Introductory Chemistry, Books a la Carte Edition & Modified MasteringChemistry with Pearson eText -- ValuePack Access Card -- for Introductory Chemistry Package
1st Edition
ISBN: 9780133877939
Author: Nivaldo J. Tro
Publisher: PEARSON
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Textbook Question
Chapter 2, Problem 29E
What density? Explain why density can work as a conversion factor. Between what quantities does it convert?
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each pair of substrates below, choose the one that will react faster in a substitution reaction, assuming that:
1. the rate of substitution doesn't depend on nucleophile concentration and
2. the products are a roughly 50/50 mixture of enantiomers.
Substrate A
Substrate B
Faster Rate
X
Ś
CI
(Choose one)
(Choose one)
CI
Br
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Br
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
The
H
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HỌC—C—0—CH, CH,
2
A
ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
Chapter 2 Solutions
Introductory Chemistry, Books a la Carte Edition & Modified MasteringChemistry with Pearson eText -- ValuePack Access Card -- for Introductory Chemistry Package
Ch. 2 - Q1.Express the number 0.000042 in scientific...Ch. 2 - Q2. A graduated cylinder has markings every...Ch. 2 - How many significant figures are in the number...Ch. 2 - Round the number 89.04997 to three significant...Ch. 2 - Q5.Perform this multiplication to the correct...Ch. 2 - Q6.Perform this addition to the correct number of...Ch. 2 - Q7. Perform this calculation to the correct number...Ch. 2 - Convert 76.8 cm to m. a. 0.0768 m b. 7.68 m c....Ch. 2 - Q9.Convert 2855 mg to kg.
a.
b. 2.855 kg
c....Ch. 2 - Q10. A runner runs 4875 ft in 6.85 minutes. What...
Ch. 2 - An automobile travels 97.2 km on 7.88 L of...Ch. 2 - Convert 876.9 in.3 tom3. a. 0.01437m3 b. 22.27 m3...Ch. 2 - Q14. A cube measures 2.5cm on each edge and has a...Ch. 2 - What is the mass of 225 mL of a liquid that has a...Ch. 2 - Q16. What is the edge length of a 155-g iron cube?...Ch. 2 - 1. Why is it necessary to include units when...Ch. 2 - Why are the number of digits reported in...Ch. 2 - Why is scientific notation useful?Ch. 2 - If a measured quantity is written correctly, which...Ch. 2 - 5. When do zeros count as significant digits, and...Ch. 2 - 6. How many significant digits are there in exact...Ch. 2 - 7. What limits the number of significant digits in...Ch. 2 - What limits the number of significant digits in a...Ch. 2 - 9. How do we determine significant figures in...Ch. 2 - What are the rules for rounding number?Ch. 2 - 11. What are the basic SI units of length, mass,...Ch. 2 - 12. List the common units of volume.
Ch. 2 - Suppose you are trying to measure the diameter of...Ch. 2 - What is the difference between mass and weight?Ch. 2 - 15. Using a metric ruler, measure these objects to...Ch. 2 - Using a stopwatch, measure each time to the...Ch. 2 - Explain why units are important in calculations.Ch. 2 - How are units treated in a calculation?Ch. 2 - 19. What is a conversion factor?
Ch. 2 - Why does the fundamental value of a quantity not...Ch. 2 - Write the conversion factor that converts a...Ch. 2 - Write conversion factors for each. a. miles to...Ch. 2 - This book outlines a four-step problem-solving...Ch. 2 - Experienced problem solvers always consider both...Ch. 2 - 25. Draw solution map to convert a measurement in...Ch. 2 - Draw a solution map to convert a measurement in...Ch. 2 - 27. Draw a solution map to convert a measurement...Ch. 2 - Draw a solution map to convert a measurement in...Ch. 2 - What density? Explain why density can work as a...Ch. 2 - Explain how you would calculate the density of a...Ch. 2 - Prob. 31ECh. 2 - Prob. 32ECh. 2 - Note: The exercises in the problems section are...Ch. 2 - Express each number in scientific notation. a....Ch. 2 - 35. Express each number in decimal notation (i.e.,...Ch. 2 - 36. Express each number in decimal notation (i.e.,...Ch. 2 - 37. Express each number in decimal notation (i.e.,...Ch. 2 - 38. Express each number in decimal notation (i.e.,...Ch. 2 - 39. Complete the table.
Decimal...Ch. 2 - Complete the table. Decimal Notation Scientific...Ch. 2 - 41. Read each instrument to the correct number of...Ch. 2 - Read each instrument to the correct number of...Ch. 2 - For each measured quantity, underline the zeros...Ch. 2 - For each measured quantity, underline the zeros...Ch. 2 - How many significant figures are in each measured...Ch. 2 - Significant Figures
46. How many significant...Ch. 2 - 47 Correct any entries in the table that are...Ch. 2 - Correct any entries in the table that are wrong....Ch. 2 - Round each number to four significant figures. a....Ch. 2 - Round each number to three significant figures. a....Ch. 2 - 51. Round each number to two significant...Ch. 2 - 52. Round each number to three significant...Ch. 2 - 53. Each number is supposed to be rounded to three...Ch. 2 - Each number is supposed to be rounded to two...Ch. 2 - Round the number on the left to the number of...Ch. 2 - 56. Round the number on the left to the number of...Ch. 2 - Perform each calculation to the correct number of...Ch. 2 - Perform each calculation to the correct number of...Ch. 2 - 59. Correct any answers that have the incorrect...Ch. 2 - 60. Correct any answers that have the incorrect...Ch. 2 - Perform each calculation to the correct number of...Ch. 2 - Perform each calculation to the correct number of...Ch. 2 - Correct any answers that have the incorrect number...Ch. 2 - Correct any answers that have the incorrect number...Ch. 2 - Perform each calculation to the correct number of...Ch. 2 - 66. Perform each calculation to the correct number...Ch. 2 - Correct any answers that have the incorrect number...Ch. 2 - Correct any answers that have the incorrect number...Ch. 2 - Perform each conversion. a.3.55 kg to grams b.8944...Ch. 2 - Perform each conversion. a.155.5 cm to meters...Ch. 2 - Perform each conversion. a.5.88 dL to liters b....Ch. 2 - 72. Perform each conversion.
a.1.08 Mm to...Ch. 2 - Perform each conversion. a. 22.5 in. to...Ch. 2 - Perform each conversion. a. 78.3 in. to...Ch. 2 - Perform each conversion. a.40.0 cm to inches b....Ch. 2 - 76. Perform each conversion.
a.254 cm to inches
b....Ch. 2 - 77. Complete the...Ch. 2 - 78. Complete the...Ch. 2 - 79. Convert g to each unit.
a.kg
b.Mg
c.mg
d....Ch. 2 - Convert 188106 g to each unit. a. mg b. cg c. ng...Ch. 2 - A student loses 3.3 lb in one month. How many...Ch. 2 - 82. A student gains 1.9 lb in two weeks. How many...Ch. 2 - A runner wants to run 10.0 km. She knows that her...Ch. 2 - A cyclist rides at an average speed of 24 mi/h. If...Ch. 2 - 85. A recipe calls for 5.0 qt of milk. What is...Ch. 2 - A gas can hold 2.0 gal of gasoline. What is this...Ch. 2 - 87. Fill in the blanks.
a.
b.
c.
Ch. 2 - Prob. 88ECh. 2 - The hydrogen atom has a volume of approximately...Ch. 2 - 90. Earth has a surface area of 197 million square...Ch. 2 - 91. A house has an area of What is its area in...Ch. 2 - A classroom has a volume of 285m3. What is its...Ch. 2 - Total U.S farmland occupies 954 million acres. How...Ch. 2 - 94. Total average U.S farm occupies 435 acres. How...Ch. 2 - A sample of an unknown metal has a mass of 35.4...Ch. 2 - A new penny has a mass 2.49 g and a valume of...Ch. 2 - Glycerol is a syrupy liquid often used in...Ch. 2 - 102. An aluminum engine block has a valume of 4.77...Ch. 2 - A supposedly gold crown is tested to determine its...Ch. 2 - 104. A vase is said to be solid platinum. It...Ch. 2 - Ethylene glycol (antifreeze) has a density of...Ch. 2 - Acetone (fingernailpolish remover) has density of...Ch. 2 - A thief uses a bag of sand to replace a gold...Ch. 2 - One of the particles in an atom is the proton. A...Ch. 2 - A block of metal has a volume 13.4in.3 and weight...Ch. 2 - 110. A log is either oak or pine. it displaces 2.7...Ch. 2 - 111. The density of aluminum is . What is its...Ch. 2 - 112. The density of platinum is . What is its...Ch. 2 - A typical backyard swimming pool holds 150 yd3 of...Ch. 2 - 114. An iceberg has a volume of . What is the mass...Ch. 2 - The mass of fuel in an airplane must be determined...Ch. 2 - Prob. 112ECh. 2 - Honda produces a hybrid electric car called the...Ch. 2 - You rent a car in Germany with a gas mileage...Ch. 2 - Prob. 115ECh. 2 - 120. A hybrid SUV consumes fuel at a rate of 12.8...Ch. 2 - Prob. 117ECh. 2 - Consider these observations on two blocks of...Ch. 2 - 123. You measure the masses and volumes of two...Ch. 2 - A bag contains a mixture of copper and lead BBs....Ch. 2 - Prob. 121ECh. 2 - A copper cube has a mass of 87.2 g. Find the edge...Ch. 2 - 127. Recall from Section 2.1 that NASA lost the...Ch. 2 - 28. A NASA satellite showed that in 2012 the ozone...Ch. 2 - 129. In 1999, scientists discovered a new class of...Ch. 2 - 130. A titanium bicycle frame contains the same...Ch. 2 - 132. The following statements are all true.
a....Ch. 2 - Convert the height of each group member from feet...
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- in the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstantarrow_forwardtrue or false, given that a 20.00 mL sample of NaOH took 24.15 mL of 0.141 M HCI to reach the endpoint in a titration, the concentration of the NaOH is 1.17 M.arrow_forwardin the bromothymol blue experiment, pKa was measured. A closely related compound has a Ka of 2.10 x 10-5. What is the pKa?a) 7.1b) 4.7c) 2.0arrow_forward
- calculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forwardtrue or falsegiven these two equilibria with their equilibrium constants:H2(g) + CI2(l) ↔ 2HCI(g) K= 0.006 CI2(l) ↔ CI2(g) K= 0.30The equilibrium contstant for the following reaction is 1.8H2(g) + CI2 ↔ 2HCI(g)arrow_forwardI2(g) + CI2(g) ↔ 2ICIK for this reaction is 81.9. Find the equilibrium concentration of I2 if the inital concentration of I2 and CI2 are 0.010 Marrow_forward
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