box under the drawing area instead. Note: if the products contain one or more pairs of enantiomers, don't worry about drawing each enantiomer with dash and wedge bonds. Just draw one molecule to represent each pair of enantiomers, using line bonds at the chiral center. + More... ☐ ☐ : ☐ + G 1. NaOMe Click and drag to start drawing a structure. 2. H +arrow_forward6. Ammonia reacts with nitrogen monoxide and oxygen to form nitrogen and water vapor. If the rate of consumption of NO is 4.5 mollitermin) (a) Find the rate of reaction (b) Find the rate of formations of N; and HO (c) Find the rate of consumption of NH, and O 4NH: 4NO 0:4: +60arrow_forward34. Give the expected major product of each of the following reactions. Conc. HI a. CH3CH2CH2OH b. (CH3)2CHCH2CH2OH Conc. HBr H Conc. HI C. OH Conc.HCI d. (CH3CH2)3COHarrow_forward
- 42. Which of the following halogenated compounds can be used successfully to prepare a Grignard reagent for alcohol synthesis by subsequent reaction with an aldehyde or ketone? Which ones cannot and why? H3C CH3 a. Br H OH b. Cl C. I H H d. Cl e. H OCH3 Br Harrow_forwardFor each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? Will the first MgBr product that forms in this reaction create a new CC bond? olo ? OH جمله O Yes Ⓒ No MgCl ? Will the first product that forms in this reaction create a new CC bond? Click and drag to start drawing a structure. Yes No X ☐ : ☐ टे PHarrow_forwardAssign all the protonsarrow_forward
- 9 7 8 C 9 8 200 190 B 5 A -197.72 9 8 7 15 4 3 0: ང་ 200 190 180 147.52 134.98 170 160 150 140 130 120 110 100 90 90 OH 10 4 3 1 2 -143.04 140. 180 170 160 150 140 130 120 110 100 90 CI 3 5 1 2 141.89 140.07 200 190 180 170 160 150 140 130 120 110 100 ៖- 90 129. 126.25 80 70 60 -60 50 40 10 125.19 -129.21 80 70 3.0 20 20 -8 60 50 10 ppm -20 40 128.31 80 80 70 60 50 40 40 -70.27 3.0 20 10 ppm 00˚0-- 77.17 30 20 20 -45.36 10 ppm -0.00 26.48 22.32 ―30.10 ―-0.00arrow_forwardAssign all the carbonsarrow_forwardC 5 4 3 CI 2 the Righ B A 5 4 3 The Lich. OH 10 4 5 3 1 LOOP- -147.52 T 77.17 -45.36 200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 ppm B -126.25 77.03 200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 ppm 200 190 180 170 160 150 140 130 120 110 100 90 80 TO LL <-50.00 70 60 50 40 30 20 10 ppm 45.06 30.18 -26.45 22.36 --0.00 45.07 7.5 1.93 2.05 -30.24 -22.36 C A 7 8 5 ° 4 3 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 ppm 9 8 5 4 3 ཡི་ OH 10 2 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 5 4 3 2 that th 7 I 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 115 2.21 4.00 1.0 ppm 6.96 2.76 5.01 1.0 ppm 6.30 1.00arrow_forward
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