Smartwork5 Printed Access Card for Use with Chemistry: The Science in Context 5th Edition (SmartWork Access Printed Access Card)
5th Edition
ISBN: 9780393615296
Author: Rein V. Kirss (Author), Natalie Foster (Author), Geoffrey Davies (Author) Thomas R. Gilbert (Author)
Publisher: W. W. Norton
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Chapter 2, Problem 2.9VP
Interpretation Introduction
Interpretation: The element among the highlighted elements in the periodic table given in Figure
Concept introduction: The periodic table consists of metals, nonmetals and metalloids. It is stated by cosmology theories that neutrons, protons, and electrons are formed within seconds of the Big Bang. The process of creating atomic nuclei that is more complex than hydrogen is followed by nucleosynthesis.
To determine: The highlighted elements that is not formed by the fusion of lighter elements in the cores of giant starts.
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Draw the anti-Markovnikov product of the hydration of this alkene.
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Note for advanced students: draw only one product, and don't worry about showing any stereochemistry. Drawing dash and wedge bonds has been disabled for
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Explanation
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
Chapter 2 Solutions
Smartwork5 Printed Access Card for Use with Chemistry: The Science in Context 5th Edition (SmartWork Access Printed Access Card)
Ch. 2.3 - Prob. 1PECh. 2.3 - Prob. 2PECh. 2.4 - Prob. 3PECh. 2.5 - Prob. 4PECh. 2.6 - Prob. 5PECh. 2.6 - Prob. 6PECh. 2.7 - Prob. 7PECh. 2.7 - Prob. 8PECh. 2.7 - Prob. 9PECh. 2.7 - Prob. 10PE
Ch. 2.7 - Prob. 11PECh. 2 - Prob. 2.1VPCh. 2 - Prob. 2.2VPCh. 2 - Prob. 2.3VPCh. 2 - Prob. 2.4VPCh. 2 - Prob. 2.5VPCh. 2 - Prob. 2.6VPCh. 2 - Prob. 2.7VPCh. 2 - Prob. 2.8VPCh. 2 - Prob. 2.9VPCh. 2 - Prob. 2.10VPCh. 2 - Prob. 2.11QPCh. 2 - Prob. 2.12QPCh. 2 - Prob. 2.13QPCh. 2 - Prob. 2.14QPCh. 2 - Prob. 2.15QPCh. 2 - Prob. 2.16QPCh. 2 - Prob. 2.17QPCh. 2 - Prob. 2.18QPCh. 2 - Prob. 2.19QPCh. 2 - Prob. 2.20QPCh. 2 - Prob. 2.21QPCh. 2 - Prob. 2.22QPCh. 2 - Prob. 2.23QPCh. 2 - Prob. 2.24QPCh. 2 - Prob. 2.25QPCh. 2 - Prob. 2.26QPCh. 2 - Prob. 2.27QPCh. 2 - Prob. 2.28QPCh. 2 - Prob. 2.29QPCh. 2 - Prob. 2.30QPCh. 2 - Prob. 2.31QPCh. 2 - Prob. 2.32QPCh. 2 - Prob. 2.33QPCh. 2 - Prob. 2.34QPCh. 2 - Prob. 2.35QPCh. 2 - Prob. 2.36QPCh. 2 - Prob. 2.37QPCh. 2 - Prob. 2.38QPCh. 2 - Prob. 2.39QPCh. 2 - Prob. 2.40QPCh. 2 - Prob. 2.41QPCh. 2 - Prob. 2.42QPCh. 2 - Prob. 2.43QPCh. 2 - Prob. 2.44QPCh. 2 - Prob. 2.45QPCh. 2 - Prob. 2.46QPCh. 2 - Prob. 2.47QPCh. 2 - Prob. 2.48QPCh. 2 - Prob. 2.49QPCh. 2 - Prob. 2.50QPCh. 2 - Prob. 2.51QPCh. 2 - Prob. 2.52QPCh. 2 - Prob. 2.53QPCh. 2 - Prob. 2.54QPCh. 2 - Prob. 2.55QPCh. 2 - Prob. 2.56QPCh. 2 - Prob. 2.57QPCh. 2 - Prob. 2.58QPCh. 2 - Prob. 2.59QPCh. 2 - Prob. 2.60QPCh. 2 - Prob. 2.61QPCh. 2 - Prob. 2.62QPCh. 2 - Prob. 2.63QPCh. 2 - Prob. 2.64QPCh. 2 - Prob. 2.65QPCh. 2 - Prob. 2.66QPCh. 2 - Prob. 2.67QPCh. 2 - Prob. 2.68QPCh. 2 - Prob. 2.69QPCh. 2 - Prob. 2.70QPCh. 2 - Prob. 2.71QPCh. 2 - Prob. 2.72QPCh. 2 - Prob. 2.73QPCh. 2 - Prob. 2.74QPCh. 2 - Prob. 2.75QPCh. 2 - Prob. 2.76QPCh. 2 - Prob. 2.77QPCh. 2 - Prob. 2.78QPCh. 2 - Prob. 2.79QPCh. 2 - Prob. 2.80QPCh. 2 - Prob. 2.81QPCh. 2 - Prob. 2.82QPCh. 2 - Prob. 2.83QPCh. 2 - Prob. 2.84QPCh. 2 - Prob. 2.85QPCh. 2 - Prob. 2.86QPCh. 2 - Prob. 2.87QPCh. 2 - Prob. 2.88QPCh. 2 - Prob. 2.89QPCh. 2 - Prob. 2.90QPCh. 2 - Prob. 2.91QPCh. 2 - Prob. 2.92QPCh. 2 - Prob. 2.93QPCh. 2 - Prob. 2.94QPCh. 2 - Prob. 2.95QPCh. 2 - Prob. 2.96QPCh. 2 - Prob. 2.97QPCh. 2 - Prob. 2.98QPCh. 2 - Prob. 2.99QPCh. 2 - Prob. 2.100QPCh. 2 - Prob. 2.101QPCh. 2 - Prob. 2.102QPCh. 2 - Prob. 2.103QPCh. 2 - Prob. 2.104QPCh. 2 - Prob. 2.105QPCh. 2 - Prob. 2.106QPCh. 2 - Prob. 2.107APCh. 2 - Prob. 2.108APCh. 2 - Prob. 2.109APCh. 2 - Prob. 2.110APCh. 2 - Prob. 2.111APCh. 2 - Prob. 2.112APCh. 2 - Prob. 2.113APCh. 2 - Prob. 2.114APCh. 2 - Prob. 2.115APCh. 2 - Prob. 2.116APCh. 2 - Prob. 2.117APCh. 2 - Prob. 2.118APCh. 2 - Prob. 2.119APCh. 2 - Prob. 2.120APCh. 2 - Prob. 2.121APCh. 2 - Prob. 2.122APCh. 2 - Prob. 2.123APCh. 2 - Prob. 2.124APCh. 2 - Prob. 2.125APCh. 2 - Prob. 2.126APCh. 2 - Prob. 2.127APCh. 2 - Prob. 2.128AP
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