SaplingPlus for Lehninger Principles of Biochemistry (Six-Month Access)
SaplingPlus for Lehninger Principles of Biochemistry (Six-Month Access)
7th Edition
ISBN: 9781319108236
Author: David L. Nelson, Michael M. Cox
Publisher: W. H. Freeman
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Chapter 2, Problem 32P
Summary Introduction

To determine: The pH of insect secretion if the concentration of formate ion is 0.0015 M , molar concentration of formate ion and formic acid is 1.45 M .

Introduction:

The Henderson-Hasselbalch equation depicts the measurement of acidity as pH (potential of hydrogen) in biochemical reactions. The isoelectric point and pH of buffers are calculated by this reaction. The pH is used to calculate the pKa of molecules. The “ionized and unionized” concentrations of chemicals are estimated with the help of this equation. The pKa is used to calculate the pH of molecules.

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(11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B Bond A Bond C a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest Bond Strongest Bond b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. c. (5pts) Use principles discussed in lecture, supported by relevant structures, to succinctly explain the why your part b (i) radical is more stable than your part b(ii) radical. Written explanation can be no more than one-two succinct sentence(s)!
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