EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG
EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG
4th Edition
ISBN: 9781119659525
Author: Klein
Publisher: WILEY CONS
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Chapter 2, Problem 42PP
Interpretation Introduction

Interpretation: The bond-line structures of all the constitutional isomers of the following compound should be drawn:

  CH3CH2CH(CH3)2

Concept Introduction: The molecules that possess same molecular formula but differ in structural arrangement of atoms in the molecule are said to be isomers of each other.

A method used to represent molecular structures of compounds is said to be bond line notation. In this notation, a line depicts a bond between two atoms and are drawn in a zigzag format. Atoms other than carbon and hydrogens are specifically depicted in this notation. It is assumed that carbon atoms are bonded to enough hydrogen atoms that are required to complete the octet.

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For a titration of 40.00 mL of 0.0500 M oxalic acid H2C2O4 with 0.1000 M KOH, calculate the pH at each of the following volume of KOH used in the titration: 1) before the titration begin;2) 15 mL; 3) 20 mL; 4) 25 mL; 5) 40 mL; 6) 50 mL. Ka1 = 5.90×10^-2, Ka2 = 6.50×10^-5 for oxalic acid.
Predict the major organic product(s), if any, of the following reactions.  Assume all reagents are in excess unless otherwise indicated.
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