ORGANIC CHEMISTRY (LOOSELEAF)
6th Edition
ISBN: 9781260475630
Author: SMITH
Publisher: MCG
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Predict the stronger acid in each pair: (a) HNO3 or HNO2;(b) H2S or H2O; (c) H2SO4 or H2SeO4; (d) CH3COOH or CCl3COOH.
NaHCO3 can deprotonate benzoic acid but cannot deprotonate phenol. On the other hand,
NaOH can deprotonate both benzoic acid and phenol. Given this information, rank the
molecules numbered I to V in order of decreasing acidity.
COH
cOH
он
H,0
H,CO,
IV
CH3
II
I
II
(A)
V > II >I > III >
IV
(В)
II > 1 > V >
III
IV
(C)
II > V >I > IV > II
Molecules like acetamide (CH3CONH2) can be protonated on either their O or N atoms when treated with a strong acid like HCl. Which site is more readily protonated and why?
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Similar questions
- Will acetylene react with sodium hydride according to the following equation to form a salt and hydrogen, H2? Using pKa values given in Table 4.1, calculate Keq for this equilibrium.arrow_forwardThe Keq for the reaction: A + B ↔ AB is 4.32 What is the Keq for 2 A + 2 B ↔ 2 AB Keq = ?arrow_forwardCalculate the equilibrium constant for the acid–base reaction between the reactants in each of the following pairs: (a) HCl + H2O (b) CH3COOH + H2O (c) CH3NH2 + H2O (d) CH3N+H3 + H2Oarrow_forward
- Predict whether aqueous solutions of the following substances are acidic, basic, or neutral and write hydrolysis equations for the acidic and basic solutions. (a) CsBr; (b) Al(NO3)3; (c) KCN; (d) CH3NH3Clarrow_forward18). The formulas and the structures of two acids are shown below. Which acid is a stronger acid? If the acid strength of the two acids is equal, say so. Cl2CHCOOH CH3COOH но но CI-C-C-OH н-с-с-он ČI Ką = 0.0324 Ką = 1.82 x 10-5 %3D a. Cl¿CHCOOH is a stronger acid than CH;COOH. b. CH;COOH is a stronger acid than CI½CHCOOH c. The two have equal acid strength. d. none of the abovearrow_forwardWhich is the stronger base, (CH3)3N or H2 BO3− ?arrow_forward
- (a) Given that Ka for acetic acid is 1.8 x 10-5 and that hypochlorous acid is 3.0 x10-8 , which is a stronger acid? (b) Which is the stronger base, the acetate ion or the hypochlorite ion? (c) calculate the Kb values for the CHCOO- and ClO- .arrow_forward1/ Hydrolysis of CH;CH,NO, with 85% H,SO, gives? 2/ When benzyl alcohol is oxidised with KMNO4, the product obtained ? 3/ In the below sequence of reactions, A and B? NaCN (CH3),CO- (HCI) 4/ Which of the following is the strongest acid? CH;COOH , BRCH,COOH , CICH,COOH , FCH,COOH 5/ Which substituted benzoic acid is most acidic? .CO2H CH3 .co,H CO2H CI .CO2H CH, 6/ Which acid is strongest or Which is most acidic? а) Cl,CH.COOН b) CICH,COOН c) CH;COOH d) CI3C.COOH 71. In the anion HCOO- the two carbon-oxygen bonds are found to be of equal length. What is the reason for it?arrow_forward3. A 0.0560 g quantity of acetic acid is dissolved in enough water to make 50.0 mL of solution. Calculate the concentrations of H;O*, CH;COO and CH;COOH at equilibrium. What is the pH of the solution? (Ka = 1.8x10) CH;COOH(aq) = CH;COO (aq) + H;O* (aq) a) Calculate the initial concentration of CH;COOH. (C:12; H:1; 0:16) b) Calculate the concentration of CH;CoO (aq) and H;O* (aq) at equilibrium. c) Calculate pH of the solution.arrow_forward
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