Pushing Electrons
4th Edition
ISBN: 9781133951889
Author: Weeks, Daniel P.
Publisher: Cengage Learning
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Consider the following SN 2 reaction:
مار
+
Br
H₂O
acetone
+ Br
OH
What effect would each of the following changes have on the rate of this reaction. Select the single best answer for each part.
Part 1 of 3
If the substrate was changed to:
The rate would
Br
O increase
O decrease
O remain unchanged
Part 2 of 3
×
S
If the nucleophile was changed to OH, the rate would:
O increase
O decrease
O remain unchanged
Part 3 of 3
If the solvent was changed to ethanol, the rate would:
Increase
O decrease
O remain unchanged
2
ol
Ar
Consider the following nucleophilic substitution reaction. The compound listed above the arrow is the solvent for the reaction. If nothing is listed over the arrow,
then the nucleophile is also the solvent for the reaction.
Part: 0/2
Part 1 of 2
Br
acetone
+ I
What is the correct mechanism for the reaction? Select the single best answer.
OSN 1
OSN 2
X
Part: 1/2
Part 2 of 2
Draw the products for the reaction. Include both the major organic product and the inorganic product. If more than one stereoisomer is possible, draw
only one stereoisomer. Include stereochemistry where relevant.
Click and drag to start drawing a
structure.
Х
5
☐
Triethyloxonium tetrafluoroborate reacts with ethanol (CH3CH2OH) to give diethyl ether (CH3CH2OCH2CH3).
BF
triethyloxonium tetrafluoroborate
Which equation, including the curved arrows, best represents the rate-determining step in the mechanism? Select the single best answer.
O
OH
CH3CH2
OH
+
H.
0+
CH₂H₂
:0
+
0+
ж
+
H
+
:0:
0
C
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- CH3CH2CH=CH2 + H₂O − H+arrow_forwardГ C-RSA CHROMATOPAC CH=1 DATA 1: @CHRM1.C00 ATTEN=10 SPEED= 10.0 0.0 b.092 0.797 1.088 1.813 C-RSA CHROMATOPAC CH=1 Report No. =13 ** CALCULATION REPORT ** DATA=1: @CHRM1.000 11/03/05 08:09:52 CH PKNO TIME 1 2 0.797 3 1.088 4 1.813 AREA 1508566 4625442 2180060 HEIGHT 207739 701206 V 287554 V MK IDNO CONC NAME 18.1447 55.6339 26.2213 TOTAL 8314067 1196500 100 C-R8A CHROMATOPAC CH=1 DATA 1: @CHRM1.C00 ATTEN=10 SPEED= 10.0 0. 0 087 337. 0.841 1.150 C-R8A CHROMATOPAC CH=1 Report No. =14 DATA=1: @CHRM1.000 11/03/05 08:12:40 ** CALCULATION REPORT ** CH PKNO TIME AREA 1 3 0.841 1099933 41.15 4039778 HEIGHT MK IDNO 170372 649997¯¯¯ CONC NAME 21.4007 78.5993 TOTAL 5139711 820369 100 3 C-R8A CHROMATOPAC CH=1 DATA 1: @CHRM1.C00 ATTEN=10 SPEED= 10.0 0.100 0:652 5.856 3 1.165 C-RSA CHROMATOPAC CH-1 Report No. =15 DATA=1: @CHRM1.000 11/03/05 08:15:26 ** CALCULATION REPORT ** CH PKNO TIME AREA HEIGHT MK IDNO CONC NAME 1 3 3 0.856 4 1.165 TOTAL 1253386 4838738 175481 708024 V 20.5739 79.4261 6092124…arrow_forwardIndicate the product that is obtained if the benzotriazole reacts with the use of a medium basic product.arrow_forward
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- How do I break down the reaction shown on the chalkboard and explain it correctly using the bromonium ion mechanism, instead of the (disproven) carbocation-based mechanismarrow_forward¿Qué the product is obtained from tetraethoxypropano and hidrazina?. Indicate the reason why the corresponding dial is used.arrow_forwardIf CH3COCH2CH(OCH3)2 is reacted with hydrazine, two isomeric products are formed. Indicate their structures and the major product.arrow_forward
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