EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
7th Edition
ISBN: 8220100853180
Author: STOKER
Publisher: CENGAGE L
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Textbook Question
Chapter 2, Problem 2.91EP
A sample of mercury is found to have a mass of 524.5 g and to have a volume of 38.72 cm3. What is its density in grams per cubic centimeter?
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Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Part I.
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff:
Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
and
(3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism
the formation of the products
For
Chapter 2 Solutions
EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
Ch. 2.1 - Prob. 1QQCh. 2.1 - Preference by scientists for metric system unit...Ch. 2.2 - In which of the following pairings of metric...Ch. 2.2 - In which of the following sequences are the metric...Ch. 2.2 - Which of the following is a correct pairing of...Ch. 2.2 - Prob. 4QQCh. 2.2 - Prob. 5QQCh. 2.2 - Prob. 6QQCh. 2.2 - Prob. 7QQCh. 2.3 - Prob. 1QQ
Ch. 2.3 - Prob. 2QQCh. 2.4 - Prob. 1QQCh. 2.4 - Prob. 2QQCh. 2.4 - Prob. 3QQCh. 2.4 - Prob. 4QQCh. 2.4 - Prob. 5QQCh. 2.4 - Prob. 6QQCh. 2.5 - In which of the following cases is the given...Ch. 2.5 - When rounded to three significant figures, the...Ch. 2.5 - Prob. 3QQCh. 2.5 - Prob. 4QQCh. 2.6 - Prob. 1QQCh. 2.6 - Prob. 2QQCh. 2.6 - Prob. 3QQCh. 2.6 - Prob. 4QQCh. 2.6 - Prob. 5QQCh. 2.6 - Prob. 6QQCh. 2.7 - Prob. 1QQCh. 2.7 - Prob. 2QQCh. 2.7 - Which of the following is an incorrect conversion...Ch. 2.7 - Prob. 4QQCh. 2.8 - Prob. 1QQCh. 2.8 - Prob. 2QQCh. 2.9 - Prob. 1QQCh. 2.9 - Prob. 2QQCh. 2.9 - Prob. 3QQCh. 2.9 - What is the mass, in grams, of 30.0 mL of liquid...Ch. 2.10 - The freezing point of water is a. 0F b. 0 K c. 0C...Ch. 2.10 - Prob. 2QQCh. 2.10 - Prob. 3QQCh. 2.10 - Prob. 4QQCh. 2 - What is the main reason scientists prefer to use...Ch. 2 - List the more common types of measurements made in...Ch. 2 - Complete the following table by filling in the...Ch. 2 - Complete the following table by filling in the...Ch. 2 - Complete the following table by filling in the...Ch. 2 - Complete the following table by filling in the...Ch. 2 - Arrange each of the following from smallest to...Ch. 2 - Arrange each of the following from smallest to...Ch. 2 - Which of the two given units is the more logical...Ch. 2 - Which of the two given units is the more logical...Ch. 2 - A person is told that there are 60 minutes in an...Ch. 2 - Prob. 2.12EPCh. 2 - Indicate whether the number in each of the...Ch. 2 - Indicate whether the number in each of the...Ch. 2 - Indicate whether each of the following quantities...Ch. 2 - Indicate whether each of the following quantities...Ch. 2 - Identify the estimated digit in each of the...Ch. 2 - Identify the estimated digit in each of the...Ch. 2 - Prob. 2.19EPCh. 2 - Prob. 2.20EPCh. 2 - Indicate to what decimal position readings should...Ch. 2 - Indicate to what decimal position readings should...Ch. 2 - Consider the following rulers as instruments for...Ch. 2 - Consider the following rulers as instruments for...Ch. 2 - Using the rulers given in Problem 2-23, what is...Ch. 2 - Using the rulers given in Problem 2-23, what is...Ch. 2 - With which of the rulers in Problem 2-23 was each...Ch. 2 - With which of the rulers in Problem 2-23 was each...Ch. 2 - Determine the number of significant figures in...Ch. 2 - Determine the number of significant figures in...Ch. 2 - Determine the number of significant figures in...Ch. 2 - Determine the number of significant figures in...Ch. 2 - In which of the following pairs of numbers do both...Ch. 2 - In which of the following pairs of numbers do both...Ch. 2 - Prob. 2.35EPCh. 2 - In the pairs of numbers of Problem 2-34, tell...Ch. 2 - Prob. 2.37EPCh. 2 - Complete the following table by filling in the...Ch. 2 - Prob. 2.39EPCh. 2 - The number of people present at an outdoor rock...Ch. 2 - Round off each of the following numbers to the...Ch. 2 - Round off each of the following numbers to the...Ch. 2 - Prob. 2.43EPCh. 2 - Round off (or add zeros) to each of the following...Ch. 2 - Complete the following table by filling in the...Ch. 2 - Complete the following table by filling in the...Ch. 2 - Without actually solving, indicate the number of...Ch. 2 - Without actually solving, indicate the number of...Ch. 2 - Prob. 2.49EPCh. 2 - Carry out the following multiplications and...Ch. 2 - Carry out the following additions and...Ch. 2 - Carry out the following additions and...Ch. 2 - What is the uncertainty in the measured value...Ch. 2 - What is the uncertainty in the measured value...Ch. 2 - For each of the following numbers, will the...Ch. 2 - For each of the following numbers, will the...Ch. 2 - Prob. 2.57EPCh. 2 - Prob. 2.58EPCh. 2 - Prob. 2.59EPCh. 2 - For each of the numbers in Problem 2-56, how many...Ch. 2 - Express the following measured values in...Ch. 2 - Express the following measured values in...Ch. 2 - Change each of the following measured values from...Ch. 2 - Change each of the following measured values from...Ch. 2 - Prob. 2.65EPCh. 2 - Prob. 2.66EPCh. 2 - What is the uncertainty, in terms of a power of...Ch. 2 - What is the uncertainty, in terms of a power of...Ch. 2 - Write each of the following numbers in scientific...Ch. 2 - Write each of the following numbers in scientific...Ch. 2 - Give the two forms of the conversion factor that...Ch. 2 - Give the two forms of the conversion factor that...Ch. 2 - Give the two forms of the conversion factor that...Ch. 2 - Give the two forms of the conversion factor that...Ch. 2 - Prob. 2.75EPCh. 2 - Indicate whether each of the following equations...Ch. 2 - Using dimensional analysis, convert each of the...Ch. 2 - Using dimensional analysis, convert each of the...Ch. 2 - The human stomach produces approximately 2500 mL...Ch. 2 - A typical loss of water through sweating for a...Ch. 2 - The mass of premature babies is customarily...Ch. 2 - The smallest bone in the human body, which is in...Ch. 2 - What volume of water, in gallons, would be...Ch. 2 - What volume of gasoline, in milliliters, would be...Ch. 2 - An individual weighs 83.2 kg and is 1.92 m tall....Ch. 2 - An individual weighs 135 lb and is 5 ft 4 in....Ch. 2 - Prob. 2.87EPCh. 2 - Prob. 2.88EPCh. 2 - Prob. 2.89EPCh. 2 - When each of the following measurements of mass is...Ch. 2 - A sample of mercury is found to have a mass of...Ch. 2 - A sample of sand is found to have a mass of 12.0 g...Ch. 2 - Acetone, the solvent in nail polish remover, has a...Ch. 2 - Silver metal has a density of 10.40 g/cm3. What is...Ch. 2 - The density of homogenized milk is 1.03 g/mL. How...Ch. 2 - Nickel metal has a density of 8.90 g/cm3. How much...Ch. 2 - Water has a density of 1.0 g/cm3 at room...Ch. 2 - Air has a density of 1.29 g/L at room temperature....Ch. 2 - Prob. 2.99EPCh. 2 - A two-gram sample of a red-colored liquid is found...Ch. 2 - Calculate the volume, in milliliters, for each of...Ch. 2 - Calculate the volume, in milliliters, for each of...Ch. 2 - An oven for baking pizza operates at approximately...Ch. 2 - A comfortable temperature for bathtub water is...Ch. 2 - Mercury freezes at 38.9C. What is the coldest...Ch. 2 - Prob. 2.106EPCh. 2 - Prob. 2.107EPCh. 2 - Which is the higher temperature, 15C or 4F?
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- 19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forwardQ4: Write organic product(s) of the following reactions and show the curved-arrow mechanism of the reactions. Br MeOH OSO2CH3 MeOHarrow_forward
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