Concept explainers
Interpretation:
The solubility behavior of Cetylethyldimethylammonium bromide in water and diethyl ether is to be predicted.
Concept Introduction:
▸ A general rule of solubility is: like dissolves like.
▸ Polar and ionic solids are dissolved in polar solvents.
▸ Nonpolar solids are dissolved in nonpolar solvents.
▸ Cetylethyldimethylammonium bromide is a salt and contains some ionic characteristics.
▸ The water is a polar solvent and according to the solubility rule, the ionic solids are soluble in water. The organic cation and the bromide ion are solvated by the water molecule.
▸ Diethyl ether is an organic compound.
▸ The hydrophobic part that is alkyl group is lipophilic and nonpolar. Due to the attractive dispersion forces between alkyl group and ether molecule. The compound Cetylethyldimethylammonium bromide is soluble in ether.
▸ The species resistant to water or the species that are incompatible with water are termed as hydrophobic.
▸ The water loving species or the species compatible with water are termed as hydrophilic species.
▸ If the compound contains one hydrophilic group and more than six carbon atoms, then the compound is insoluble in water.
▸ Alkyl chains with high molecular weight are hydrophobic in nature.
▸ The hydroxyl group is hydrophilic in nature because it forms hydrogen bonding with water molecules.
▸ The carbonyl oxygen and hydroxyl group of
▸ A hydrogen bond is a partially electrostatic force of attraction between a hydrogen atom which is bound to more electronegative atom such as nitrogen, oxygen or fluorine and another atom bearing a lone pair of electron.
Want to see the full answer?
Check out a sample textbook solutionChapter 2 Solutions
EBK ORGANIC CHEMISTRY
- Calculate the atomic packing factor of diamond knowing that the number of Si atoms per cm3 is 2.66·1022 and that the atomic radii of silicon and oxygen are, respectively, 0.038 and 0.117 nm.arrow_forwardA pdf file of your hand drawn, stepwise mechanisms for the reactions. For each reaction in the assignment, you must write each mechanism three times (there are 10 reactions, so 30 mechanisms). (A) do the work on a tablet and save as a pdf., it is expected to write each mechanism out and NOT copy and paste the mechanism after writing it just once. Everything should be drawn out stepwise and every bond that is formed and broken in the process of the reaction, and is expected to see all relevant lone pair electrons and curved arrows. Aldol: NaOH HO H Δ NaOH Δarrow_forwardNonearrow_forward
- Draw structures corresponding to the following names and give IUPAC names for the following compounds: (8 Point) a) b) c) CH3 CH2CH3 CH3CHCH2CH2CH CH3 C=C H3C H H2C=C=CHCH3 d) CI e) (3E,5Z)-2,6-Dimethyl-1,3,5,7-octatetraene f) (Z)-4-bromo-3-methyl-3-penten-1-yne g) cis-1-Bromo-2-ethylcyclopentane h) (5R)-4,4,5-trichloro-3,3-dimethyldecanearrow_forwardNonearrow_forwardReview: Design a total total synthesis synthesis of the following compound using methyloxacyclopropane and any other necessary reagents.arrow_forward
- Nonearrow_forwardDraw a Newman projection from carbon 3 to carbon 2 in the highest energy conformation for the following molecule. What is this conformation called? What kind of strain is present? Brarrow_forwardWhich of the following dienophiles is most reactive in a Diels-Alder reaction: Please explain why the correct answer to this question is option 5. Please provide a detailed explanation.arrow_forward
- Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co