Chemistry In Focus
7th Edition
ISBN: 9781337670425
Author: Tro
Publisher: Cengage
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Chapter 2, Problem 39E
A
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Using the conditions of spontaneity to deduce the signs of AH and AS
Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy
AS.
Note: if you have not been given enough information to decide a sign, select the "unknown" option.
reaction
observations
conclusions
A
This reaction is always spontaneous, but
proceeds slower at temperatures above
120. °C.
ΔΗ is
(pick one)
AS is
(pick one)
ΔΗ is
(pick one)
B
This reaction is spontaneous except above
117. °C.
AS is
(pick one)
ΔΗ is
(pick one)
This reaction is slower below 20. °C than
C
above.
AS is
|(pick one)
?
18
Ar
1
Calculating the pH at equivalence of a titration
Try Again
Your answer is incorrect.
0/5
a
A chemist titrates 70.0 mL of a 0.7089 M hydrocyanic acid (HCN) solution with 0.4574M KOH solution at 25 °C. Calculate the pH at equivalence. The pK of
hydrocyanic acid is 9.21.
Round your answer to 2 decimal places.
Note for advanced students: you may assume the total volume of the solution equals the initial volume plus the volume of KOH solution added.
pH
=
11.43]
G
00.
18
Ar
B•
Chapter 2 Solutions
Chemistry In Focus
Ch. 2 - The volume of a liquid can be measured with a...Ch. 2 - Scientific Notation Express the number 0.0000023...Ch. 2 - Prob. 2SCCh. 2 - Prob. 3SCCh. 2 - Converting Between Units Convert 34.0 cm to...Ch. 2 - Prob. 2.3YTCh. 2 - Extracting Information from Graphical Data The...Ch. 2 - Solving Word Problems...Ch. 2 - Solving Word Problems Involving Units Raised to a...Ch. 2 - Prob. 2.7YT
Ch. 2 - Prob. 2.8YTCh. 2 - Without doing any calculations, determine whether...Ch. 2 - Prob. 1ECh. 2 - Prob. 2ECh. 2 - Prob. 3ECh. 2 - What is the difference between reporting the...Ch. 2 - Prob. 5ECh. 2 - Prob. 6ECh. 2 - Prob. 7ECh. 2 - Prob. 8ECh. 2 - Prob. 9ECh. 2 - What is a conversion factor? Give two examples of...Ch. 2 - Prob. 11ECh. 2 - Identify the decimal part, the exponential part,...Ch. 2 - What is density? Give two examples of possible...Ch. 2 - Since oil floats on water, what can you say about...Ch. 2 - Express each of the following in scientific...Ch. 2 - Express each of the following numbers in...Ch. 2 - Express each of the following in decimal notation:...Ch. 2 - Express each of the following in decimal notation:...Ch. 2 - The circumference of Earth at the equator is...Ch. 2 - The distance from New York to Los Angeles is 2777...Ch. 2 - A can of soda contains 12 fluid ounces. What is...Ch. 2 - A laboratory beaker can hold 150mL. How many fluid...Ch. 2 - A car has a fuel efficiency of 27 miles per...Ch. 2 - A European rental car can travel 17 km on a liter...Ch. 2 - Perform each of the following conversions within...Ch. 2 - Perform each of the following conversions within...Ch. 2 - Prob. 27ECh. 2 - Perform the following conversions between the...Ch. 2 - A pond has a surface area of 1552m2. Convert this...Ch. 2 - An orange has a volume of 54cm3. Convert this...Ch. 2 - Prob. 31ECh. 2 - Prob. 32ECh. 2 - A runner runs at a pace of 8.5 minutes per mile....Ch. 2 - A driver drives an average speed of 58 miles per...Ch. 2 - A sports utility vehicle gets 12 miles per gallon...Ch. 2 - A hybrid electric vehicle (HEV) is a car with both...Ch. 2 - The following graph shows the concentration of an...Ch. 2 - The following graph shows the historical...Ch. 2 - A 28.4-cm3 sample of titanium has a mass of...Ch. 2 - A 1.5-cm3 sample of silicon has a mass of 3.5 g....Ch. 2 - A 5.00-L sample of pure glycerol has a mass of...Ch. 2 - A 3.80-mL sample of mercury has a mass of 51.4g....Ch. 2 - Ethylene glycol (antifreeze) has a density of...Ch. 2 - A thief plans to steal a bar of gold from a womans...Ch. 2 - Prob. 45ECh. 2 - A proton has a radius of approximately 110-13 cm...Ch. 2 - What did Einstein mean when he said, The most...Ch. 2 - Prob. 48ECh. 2 - Prob. 49ECh. 2 - Prob. 50ECh. 2 - Prob. 51ECh. 2 - Consider each of the following balances. Which one...Ch. 2 - Each of the following coins is photographed to...Ch. 2 - Obtain an outdoor thermometer and record the...
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- Using the conditions of spontaneity to deduce the signs of AH and AS Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy AS. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction observations conclusions A The reverse of this reaction is always spontaneous but proceeds faster at temperatures above -48. °C. ΔΗ is (pick one) ✓ AS is (pick one) B This reaction is spontaneous except below 114. °C but proceeds at a slower rate below 135. °C. ΔΗ is (pick one) AS is (pick one) ΔΗ is C This reaction is exothermic and proceeds faster at temperatures above -43. °C. (pick one) AS is (pick one) v Х 5 ? 18 Ararrow_forwardion. A student proposes the following Lewis structure for the perchlorate (CIO) io : :0: : Cl : - - : :0: ك Assign a formal charge to each atom in the student's Lewis structure. atom central O formal charge ☐ top O ☐ right O ☐ bottom O ☐ Cl ☐arrow_forwardDecide whether these proposed Lewis structures are reasonable. proposed Lewis structure Yes. Is the proposed Lewis structure reasonable? Cl- : 2: :Z: :Z: N—N : 0: C C1: O CO No, it has the wrong number of valence electrons. The correct number is: ☐ No, it has the right number of valence electrons but doesn't satisfy the octet rule. The symbols of the problem atoms are:* ☐ Yes. No, it has the wrong number of valence electrons. The correct number is: ☐ No, it has the right number of valence electrons but doesn't satisfy the octet rule. The symbols of the problem atoms are:* | Yes. No, it has the wrong number of valence electrons. The correct number is: No, it has the right number of valence electrons but doesn't satisfy the octet rule. The symbols of the problem atoms are:* | If two or more atoms of the same element don't satisfy the octet rule, just enter the chemical symbol as many times as necessary. For example, if two oxygen atoms don't satisfy the octet rule, enter "0,0". ☑arrow_forward
- Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy AS. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction observations conclusions ΔΗ is (pick one) A This reaction is faster above 103. °C than below. AS is (pick one) ΔΗ is (pick one) B This reaction is spontaneous only above -9. °C. AS is (pick one) ΔΗ is (pick one) C The reverse of this reaction is always spontaneous. AS is (pick one) 18 Ararrow_forwardUse the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy AS. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction observations conclusions A The reverse of this reaction is always spontaneous but proceeds slower at temperatures below 41. °C. ΔΗ is (pick one) AS is (pick one) ΔΗ is (pick one) B This reaction is spontaneous except above 94. °C. AS is (pick one) This reaction is always spontaneous, but ΔΗ is (pick one) C proceeds slower at temperatures below −14. °C. AS is (pick one) Х 00. 18 Ar 무ㅎ B 1 1arrow_forwardDraw the product of the reaction shown below. Ignore inorganic byproducts. + H CH3CH2OH HCI Drawingarrow_forward
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