Chemistry-Stud. Solution Guide
9th Edition
ISBN: 9781285697185
Author: ZUMDHAL
Publisher: CENGAGE L
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Textbook Question
Chapter 2, Problem 53E
- a. Classify the following elements as metals or nonmetals:
| Mg | Si | Rn |
| Ti | Ge | Rn |
| Au | B | Am |
| Bi | At | Br |
- b. The distinction between metals and nonmetals is really not a clear one. Some elements, called metalloids, are intermediate in their properties. Which of these elements would you reclassify as metalloids? What other elements in the periodic table would you expect to be metalloids?
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Question 11 of 18 (1 point) Question Attempt: 3 of
How many signals do you expect in the 'H NMR spectrum for this molecule?
Br
Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red.
Note for advanced students: In this question, any multiplet is counted as one signal.
Number of signals in the 'H NMR spectrum.
1
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional Hs to color in top
molecule
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box…
Organic Chemistry
Esterification reactions
1. Write the steps to prepare ester.
2. Write complete reaction of ethanol and acetic acid to make ester.
3. What does ester smell like? What are the uses of ester.
4. What the role of sulfuric acid in the esterification reaction
11. Complete the following esterification reaction with names of all the reactants and products under.
Hint: Remove the water and end up with ester
R-C-OH + ROH
R-C-OR + H₂O
A carboxylic acid
An alcohol
An ester
Water
BYJU'S
H-C-C
O-H
Нин
C-C-C-H
HAAA
H O-C-C-C-H
AAA
Ethanoic acid
Propanol
Water Propyl ethanoate
By com
CH3COOH + CH3CH2CH2CH₂CH₂OH →
Practice for alcohols aldehydes and ketones:
12. Draw the structures from the following names mixed of alcohol/aldehyde and ketone:
a. 4-methyl cyclohexanone
b. 3-methyl-2-pentenal
c. 2,3-dimethylcyclohexanone
d. 1,3propanediol or Propane 1,3 diol
13. Write systematic names for the following compounds identify
functional group:
a.
b. (CH3)2CH-C
OH
c) CH(CH₂)--
OH
-,-,
Chapter 2 Solutions
Chemistry-Stud. Solution Guide
Ch. 2 - Use Daltons atomic theory to account for each of...Ch. 2 - What evidence led to the conclusion that cathode...Ch. 2 - What discoveries were made by J. J. Thomson, Henri...Ch. 2 - Consider Ernest Rutherfords -particle bombardment...Ch. 2 - Do the proton and the neutron have exactly the...Ch. 2 - What is the distinction between atomic number and...Ch. 2 - Distinguish between the terms family and period in...Ch. 2 - The compounds AlCl3, CrCl3, and ICl3 have similar...Ch. 2 - Prob. 9RQCh. 2 - How would you name HBrO4, KIO3, NaBrO2, and HIO?...
Ch. 2 - Which of the following is true about an individual...Ch. 2 - How would you go about finding the number of chalk...Ch. 2 - These questions concern the work of J. J. Thomson....Ch. 2 - Prob. 4ALQCh. 2 - You have a chemical in a sealed glass container...Ch. 2 - The formula of water is If-O. Which of the...Ch. 2 - You may have noticed that when water boils, you...Ch. 2 - One of the best indications of a useful theory is...Ch. 2 - Prob. 9ALQCh. 2 - Prob. 10ALQCh. 2 - Label each of the following as an atomic element,...Ch. 2 - Prob. 12ALQCh. 2 - Prob. 13ALQCh. 2 - Prob. 14ALQCh. 2 - Which of tire following explain how an ion is...Ch. 2 - What refinements had to be made in Daltons atomic...Ch. 2 - When hydrogen is burned in oxygen to form water,...Ch. 2 - The two most reactive families of elements are the...Ch. 2 - Explain the law of conservation of mass, the law...Ch. 2 - Section 2.3 describes the postulates of Daltons...Ch. 2 - The contributions of J. J. Thomson and Ernest...Ch. 2 - Prob. 22QCh. 2 - The number of protons in an atom determines the...Ch. 2 - If the volume of a proton were similar to the...Ch. 2 - Prob. 25QCh. 2 - List some characteristic properties that...Ch. 2 - Consider the elements of Group 4A (the carbon...Ch. 2 - Distinguish between the following terms. a....Ch. 2 - Label the type of bonding for each of the...Ch. 2 - The vitamin niacin (nicotinic acid. C6H5NO2) can...Ch. 2 - Prob. 31QCh. 2 - Prob. 32QCh. 2 - When mixtures of gaseous H2 and gaseous Cl2 react,...Ch. 2 - Observations of the reaction between nitrogen gas...Ch. 2 - A sample of chloroform is found to contain 12.0 g...Ch. 2 - A sample of H2SO4 contains 2.02 g of hydrogen,...Ch. 2 - Hydrazine, ammonia, and hydrogen azide all contain...Ch. 2 - Consider 100.0-g samples of two different...Ch. 2 - The three most stable oxides of carbon ire carbon...Ch. 2 - Two elements. R and Q, combine to form two binary...Ch. 2 - In Section 1.1 of the text, the concept of a...Ch. 2 - In a combustion reaction, 46.0 g of ethanol reacts...Ch. 2 - Early tables of atomic weights (masses) were...Ch. 2 - Indium oxide contains 4.784 g of indium for every...Ch. 2 - Prob. 45ECh. 2 - If you wanted to make an accurate scale model of...Ch. 2 - In an experiment it was found that the total...Ch. 2 - A chemist in a galaxy tar, far away performed the...Ch. 2 - What are the symbols of the following metals:...Ch. 2 - What are the symbols of the following nonmetals:...Ch. 2 - Give the names of the nonmetals that correspond to...Ch. 2 - a. Classify the following elements as metals or...Ch. 2 - a. List the noble gas elements. Which of the noble...Ch. 2 - For each of the following sets of elements, label...Ch. 2 - Prob. 56ECh. 2 - Prob. 57ECh. 2 - Write the atomic symbol (ZAX) for each of the...Ch. 2 - Write the symbol of each atom using the ZAX...Ch. 2 - For carbon-14 and carbon-12, how many protons and...Ch. 2 - How many protons and neutrons are in the nucleus...Ch. 2 - Prob. 62ECh. 2 - For each of the following ions, indicate the...Ch. 2 - How many protons, neutrons, and electrons are in...Ch. 2 - Prob. 65ECh. 2 - What is the symbol of an ion with 16 protons, 18...Ch. 2 - Complete the following table: Symbol Number of...Ch. 2 - Complete the following table: Symbol Number of...Ch. 2 - Would you expect each of the following atoms to...Ch. 2 - Prob. 70ECh. 2 - Name the compounds in parts ad and write the...Ch. 2 - Name the compounds in parts a-d and write the...Ch. 2 - Prob. 73ECh. 2 - Prob. 74ECh. 2 - Prob. 75ECh. 2 - Prob. 76ECh. 2 - Prob. 77ECh. 2 - Prob. 78ECh. 2 - Prob. 79ECh. 2 - Prob. 80ECh. 2 - Prob. 81ECh. 2 - Prob. 82ECh. 2 - Prob. 83ECh. 2 - Write the formula for each of the following...Ch. 2 - Prob. 85ECh. 2 - Write the formula for each of the following...Ch. 2 - Prob. 87ECh. 2 - Each of the following compounds is incorrectly...Ch. 2 - Chlorine has two natural isotopes: 1737Cl and...Ch. 2 - What are the symbols for the following nonmetal...Ch. 2 - Four Fe2+ ions are key components of hemoglobin,...Ch. 2 - Which of the following statements is(are) true?...Ch. 2 - The isotope of an unknown element, X, has a mass...Ch. 2 - Prob. 94AECh. 2 - Prob. 95AECh. 2 - Identify each of the following elements: a. a...Ch. 2 - Prob. 97AECh. 2 - Prob. 98AECh. 2 - Prob. 99AECh. 2 - Prob. 100AECh. 2 - Prob. 101AECh. 2 - Prob. 102AECh. 2 - Complete the following table. Atom/Ion Protons...Ch. 2 - Which of the following is{are) correct? a. 40Ca2...Ch. 2 - Prob. 105CWPCh. 2 - Prob. 106CWPCh. 2 - Prob. 107CWPCh. 2 - Prob. 108CWPCh. 2 - Reaction of 2.0 L of hydrogen gas with 1.0 L of...Ch. 2 - A combustion reaction involves the reaction of a...Ch. 2 - A chemistry instructor makes the following claim:...Ch. 2 - The early alchemists used to do an experiment in...Ch. 2 - Consider the chemical reaction as depicted below....Ch. 2 - Each of the following statements is true, but...Ch. 2 - You have two distinct gaseous compounds made from...Ch. 2 - A single molecule has a mass of 7.31 1023 g....Ch. 2 - You take three compounds, each consisting of two...Ch. 2 - Prob. 119IPCh. 2 - Prob. 120IPCh. 2 - Using the information in Table 2.1, answer the...
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- may you please show all steps! i am having a hard time understanding and applying in this format, thank you!arrow_forward10. Complete the substitution reaction of 2 pentanol with these reagents. Reagents & Reaction Conditions use practice sheet. Please write only major products, minor product like water, other gases are not required. Hint: In substitution of alcohol, we generally substitute OH group with Halogens like cl, Br, F using some reagent containing halogens. Ensure to add halogens to the same carbon number where you are removing OH from Examples Alcohols can be converted to Alkyl Halides with HX acids HBr H₂O HCI + H₂O HI + H₂O CH,CH₂OH + SOCI₂ CH,CH₂OH + PCI₁₂ A BBYJU'S CH CHCI + SO₂+ HCI CH₂CH CIP(OH), + HCI CH,CH₂OH + PCI CHCHCI + POCI + HCI CH,CH₂OH + PBr, CH,CH,Br + P(OH), + HBr 1. Reaction with HBr with 2 Pentanol 2.Reaction with HI with 2 pentanol © Byjus.com 3.Reaction with HCI+ZnCl,, with 2 pentanol (Zncl2 is catalyst no role) 4.Reaction with SOCI,, with 2 Pentanol 5.Reaction with PBr; or PCl, with 2 pentanolarrow_forward3. Is 2-methyl-2-propanol a primary, secondary, or tertiary alcohol? Write out the structures of 2-methyl-2-propanol and also any oxidation products of 2- methyl-2- propanol. If there is more than one oxidation product, give the structure of each of the products. 4. 2-Propanol is the IUPAC systematic name of this alcohol. It has a common name by which it is much better known (You'll see it in the grocery store or pharmacy). Give that common name 5. Aldehydes can be synthesized by the oxidation of. Please choose from below choices A. Primary alcohols B. Secondary alcohols C. Organic acids D. Inorganic acids 6. Tertiary alcohol Can undergo oxidation. yes or no. ? If yes then answer the product.arrow_forward
- Finish the reactions hand written pleasearrow_forwardPart A Identify each alcohol as primary, secondary, or tertiary Drag the appropriate items to their respective bins. CH₂ H₂C- -C-OH HO CH₂ Primary Он OH CH₂ OH CCH₂OH CH₂ сн Secondary Tertiary Reset Help CH,CH₂ (CH)CHCH,OH CH,CH,CH,CCH, CHOH CH₂ Different types of alcohol groups Alcohol and its reaction: 8. Combing two alcohol molecules below and completing the reaction with Product .( Hint Reaction called etherification as ether is formed and name the ether once you complete the reaction. Hint.: R-O-H+H-O-RR-O-R Do the reaction: CH₂OH + CH₂OH---→ + H-O-H 9. Write the reaction of formation of alcohol from alkene by adding water: Addition reaction also called hydration reaction as we are adding water which occur always in presence of acid Hint: Break the double bond and add H and OH if symmetrical then add anywhere if unsymmetrical then follow Markovnikov rule H should go to that double bone carbon which has more hydrogen CH2=CH2 + H₂O-→arrow_forwardComplete the reaction hand written pleasearrow_forward
- Predict the major products of this organic reaction: HBr (1 equiv) cold ? Some important notes: • Draw the major product, or products, of this reaction in the drawing area below. • You can draw the products in any arrangement you like. • Pay careful attention to the reaction conditions, and only include the major products. • Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers. • Note that there is only 1 equivalent of HBr reactant, so you need not consider the case of multiple additions. dm Re Explanation Check ©2025 McGraw Hill LLC. All Rights Reserved. Termarrow_forwardb) Use curved arrows to show the reaction of the radical with hydrogen bromide. Br: Br H .. Answer Bankarrow_forwardIndicate the reaction products when CH3COCH2COOCH2COOC2H5 (ethyl acetoacetoacetate) reacts with 1º OH-/H2O and 2º H3O+arrow_forward
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